Drum Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 12/4/2015 Revision date: 9/9/2016 Supersedes: 12/4/2015 Version: 1.

Transcription

1 Date of issue: 12/4/2015 Revision date: 9/9/2016 Supersedes: 12/4/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixtures Trade name : Product code : BCP308F Type of product : WG (Water dispersible granule) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Professional use : Fungicide Uses advised against 1.3. Details of the supplier of the safety data sheet Belchim Crop Protection NV/SA Technologielaan Londerzeel - Belgium T +32 (0) F +32 (0) info@belchim.com Emergency telephone number Emergency number : +32(0) H/7 days SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category 2 Sensitisation Skin, Category 1 Reproductive toxicity, Category 2 Specific target organ toxicity Repeated exposure, Category 2 H319 H317 H361fd H373 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of hazard classes and H-statements : see section 16 Adverse physicochemical, human health and environmental effects Suspected of damaging fertility or the unborn child. May cause damage to organs (blood, thymus) through prolonged or repeated exposure. May cause an allergic skin reaction. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) : Warning GHS07 GHS08 GHS09 Hazard statements (CLP) Precautionary statements (CLP) : H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child H373 - May cause damage to organs (blood, thymus) through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects : P260 - Do not breathe spray P273 - Avoid release to the environment P280 - Wear protective gloves P308+P313 - IF exposed or concerned: Get medical advice/attention P391 - Collect spillage 1/13/2017 EN (English) 1/7

2 EUH-statements P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste. : EUH401 - To avoid risks to human health and the environment, comply with the instructions for use 2.3. Other hazards PBT: not relevant no registration required vpvb: not relevant no registration required SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Cymoxanil (CAS No) (EC no) (EC index no) Mixture of potassium polycarboxylate, contains ammonium distyryl-penyl ethersulphate and toluene Sulfuric acid, mono-c12-14-alkyl esters, sodium salt (CAS No) ; (EC no) (REACH-no) XXXX Fumaric Acid (CAS No) (EC no) (EC index no) X Full text of H-statements: see section Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 Repr. 2, H361fd STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 < 20 Eye Irrit. 2, H319 Aquatic Chronic 3, H412 < 5 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 < 5 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove contaminated clothes. If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell. Do not induce vomiting. Do not ingest Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Symptoms/injuries after eye contact : May cause an allergic skin reaction. : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Do not use extinguishing media containing water. : Toxic fumes may be released Advice for firefighters Firefighting instructions Protection during firefighting : Cool closed containers exposed to fire with water spray. Contain the extinguishing fluids by bunding (the product is hazardous for the environment). : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 1/13/2017 EN (English) 2/7

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Do not allow into drains or water courses Methods and material for containment and cleaning up For containment Methods for cleaning up Other information : Collect spillage. Contain the spilled material by bunding (product is hazardous for the environment). : Mechanically recover the product. Notify authorities if product enters sewers or public waters. : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Avoid all eye and skin contact and do not breathe vapour and mist. : Ensure good ventilation of the work station. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with skin and eyes. : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Ensure good ventilation of the work station. : Gloves. Protective clothing. Protective goggles. : Use neoprene gloves. Nitrile rubber gloves : Chemical goggles or safety glasses. Safety glasses : Wear suitable protective clothing. Rubber boots. Neoprene rubber or butyl rubber suit : In case of inadequate ventilation wear respiratory protection. Wear respiratory protection Environmental exposure controls Other information : Avoid release to the environment. : Wash hands with water and soap. Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 1/13/2017 EN (English) 3/7

4 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph ph solution Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : Solid : Granulate. : Beige. : %; Water Auto-ignition temperature : > 267 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity : Not flammable : 0.88 g/ml : Dispersible. : None. : None. The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation > 2000 mg/kg > 2000 mg/kg 960 mg/kg > 2000 mg/kg > 5.6 mg/l/4h 1/13/2017 EN (English) 4/7

5 Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Eye irritation : May cause an allergic skin reaction : Suspected of damaging fertility. Suspected of damaging the unborn child. : May cause damage to organs (blood, thymus) through prolonged or repeated exposure. SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 EC50 Daphnia 1 EC50 72h algae (1) : Very toxic to aquatic life with long lasting effects. > 10 mg/l > 100 mg/l > 1 mg/l LC50 fish 1 EC50 other aquatic organisms 1 EC50 72h algae (1) > 29 mg/l 27 mg/l 0.12 mg/l NOEC chronic fish mg/l (90 d) NOEC chronic crustacea mg/l (21 d) Persistence and degradability Persistence and degradability Persistence and degradability No supplementary information available. No supplementary information available Bioaccumulative potential Bioaccumulative potential Mobility in soil Ecology - soil No bioaccumulation. Biodegradability in soil: no data available Results of PBT and vpvb assessment PBT: not relevant no registration required vpvb: not relevant no registration required Component Other adverse effects Other adverse effects This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII : No supplementary information available. SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste treatment methods SECTION 14: Transport information : Waste instruction. : Dispose of contents/container in accordance with licensed collector s sorting instructions. In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name ENVIRONMENTALLY ENVIRONMENTALLY Environmentally ENVIRONMENTALLY ENVIRONMENTALLY 1/13/2017 EN (English) 5/7

6 ADR IMDG IATA ADN RID Transport document description ENVIRONMENTALLY ENVIRONMENTALLY, 9, III,, 9, III, (E) MARINE POLLUTANT hazardous substance, solid, n.o.s. (Cymoxanil) Environmentally hazardous substance, solid, n.o.s. (Cymoxanil), 9, III ENVIRONMENTALLY, 9, III ENVIRONMENTALLY, 9, III Transport hazard class(es) Packing group III III III III III Environmental hazards Marine pollutant : Yes Special precautions for user - Overland transport Orange plates : No supplementary information available - Transport by sea No data available - Air transport No data available - Inland waterway transport Classification code (ADN) : M7 Number of blue cones/lights (ADN) : 0 - Rail transport No data available Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations National regulation Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information 1/13/2017 EN (English) 6/7

7 Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H302 H315 H317 H318 H319 H361fd H373 H400 H410 H412 EUH401 Harmful if swallowed Causes skin irritation May cause an allergic skin reaction Causes serious eye damage Causes serious eye irritation Suspected of damaging fertility. Suspected of damaging the unborn child May cause damage to organs through prolonged or repeated exposure Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects To avoid risks to human health and the environment, comply with the instructions for use SDS EU BCP (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 1/13/2017 EN (English) 7/7