: Narita. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

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1 Date of issue: 2018/11/20 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name Type of product : : EC (Emulsifiable concentrate) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Function or use category : Professional use : Fungicide Uses advised against 1.3. Details of the supplier of the safety data sheet Belchim Crop Protection NV/SA Technologielaan Londerzeel - Belgium T +32 (0) F +32 (0) info@belchim.com - : Plant protection products 1.4. Emergency telephone number Emergency number : +32(0) H/7 days SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 4 H302 Serious eye damage/eye irritation, Category 2 Aspiration hazard, Category 1 Hazardous to the aquatic environment Chronic Hazard, Category 2 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Harmful if swallowed. Causes serious eye irritation. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects Label elements H319 H304 H411 Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) EUH-statements : Danger GHS07 GHS08 GHS09 : H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII : P102 - Keep out of reach of children. P280 - Wear eye protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P331 - Do NOT induce vomiting. P337+P313 - If eye irritation persists: Get medical advice/attention. P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as nonhazardous waste. : EUH401 - To avoid risks to human health and the environment, comply with the instructions for use. EN (English) 1/7

2 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier Conc (% w/w) Classification according to Regulation (EC) No. 1272/2008 [CLP] Difenoconazole (CAS-No.) ,58 Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If you feel unwell, seek medical advice (show the label where possible). Never give anything by mouth to an unconscious person. : Remove person to fresh air and keep comfortable for breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after eye contact Symptoms/effects after ingestion : Eye irritation. : Risk of lung oedema Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. : Do not use a heavy water stream Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Prevent fire fighting water from entering the environment. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Evacuate unnecessary personnel For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. : Dispose of materials or solid residues at an authorized site. 2018/11/20 (Version: 1.0) EN (English) 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool. Keep only in original container. Incompatible products Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls: Avoid release to the environment. : Strong acids. Strong bases. : Direct sunlight. Sources of ignition. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph : light brown. light yellow. : characteristic. ph solution : 6,5 (1 %) Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : 75 C : Not applicable Auto-ignition temperature : > 260 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1,06 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Not applicable : None. : Non oxidizing material according to EC criteria. 2018/11/20 (Version: 1.0) EN (English) 3/7

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Strong bases. Strong acids Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Oral: Harmful if swallowed. LD50 oral rat LD50 dermal rat mg/kg > 2000 mg/kg LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard mg/kg > 2000 mg/kg > 3,3 mg/l/4h : Causes serious eye irritation. : May be fatal if swallowed and enters airways. SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects. : Toxic to aquatic life with long lasting effects. LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) 1-10 mg/l (96 H; Oncorhynchus mykiss) 1-10 mg/l (48 H; Daphnia magna) 1-10 mg/l (72 H; Pseudokirchneriella subcapitata) 2018/11/20 (Version: 1.0) EN (English) 4/7

5 LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) Persistence and degradability Persistence and degradability < 1 mg/l < 1 mg/l < 1 mg/l Not readily biodegradable. Persistence and degradability Bioaccumulative potential Not readily biodegradable. May cause long-term adverse effects in the environment. Bioconcentration factor (BCF REACH) 300 Bioaccumulative potential Not established. Bioconcentration factor (BCF REACH) 330 Log Pow 4, Mobility in soil Log Koc 3,58 Ecology - soil Results of PBT and vpvb assessment Low mobility (soil). This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Component Other adverse effects This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Ecology - waste materials : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID : 375 : 969 : A197 : 375 : UN number UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (Difenoconazole) 2018/11/20 (Version: 1.0) EN (English) 5/7

6 Transport document description III, (-) III, MARINE POLLUTANT Environmentally hazardous substance, liquid, n.o.s. (Difenoconazole), 9, III III III Transport hazard class(es) Packing group III III III III III Environmental hazards Marine pollutant : Yes No supplementary information available Special precautions for user Overland transport Special provisions (ADR) : 274, 335, 375, 601 Orange plates : Transport by sea No data available Air transport No data available Inland waterway transport Classification code (ADN) Number of blue cones/lights (ADN) : 0 Rail transport No data available : M Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3(b) 3(c) Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Directive 2012/18/EU (SEVESO III) National regulations Chemical safety assessment No chemical safety assessment has been carried out 2018/11/20 (Version: 1.0) EN (English) 6/7

7 SECTION 16: Other information Data sources : SDS of suppliers. ECHA (European Chemicals Agency). REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 H302 H304 H319 H400 H410 H411 EUH401 Harmful if swallowed. May be fatal if swallowed and enters airways. Causes serious eye irritation. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. To avoid risks to human health and the environment, comply with the instructions for use. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2018/11/20 (Version: 1.0) EN (English) 7/7