Material Safety Data Sheet 21105D

Transcription

1 Revision Date: 05/07/2008 Issued: 05/07/2008 Responsible Party: Material Safety Data Sheet FUNGITROL 920 FUNGICIDE 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION International Specialty Products 1361 Alps Rd. Wayne, N.J U.S.A. Telephone: (973) Emergency Telephone Number: Prepared By: Product Id: Product Name: CAS Registry Number: CAS Name: Product Use: CHEMTREC: or (Outside of the USA) (Spill Related Emergencies) PROSAR: (Health Related Emergencies) Product Stewardship FUNGITROL 920 FUNGICIDE NA MIXTURE Biocide 2. HAZARDS IDENTIFICATION Emergency Overview WARNING! HARMFUL IF INHALED. CAUSES MODERATE SKIN IRRITATION. CAUSES MODERATE EYE IRRITATION. White Liquid Hazard Overview Target Organs: Primary Route(s) of Exposure: Acute Health Hazards: Chronic Health Hazards: Eyes Skin Respiratory System Eyes. Skin. Inhalation. Causes moderate skin irritation. Causes moderate eye irritation. Unknown Signs and Symptoms of Overexposure Eye Contact: Causes moderate eye irritation. Skin Contact: Ingestion: Inhalation: Causes moderate skin irritation. May be harmful if swallowed. Harmful if inhaled. Page 1 of 6

2 3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS Components: Weight % Carbamic acid. butyl-, 3-iodo propynyl ester (IPBC) NJ TSRN# % Eye Contact: Skin Contact: Ingestion: Inhalation: 4. FIRST AID MEASURES In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Immediately wash with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing or if breathing is difficult, give artificial respiration or oxygen by trained personnel. Seek medical attention. 5. FIRE FIGHTING MEASURES NFPA Rating: Health: 2 Flammability: 0 Reactivity: 0 Flash Point ( F): Extinguishing Media: Not determined water fog, carbon dioxide, foam, dry chemical Unusual Fire/Explosion Hazards: Unknown Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing equipment. HMIS RATING: HEALTH 2* FLAMMABILITY 0 PHYSICAL HAZARD 0 Personal Precautionary Measures: Procedure for Cleaning/Absorption: Handling: Storage: Engineering Controls: Respiratory Protection: Hand Protection: Eye Protection: 6. ACCIDENTAL RELEASE MEASURES Use appropriate protective equipment. Contain spill with sand or other inert materials. 7. HANDLING AND STORAGE Avoid contact with skin and eyes. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Wash thoroughly with soap and water after handling. Keep containers tightly closed when not in use. Store in a cool, dry place, out of direct sunlight. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Use in a well ventilated area. Use in a well ventilated area. Wear a NIOSH approved respirator appropriate for airborne exposure at the point of use. All cleanable impervious glove types are acceptable. Chemical goggles; also wear a face shield if splashing hazard exists. Page 2 of 6

3 Exposure Limits Components: ACGIH Threshold Limit Values Data - Time Weighted Average (TWA): OSHA Specifically Regulated Substances Data - Time Weighted Average (TWA): Carbamic acid. butyl-, 3-iodo- No TLV/TWA Established No TLV/TWA Established 2-propynyl ester (IPBC) NJ TSRN# mg/m 3 15 mg/m 3 (Total dust) Physical State: Color: Odor: Odor Threshold: ph: Specific Gravity: Bulk Density: 9. PHYSICAL AND CHEMICAL PROPERTIES Dispersion White None Not available (10% solution) g/cm3 9.4 lbs/gal Boiling Point ( F): 212 Melting Point/Freezing Point( F): 35.6 Vapor Pressure: Solubility: Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Materials to Avoid: Hazardous decomposition products: Toxicity Test: Acute Oral LD50 (mg/kg): Acute Dermal LD50 (mg/kg): Acute Inhalation LC50 (mg/l): Sensitization: Mutagenicity: F Miscible in Water 10. STABILITY AND REACTIVITY Stable under normal conditions of handling, use and transportation. Will not occur None anticipated Strong bases. Corrodes metal packaging containers. Non-protected steel. Carbon monoxide. Carbon dioxide. Iodine vapors. 11. TOXICOLOGICAL INFORMATION 2,389 (rat) (similar product) >5,000 (rat) (similar product) 1.80 (4H) (rat) (similar product) Non- sensitizing to guinea pig skin. (similar product) (IPBC) Non-mutagenic (Bacterial Reverse Mutation Assay, Chromosomal Aberration Study, Unscheduled DNA Synthesis) Page 3 of 6

4 Carcinogenicity: IARC 2B : Possibly Carcinogenic to Humans (trade secret) This material contains a component that has been tested in several carcinogenicity studies. Lung tumors were observed in rats following high dose exposure by inhalation and in female rats exposed by intratracheal instillation. Other studies have shown no tumors in rats following inhalation exposure and no tumors in mice or rats following oral exposure. Not carcinogenic in rats after daily administration for 2 years via the diet (up to 80 mg/kg/day) (IPBC) Teratogenicity: Skin Irritation: Eye Irritation: Other Information: Biodegradability: Aquatic Toxicity: (IPBC) Does not cause reproductive or developmental toxicity or teratogenicity when administered orally to mice or rats. Moderately irritating to rabbit skin. (similar product) Moderately irritating to rabbit eye. (similar product) (IPBC) 13-Week Oral Toxicity: given to rats by gavage for 5 days/week for 13 weeks at 20, 50 or 125 mg/kg/day with a NOEL of 20 mg/kg/day. 4-Week Feeding Study: administered to rats via the diet at 60, 125 or 250 mg/kg/day for 4 weeks resulted in treatment-related effects at all doses. A NOEL was not established. 12. ECOLOGICAL INFORMATION Not determined. (IPBC) Bioconcentration: low potential for concentration in aquatic biota Rainbow Trout: 24, 48, 72 and 96 hour LC50's in rainbow trout were >0.12, 0.097, and ppm respectively Bluegill: 24, 48, 72 and 96 hour LC50's in Bluegill were >0.32, 0.23, 0.23 and 0.23pmm respectively Daphnia magna: 48 hour LC50 in Daphnia magna was determined to be ppm in a 48-hour static test without renewal of test media. In a chronic study, the 7-day, 14-day, and 21-day EC50's were 0.142, and 0.133ppm respectively Avian Toxicity: was not toxic when ingested by quail or malard ducks Disposal of Waste Method: 13. DISPOSAL CONSIDERATIONS Federal, state and local disposal laws and regulations will determine the proper waste disposal/recycling/reclamation procedure. Disposal requirements are dependent on the hazard classification and will vary by location and the type of disposal selected. RCRA Class- Components: Listed. Carbamic acid. butyl-, 3-iodo-2-propynyl ester (IPBC) Land Transportation: DOT (Non-Bulk): UN/NA Number: DOT Shipping Name: 14. TRANSPORT INFORMATION UN3082 Hazard Class: 9 Page 4 of 6

5 DOT (Bulk): UN/NA Number: DOT Shipping Name: UN3082 Hazard Class: 9 DOT Marine Pollutant: This product has been determined to be a marine pollutant. Air Transportation (IATA): UN Number: 3082 Proper Shipping Name: Hazard Classification: 9 Sea Transportation (IMO): UN/ID Number: 3082 Proper Shipping Name: Hazard Classification: 9 Marine Pollutant: This product has been determined to be a marine pollutant. TDG (Canada): UN Number: 3082 Proper Shipping Name: Hazard Class: 9 TDG Marine Pollutant: TSCA Inventory List: California Proposition 65 Carcinogens & Reproductive Toxicity (CRT) List: WHMIS Ingredient Disclosure List: This product has been determined to be a marine pollutant. 15. REGULATORY INFORMATION This product and/or its components is listed on TSCA. None of the components of this product is listed on CALPROP. None of the components of this product is listed on WHMIS Ingredient Disclosure list. Canada DSL Inventory List: This product and/or its components is listed on DSL. Page 5 of 6

6 Canada NDSL Inventory List: Japan Inventory of Existing & New Chemical Substances (ENCS): Australia Inventory of Chemical Substances (AICS) List: EU EINECS List: ELINCS: This product and/or its components is not listed on NDSL. This product and/or its components is not listed on ENCS. This product and/or its components is not listed on AICS. This product and/or its components is not listed on or is exempt from EINECS. This product and/or its components is not listed on ELINCS. Components: Carbamic acid. butyl-, 3-iodo- 2-propynyl ester (IPBC) 313 Toxic Chemical Data - De minimis concentration: 302 Extremely Hazardous Substance Extremely Hazardous Spill Data - Reportable quantity: 302 Extremely Hazardous Substance Data - Threshold Planning Quantity: 1.0 % Listed. 313 Toxic Chemical - Prepared By: Legend: Important Note: 16. OTHER INFORMATION Product Stewardship N.Av.= Not Available; N.A.= Not Applicable For purposes of this MSDS, International Specialty Products, as responsible party, provides the information herein which is intended for use by persons who have or should obtain professional knowledge and experience in the subjects discussed. ISP s industrial products are used as materials in the production of products by industrial customers. ISP usually has only limited information about the products of its customers and their composition, methods of manufacture and use. Accordingly, ISP MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY, COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF, ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers independently test and evaluate its products and their products and processes in which ISP products are used in order to decide their safety and effectiveness. ***END OF MSDS*** Page 6 of 6