SAFETY DATA SHEET BLUE STAR DE-ICER AEROSOL

Transcription

1 Report Date : 25/06/ / 5 SDS NO.: SAFETY DATA SHEET BLUE STAR DE-ICER AEROSOL 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. INTERNAL ID APPLICATION SUPPLIER BLUE STAR DE-ICER AEROSOL EDI300, SDI600, SDI300, SDI411, JDI300, JDI600, NDI411, SPW600, MDV600, NDI501, EDI301, EDI600, EDI601, HOT042, NDI311, NDI004, NDI601, SDI311 C Antifreeze liquid TETROSYL LIMITED BEVIS GREEN WORKS WALMERSLEY BURY BL9 6RE info@tetrosyl.com 2 HAZARDS IDENTIFICATION Extremely flammable. CLASSIFICATION F+;R12. HUMAN HEALTH See section 11 for additional information on health hazards. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification AMMONIA...% <1% C;R34 N;R50 BUTANE/PROPANE BLEND % F+;R12. ETHANEDIOL % Xn;R22 ETHANOL % F;R11 IPA % F;R11 Xi;R36 R67 METHANOL % F;R11 T;R23/24/25,R39/23/24/25 The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES GENERAL INFORMATION Remove affected person from source of contamination. Get medical attention immediately! INHALATION Move injured person into fresh air immediately. Call an ambulance. Be aware that symptoms of lung oedema (shortness of breath) may develop up to 24 hours after exposure. Bring these instructions. Place unconscious person on the side in the recovery position and ensure breathing can take place. INGESTION Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If vomiting occurs, keep head low. Transport immediately to hospital and take these instructions. SKIN CONTACT Remove contaminated clothing immediately and wash skin with soap and water. Consult a physician for specific advice.

2 Report Date : 06/07/ / 3 SDS NO.: SAFETY DATA SHEET ALL SEASONS SCREENWASH 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER ALL SEASONS SCREENWASH NSW010, NSW025, NSW050, SWA001, SWA005, SWA025, SWA199, SWA500, SWA506 Glass cleaner TETROSYL LIMITED BEVIS GREEN WORKS WALMERSLEY BURY BL9 6RE info@tetrosyl.com 2 HAZARDS IDENTIFICATION Flammable CLASSIFICATION R10. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification BUTYL GLYCOL <0.1% Xn;R20/21/22 Xi;R36/38 ETHANOL % F;R11 IPA % F;R11 Xi;R36 R67 METHANOL <1% F;R11 T;R23/24/25,R39/23/24/25 The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES 5 FIRE-FIGHTING MEASURES 6 ACCIDENTAL RELEASE MEASURES 7 HANDLING AND STORAGE 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std TWA - 8 hrs STEL - 15 min Notes BUTYL GLYCOL WEL 25 ppm(sk) 50 ppm(sk) ETHANOL WEL 1000 ppm 1920 mg/m3 IPA WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 METHANOL WEL = Workplace Exposure Limit. WEL ppm(sk) mg/m3(sk) ppm(sk) 333 mg/m3(sk)

3 Report Date : 06/07/ / 3 9 PHYSICAL AND CHEMICAL PROPERTIES ALL SEASONS SCREENWASH SDS NO.: APPEARANCE COLOUR ODOUR Coloured liquid Blue Odour of alcohol BOILING POINT ( C) 86 FLASH POINT ( C) STABILITY AND REACTIVITY 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION 13 DISPOSAL CONSIDERATIONS 14 TRANSPORT INFORMATION UK ROAD CLASS 3 PROPER SHIPPING NAME FLAMMABLE LIQUID, N.O.S. (ETHANOL, METHANOL) UN NO. ROAD ADR CLASS NO. ADR PACK GROUP III UK ROAD PACK GR. ADR CLASS TUNNEL RESTRICTION CODE HAZARD No. (ADR) 30 ADR LABEL NO. 3 HAZCHEM CODE RID CLASS NO. 3YE 3 CEFIC TEC(R) NO. RID PACK GROUP UN NO. SEA 1993 IMDG CLASS 3 IMDG PACK GR. III UN NO. AIR 1993 AIR CLASS 3 AIR PACK GR. 15 REGULATORY INFORMATION III EMS III Class 3: Flammable liquids. (D/E) 30GF1-III, 30GF1-sp III F-E, S-E RISK PHRASES SAFETY PHRASES R10 S2 S46 S51 S56 Flammable Keep out of the reach of children If swallowed, seek medical advice immediately and show this container or label. Use only in well-ventilated areas. Dispose of this material and its container to hazardous or special waste collection point. 16 OTHER INFORMATION REVISION DATE 02/07/2008 REV. NO./REPL. SDS GENERATED 19

4 Report Date : 06/07/ / 3 ALL SEASONS SCREENWASH SDS NO.: RISK PHRASES IN FULL R11 R20/21/22 R23/24/25 R36 R36/38 R39/23/24/25 R67 Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes. Irritating to eyes and skin. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Vapours may cause drowsiness and dizziness. DISCLAIMER The information provided in this document has been compiled on the basis of our current knowledge and is believed to be in accordance with the requirements of the Dangerous Substances Directive, Dangerous Preparations Directive and Safety Data Sheets Directive. The information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any particular conditions or process. The conditions and extent of storage and use of material are outside of our control and within the control of the possessor or user. Consequently it is the responsibility of the possessor or user to satisfy themselves as to the completeness of such information and the suitability of the material for their own particular circumstances, conditions or use.

5 Material Safety Data Sheet ***SECTION 1-CHEMICAL PRODUCT AND COMPANY IDENTIFICATION*** Product Name: Silocone Oil Company Identification: JIANGYIN YINGHUAMENG HOUSEWARE CO.,LTD. YUECHENG TOWN, JIANGYIN, JIANGSU, CHINA. Emergency telephone ****SECTION 2-COMPOSITION, INFORMATION ON INGREDIENTS**** Formula % Polydimethylsiloxane 100 ****SECTION 3-HAZARDS IDENTIFICATION**** CAUTION! May cause eye irritation. Attention: Not for injection into humans. May generate formaldehyde at temperature greater than 150C. *****SECTION 4-FIRST AID MEASURES**** EYES In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. SKIN Wash with soap and water. INGESTION Do not include vomiting. Slowly dilute with 1-2 glasses of water or mink and seek medical attention. Never give anything by mouth to an unconscious person. INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If breathing is difficult give oxygen. Get medical attention. *****SECTION 5-FIRE EIGHTING MEASURES Dry chemical, sandy soil, chemical foam or carbon dioxide. *****SECTION 6-ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid contact with skin, eyes and clothing. Enviromental precautions: Do not flush into surface water, sanitary sewer or ground water system.

6 ****SECTION 7-HANDLING and STORAGE***** STORAGE Store in a cool, well-ventilated area. Keep away from ignition sources, heat and flame. Store in a tightly closed container. Incompatibilities: oxidants and food. *****SECTION 8-EXPOSURE CONTROLS, PERSONAL PROTECTION**** PROTECTIVE GLOVES Rubber or plastic gloves EYE AND FACE PROTECTION Safety glasses OTHER PROTECTIVE EQUIPMENT Wear suitable protective clothing and eye/face protection. *****SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES**** BOILING POINT >204 VAPOR PRESSURE(20C)(MM HG) Negligible VAPOR DENSITY (AIR=1) FREEZING POINT MELTING POINT PHYSICAL STATE Liquid ODOR None COLOR Clear SPECIFIC GRAVITY (WATER=1) ca.0.97 DENSITY(KG/M3) ca.970kg/m3 PH NA SOLUBILITY IN ORGANIC SOLVENT(STATE SOLVENT) VOC EXCL.H2O & EXEMPTS (G/L) ca.14 Slightly in Toluene ****SECTION 10-STABILITY AND REACTIVITY***** STABLILITY Stable. HAZARDOUS POLYMERIZATION Will not occur.

7 HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS Carbon dioxide INCOMPATIBILITY(MATERIALS TO AVOID) None known. CONDITIONS TO AVOID None known. ****SECTION 11-TOXICOLOGICA INFORMATION**** Acute dermal LD50rat>5,000mg/kg Acute eye irritation/corrosion (Rabbit) Acute skin sensitization(guinea pig) not irritant not irritant MUTAGENICITY Unknown. ****SECTION 12-ECOLOGICAL INFORMATION**** ECOTOXICOLOGY No data available. CHEMICAL FATE No data available. DISTRIBUTION No data available. ****SECTION 13- DISPOSAL CONSIDERATIONS**** Waste from residues/ unused products: Residal chemical should be disposed by incineration or by other modes of disposal in compliance with local legislation. Packaging material should be subjected to waste management schemes.(recovery recycling reuse.)according to local legislation. ****SECTION 14-TRANSPORT INFORMATION**** Road (CDGRR) : not restricted. Air (IATA) : not restricted.

8 Sea (IMDG) : not restricted. *****SECTION 15-REGULATORY INFORMATION**** Directive 1999/45/EC (classification and labelling): Symbols: Xn Harmful N Dangerous for the environment R Phrases: R65 Harmful: may cause lung damage if swallowed. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S Phrases: S 2 Keep out of reach of children S56 Dispose of this material and its container at hazardous or special waste collection point. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S24/25 Avoid contact with skin and eyes. S37 Wear suitable gloves ****SECTION 16-ADDITIONAL INFORMATION**** The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to detemine the suitability of the information for their particular purposes.

9 Report Date : 25/06/ / 5 EYE CONTACT BLUE STAR DE-ICER AEROSOL Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Immediately transport to hospital or eye specialist. 5 FIRE-FIGHTING MEASURES SDS NO.: EXTINGUISHING MEDIA Use fire-extinguishing media appropriate for surrounding materials. SPECIAL FIRE FIGHTING PROCEDURES Be aware of danger of explosion. SPECIFIC HAZARDS By heating and fire, toxic vapours/gases may be formed. PROTECTIVE MEASURES IN FIRE Leave danger zone immediately. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. In case of spills, beware of slippery floors and surfaces. ENVIRONMENTAL PRECAUTIONS The product should not be dumped in nature but collected and delivered according to agreement with the local authorities. SPILL CLEAN UP METHODS For waste disposal, see section 13. When dealing with a spillage, please consult the section relating to suitable protective measures. Absorb spillage with non-combustible, absorbent material. Ventilate well. Prevent discharge of larger quantity to drain. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Read and follow manufacturer's recommendations. Always remove grease with soap and water or skin cleaning agent, never use organic solvents. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Do not eat, drink or smoke when using the product. STORAGE PRECAUTIONS Keep away from heat, sparks and open flame. Store in tightly closed original container in a dry, cool and well-ventilated place. STORAGE CLASS Flammable liquid storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std TWA - 8 hrs STEL - 15 min Notes AMMONIA...% WEL 18 mg/m3 25 mg/m3 BUTANE/PROPANE BLEND ETHANEDIOL ETHANOL IPA WEL 1000 ppm 1750 mg/m ppm 2180 mg/m3 WEL 10 mg/m3(sk) 104 mg/m3(sk) WEL 1000 ppm 1920 mg/m3 WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 METHANOL WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT WEL ppm(sk) mg/m3(sk) ppm(sk) 333 mg/m3(sk)

10 Report Date : 25/06/ / 5 PROCESS CONDITIONS BLUE STAR DE-ICER AEROSOL Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station. ENGINEERING MEASURES Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit is not exceeded. RESPIRATORY EQUIPMENT In case of inadequate ventilation use suitable respirator. HAND PROTECTION The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTION Wear splash-proof eye goggles to prevent any possibility of eye contact. OTHER PROTECTION Provide eyewash station. HYGIENE MEASURES Wash contaminated clothing before reuse. Wash at the end of each work shift and before eating, smoking and using the toilet. SKIN PROTECTION Protection suit must be worn. 9 PHYSICAL AND CHEMICAL PROPERTIES SDS NO.: APPEARANCE Aerosol 10 STABILITY AND REACTIVITY STABILITY No particular stability concerns. 11 TOXICOLOGICAL INFORMATION HEALTH WARNINGS This chemical can be hazardous when inhaled and/or touched. Vapour from this chemical can be hazardous when inhaled. ROUTE OF ENTRY Inhalation. Ingestion. Skin and/or eye contact. Skin absorption. 12 ECOLOGICAL INFORMATION ECOTOXICITY Dangerous for the environment if discharged into watercourses. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION When handling waste, consideration should be made to the safety precautions applying to handling of the product. Only experts should be permitted to carry out disposal of this material. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. Absorb spillage with non-combustible, absorbent material. 14 TRANSPORT INFORMATION GENERAL Full protective clothing should be worn when handling this product.

11 Report Date : 25/06/ / 5 BLUE STAR DE-ICER AEROSOL SDS NO.: UK ROAD CLASS 2.1 PROPER SHIPPING NAME AEROSOLS UN NO. ROAD 1950 UK ROAD PACK GR. # ADR CLASS NO. 2.1 ADR CLASS ADR PACK GROUP # ADR LABEL NO. 2.1 CEFIC TEC(R) NO. 20G5F RID CLASS NO. 2.1 RID PACK GROUP # UN NO. SEA 1950 IMDG CLASS 2.1 IMDG PACK GR. # EMS F-D, S-U MFAG MARINE POLLUTANT No. UN NO. AIR 1950 AIR CLASS 2.1 AIR PACK GR. # 15 REGULATORY INFORMATION Class 2: Gases See Guide LABELLING Extremely Flammable RISK PHRASES SAFETY PHRASES R12 A1 A2 S2 S9 S16 S51 S56 S46 S23 Extremely flammable. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep out of the reach of children Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Use only in well-ventilated areas. Dispose of this material and its container to hazardous or special waste collection point. If swallowed, seek medical advice immediately and show this container or label. Do not breathe vapour/spray. DETERGENT LABELLING EU DIRECTIVES < 5% Aliphatic hydrocarbons Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. System of specific information relating to Dangerous Preparations. 2001/58/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. 16 OTHER INFORMATION REVISION COMMENTS NOTE: Lines within the margin indicate significant changes from the previous revision.

12 Report Date : 25/06/ / 5 ISSUED BY HS&E Manager. REVISION DATE 16/06/2008 REV. NO./REPL. SDS GENERATED 22 BLUE STAR DE-ICER AEROSOL SDS NO.: RISK PHRASES IN FULL R11 R12 R22 R23/24/25 R34 R36 R37 R39/23/24/25 R50 R67 Highly flammable. Extremely flammable. Harmful if swallowed. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to eyes. Irritating to respiratory system. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms. Vapours may cause drowsiness and dizziness. DISCLAIMER The information provided in this document has been compiled on the basis of our current knowledge and is believed to be in accordance with the requirements of the Dangerous Substances Directive, Dangerous Preparations Directive and Safety Data Sheets Directive. The information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any particular conditions or process. The conditions and extent of storage and use of material are outside of our control and within the control of the possessor or user. Consequently it is the responsibility of the possessor or user to satisfy themselves as to the completeness of such information and the suitability of the material for their own particular circumstances, conditions or use.