Safety Data Sheet PYRETHRO VIORYL 5SC. Insecticide with natural pyrethrins: extracts from the plant Chrysanthemum cinerariaefolium

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1 Chemical & Agricultural Industry, research s.a. Safety Data Sheet PYRETHRO VIORYL 5SC 1. IDENTIFICATION OF THE PRODUCT AND THE COMPANY 1.1 Identification of the product Designation Description Trade name Insecticide with natural pyrethrins: extracts from the plant Chrysanthemum cinerariaefolium PYRETHRO VIORYL 5SC 1.2 Use of the product Product use Suspension liquid used as insecticide in Agricultural crops. 1.3 Company details Produced by VIORYL S.A. Telephone No th km Athens-Lamia Nat. Road Telefax No AFIDNES GREECE 1.4 Emergency telephone number : Poisoning center HAZARDS IDENTIFICATION 2.1 Classification Classified as irritating material. Dangerous substance: pyrethrins Cas no: , According to the Directive 67/548 EC and Directive 1999/45 EC Xi Ν IRRITANT DANGEROUS FOR THE ENVIRONMENT (R) Phrases: R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. (S) Phrases: S1/2 Keep locked up and out of reach of children. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 Wear suitable protective clothing. S20/21 When using do not eat, drink or smoke. S28 After contact with skin, wash immediately with plenty of water S61:Avoid release to the environment refer to special instruction/data sheets.

2 According to Regulation 1272/2008/ΕC Pictograms: Warning Hazard statements H411: Toxic to aquatic life with long lasting effects, Hazard class: Hazardous to the aquatic environment, long-term, Category 2 H317: May cause an allergic skin reaction Hazard class: Sensitisation, Skin, Category 1 Precautionary statements General P405+P102 Keep it locked and out of reach of children. P103 Read label before use. P270: Do no eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305+P351 IF IN EYES: Rinse cautiously with water for several minutes. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to an approved waste collection point P321: Specific treatment (see on this label). EUH401: To avoid risks to human health and the environment, comply with the instructions for use. 2.2 Environment This product is expected to harm aquatic organisms. Avoid discharge to natural water resources, ponds and lakes with aquatic life. (See Section 12.) 2.3 Other Fire, heating and detonation: This product will burn although it is not easily ignited. Toxic vapors (carbon monoxide and dioxide) could be released during a fire. Respiratory protection should be provided. 3. COMPOSITION / INFORMATION ON INGREDIENTS 3.1 Nature of ingredients and concentration. COMPONENT % EC Classification According to the Dir. 67/548 EC and 1999/45 EC Pyrethrins CAS No.: w/v Xn R20/21/22, R65,R43 N R50/53 According to the regulation 1272/2008/ΕC Danger, Acute inhalation tox. 4: H332 Skin irrit/ Category 2: H315, Eye irrit.category 2: H319 Skin sensitisation, 1: H317, Aspiration hazard, 1: H304 Chronic hazard to the aquatic environment Category 1: H FIRST-AID MEASURES Skin Contact: Causes mild irritation of the skin. Prolonged contact may cause redness. Wash the affected area with soap and water. Eye Contact: Causes severe irritation, experienced as discomfort or pain, excess blinking and tear production, redness, swelling, and chemical burn of the eye. Flush/irrigate eye with copious amounts of water for at least 10 minutes. Obtain medical attention if eyes irritation persists. Ingestion: Harmful if swallowed. Causes nausea and vomiting. Do not induce vomiting. Give water or milk to drink. Obtain medical attention if more than a small quantity has been swallowed. Inhalation: May cause temporal irritation to the respiratory truck. Remove to fresh air. Long term effects: No adverse effects are known.

3 5. FIRE-FIGHTING MEASURES 5.1 If the product is not directly involved in the fire Use the best means available to extinguish the fire. 5.2 If the product is involved in the fire When involved in a fire and exposed to extremely high temperatures, the components of this product can decompose to produce toxic smoke and vapors. Use foam, dry chemical or CO 2. NEVER USE WATER 6. ACCIDENTAL RELEASE MEASURES -If material is released or spilled the workers should wear eye and skin protection during handling with spillage. Floor may be slippery; use care to avoid falling. Contain spill immediately with inert materials (e.g. sand, earth). -Take care to avoid the contamination of water sources and drains and inform the appropriate authority in case of accidental contamination of water sources. 7. HANDLING AND STORAGE 7.1 Handling -Use with adequate ventilation. Wash thoroughly hands after handling. Keep away from heat, sparks and flames. - Avoid contamination by incompatible materials. - Avoid unnecessary exposure to the atmosphere. 7.2 Storage - Keep away from heat and sunlight. - Keep away from combustible materials and substances mentioned under Section On farm, ensure that the product is not stored near hay, straw, grain diesel oil, etc. - Ensure high standard of housekeeping in the storage area. 8. EXPOSURE CONTROL / PERSONAL PROTECTION 8.1 Occupational exposure limits No specific official limits. 8.2 Precautionary and engineering measures Avoid high mist concentration and provide ventilation where necessary. 8.3 Personal Protection Wear suitable gloves when handling the product over long periods. Wear goggles or safety glasses. After handling product, wash hands and observe good hygiene practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor ph Melting point Flash point Explosive properties Oxidizing properties Suspension Botanical aromatic 7 0,2 (1% dilution) Not applicable Non flammable Not explosive as per EC test A14 (67/548/EC). Not classed as an oxidizing material according to Directive 88/379/EC. Bulk weight 0.9 Kg/dm 3 Solubility in water Disperses readily in water to form an emulsion 10. STABILITY AND REACTIVITY 10.1 Stability The product is stable under normal conditions of storage, handling and use.

4 10.2 Conditions to avoid Contamination by incompatible materials. Intense heat and direct sunlight Materials to avoid Do not store with oxidizing agents 10.4 Hazardous polymerization: Will not occur 10.5 Hazardous Decomposition Products: When involved in a fire, the components of this product can decompose to produce dense irritating smoke and gases of carbon monoxide and dioxide, water vapor and unidentified organic compounds. 11. TOXICOLOGICAL INFORMATION 11.1 General See Section Toxicity Data Information on the active ingredient Acute LD50 (female) rat oral 2, 000 mg/kg Acute LD50 rat dermal > 5,000 mg/kg Acute LD50 rat inhalation > 2.02 mg/l (4h) 12. ECOLOGICAL INFORMATION 12.1 Mobility Pyrethrins are considered to show almost no mobility, as the adsorption rate by soil particles is greater than 95% Persistence /Degradability Not readily biodegradable but degrades progressively to simple organic molecules Bio-accumulation The product does not show any bio-accumulation phenomena Ecotoxicity This product itself and its products of degradation are not toxic under normal conditions of use. It is however expected to damage aquatic organisms as potential pollutant of water resources, ponds and lakes. Information on the active ingredient: Acute LDC50 (bobwhite quail) >2000 mg/kg Acute LC50 (flowthrough, bluegill sunfish) 10 μg/l (96h) Acute LC50 (flowthrough, Daphnia) 12 μg/l (48h) 13. DISPOSAL CONSIDERATIONS 13.1 General If uncontaminated, recover and reuse as product. If contaminated with other materials, the nature and extent of contamination may require use of specialized disposal methods. 14. TRANSPORT INFORMATION 14.1 UN classification Classified according to the criteria of the following international transport codes IATA (Air Transport), RID (rail), ADR (road) and IMDG (sea): Road ADR Railway (RID)

5 Sea (IMDG) Marine pollutant Air (ICAO/IATA) 15. REGULATORY INFORMATION 15.1 EC Directives Classification in accordance with the Directives 67/548 EC, the Directive 1999/45 EC and the Regulation 1272/2008/ΕC. 16. OTHER INFORMATION According to the Directive 67/548EC, the Directive 1999/45EC and the Regulation 1272/2008/ΕC the risk numbers mentioned in the paragraph 3.1 are provided by the following statements: N Dangerous for the environment Xn Harmfull R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R43 May cause sensitisation by skin contact. H332 Harmful if inhaled. H410 Very toxic to aquatic life with long lasting effects. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H304 May be fatal if swallowed and enters airways. The information in this Safety Data Sheet is given in good faith and belief in its accuracy based on our knowledge of the substance/preparation concerned at the date of publication. It does not imply the acceptance of any legal liability or responsibility whatsoever by the Company for the consequences of its use or misuse in any particular circumstances. Date of last issue: 3/6/2014