Safety Data Sheet According to EC Directive 91/155/EEC Date of issue: Supersedes edition of
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1 Safety Data Sheet Date of issue: Supersedes edition of Identification of the substance/preparation and of the company/undertaking Identification of the product Use of the substance/preparation Chemical for synthesis Company/undertaking identification Company: Merck Schuchardt OHG * Hohenbrunn * Germany * Tel: /802-0 Emergency telephone No.: Please contact the regional Merck representation in your country. 2. Composition/information on ingredients Synonyms o-chlorobenzene CAS-No.: EC-Index-No.: M: g/mol EC-No.: Formula Hill: C 6 H 4 Cl 2 3. Hazards identification Harmful if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. First aid measures After inhalation: fresh air. If necessary, apply mouth-to-mouth resuscitation or mechanical ventilation. Keep airways free. After skin contact: wash off with plenty of water. Remove contaminated clothing. After eye contact: rinse out with plenty of water with the eyelid held wide open. Call in ophtalmologist. After swallowing: make victim drink plenty of water, avoid vomiting (risk of aspiration!). Subsequently administer: Sodium sulfate (1 tablespoon/1/4 l water). Call in physician. The Safety Data Sheets for catalog items are also available at Page 1 of 6
2 5. Fire-fighting measures Suitable extinguishing media: Water, CO 2, foam, powder. Special risks: Combustible. Vapours heavier than air. Formation of hazardous combustion gases or vapours possible in event of fire. Forms explosive mixtures with air at ambient temperatures. The following may develop in event of fire: hydrochloric acid, chlorine, phosgene, dioxin. Special protective equipment for fire fighting: Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing. Other information: Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or groundwater. 6. Accidental release measures Person-related precautionary measures: Avoid substance contact. Do not inhale vapours/aerosols. Ensure supply of fresh air in enclosed rooms. Environmental-protection measures: Do not allow to enter sewerage system. Procedures for cleaning / absorption: Take up with liquid-absorbent material (e.g. Chemizorb ). Forward for disposal. Clean up affected area. 7. Handling and storage Handling: No further requirements. Storage: Tightly closed. At +15 C to +25 C. 8. Exposure controls/personal protection Specific control parameter EC Name 1,2-Dichlorobenzene Value 20 ml/m mg/m 3 Skin resorption Risk of skin absorption Personal protective equipment: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. The Safety Data Sheets for catalog items are also available at Page 2 of 6
3 Respiratory protection: Eye protection: Hand protection: required when vapours/aerosols are generated. Filter A (acc. to DIN 3181) for vapours of organic compounds required In full contact: Glove material: viton Layer thickness: 0.70 mm Breakthrough time: > 480 Min. In splash contact: Glove material: nitrile rubber Layer thickness: 0.40 mm Breakthrough time: > 30 Min. The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN374, for example KCL 890 Vitoject (full contact), 730 Camatril -Velours (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet and supplied by us as well as to the purpose specified by us. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D Eichenzell, Internet: Industrial hygiene: Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash hands and face after working with substance. 9. Physical and chemical properties Form: liquid Colour: colourless Odour: characteristic ph value not available Viscosity dynamic (20 C) 1.32 mpa*s Melting point -17 C Boiling point 180 C Ignition temperature 640 C Flash point 66 C c.c. (DIN 51758) Explosion limits lower 2.2 Vol% upper 12 Vol% Vapour pressure (20 C) 1.33 hpa Relative vapour density 5.1 Density (20 C) 1.31 g/cm 3 Solubility in water (20 C) almost insoluble log Pow: 3.43 (experimental) The Safety Data Sheets for catalog items are also available at Page 3 of 6
4 10. Stability and reactivity Conditions to be avoided Heating. Substances to be avoided Violent reactions possible with: alkali metals, alkaline earth metals, halogenated hydrocarbons / aluminium, light metals, acids and water. Hazardous decomposition products in the event of fire: See chapter 5. Further information solvent for resins and oils unsuitable working materials: various plastics, rubber, aluminium. Explosible with air in a vaporous/gaseous state. 11. Toxicological information Acute toxicity LC 50 (inhalation, rat): 8.15 mg/l /4 h. LD 50 (dermal, rabbit): >10000 mg/kg. LD 50 (oral, rat): 500 mg/kg. Specific symptoms in animal studies: Eye irritation test (rabbit): Irritations. Skin irritation test (rabbit): Irritations. Subacute to chronic toxicity Bacterial mutagenicity: Ames test: negative. Further toxicological information After inhalation of vapours: mucosal irritations, coughing, dyspnoea. After skin contact: Severe irritations. Degreasing effect on the skin, possibly followed by secondary inflammation. Danger of skin absorption. After eye contact: Severe irritations. After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. After absorption of large quantities: CNS disorders (psychoses, headache, dizziness, narcosis). After long-term exposure to the chemical: Toxic effect on: liver, kidneys. Further data The product should be handled with the care usual when dealing with chemicals. The Safety Data Sheets for catalog items are also available at Page 4 of 6
5 12. Ecological information Biologic degradation: Biodegradation: 58 % /20 d (closed bottle test). Biologically not readily degradable. Behavior in environmental compartments: Distribution: log p(o/w): 3.43 (experimental). An appreciable bioaccumulation potential is to be expected (log P(o/w) >3). Ecotoxic effects: Biological effects: Highly toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Fish toxicity: Br.rerio LC 50 : 5.2 mg/l /96 h. Daphnia toxicity: Daphnia magna EC 50 : 1.7 mg/l /24 h. Algeal toxicity: Desmodesmus subspicatus IC 50 : 14 mg/l /48 h. Maximum permissible toxic concentration: Bacterial toxicity: Ps.putida EC 5 : 15 mg/l /16 h. Further ecologic data: Do not allow to enter waters, waste water, or soil! 13. Disposal considerations Product: Chemicals must be disposed of in compliance with the respective national regulations. Under you will find country- and substance-specific information as well as contact partners. Packaging: Merck product packaging must be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system. Under you will find special information on the respective national conditions as well as contact partners. 14. Transport information Road & Rail ADR, RID UN 1591 O-DICHLORBENZEN, 6.1, III Inland waterway ADN, ADNR not tested Sea IMDG-Code UN 1591 ORTHO-DICHLOROBENZENE, 6.1, III Ems F-A S-A Air CAO, PAX O-DICHLOROBENZENE, 6.1, UN 1591, III The transport regulations are cited according to international regulations and in the form applicable in Germany. Possible national deviations in other countries are not considered. The Safety Data Sheets for catalog items are also available at Page 5 of 6
6 15. Regulatory information Labelling according to EC Directives Symbol: Xn Harmful N Dangerous for the environment R-phrases: 22-36/37/38-50/53 Harmful if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases: Do not breathe vapour. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. EC-No.: EC label Reduced labelling (1999/45/EC,Art.10,4) Symbol: Xn Harmful N Dangerous for the environment R-phrases: 22 Harmful if swallowed. S-phrases: Other information Reason for alteration General update. Regional representation: This information is given on the authorised Safety Data Sheet for your country. The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product. The Safety Data Sheets for catalog items are also available at Page 6 of 6
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