Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (, Canada). Material Safety Data Sheet Sulex 70. Product and company identification Product name Material uses Headquarters MSDS authored by In case of emergency Sulex 70 Treatment of plants. CHEMTRADE LOGISTICS 55 Gordon Baker Road Suite 300 Toronto, Ontario M2H 3N5 For MSDS Info (46) KMK Regulatory Services Inc. Canada CANUTEC US CHEMTREC Chemtrade Emergency Contact (866) Hazards identification Emergency overview Color Physical state Signal word Hazard statements Precautions Yellow. [Light] Liquid. CAUTION! MAY BE HARMFUL IF SWALLOWED. Do not ingest. Wash thoroughly after handling. OSHA/HCS status While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR ), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Routes of entry Eye contact. Inhalation. Ingestion. Potential acute health effects Inhalation Very hazardous by the following route of exposure of inhalation. May be fatal if inhaled. Ingestion May be harmful if swallowed. Skin Slightly irritating to the skin. Eyes Slightly irritating to the eyes. Potential chronic health effects Chronic effects No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Over-exposure signs/symptoms Inhalation No specific data. Ingestion No specific data. Skin No specific data. Eyes No specific data. Medical conditions None known. aggravated by overexposure KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. /7

2 2. Hazards identification See toxicological information (Section ) 3. Composition/information on ingredients Name CAS number % Sulfur Canada Name CAS number % Sulfur There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Protection of first-aiders Notes to physician 5. Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Hazardous thermal decomposition products Special protective equipment for fire-fighters Special remarks on fire hazards Special remarks on explosion hazards If irritation occurs, immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. Obtain medical attention IMMEDIATELY. Wash with soap and water. Cold water may be used. Get medical attention if irritation develops. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If potentially dangerous quantities of this material have been swallowed, call a physician immediately. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. No specific treatment. Medical staff must contact Posion Control Center. May be combustible at high temperature. SMALL FIRE Use dry chemical powder. LARGE FIRE Use water spray, fog or foam. Do not use water jet. Decomposition products may include the following materials sulfur oxides Be sure to use an approved/certified respirator or equivalent. Not available. Not available. KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 2/7

3 6. Accidental release measures Personal precautions Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Small spill Large spill 7. Handling Storage 8. Handling and storage Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Absorb with an inert material and transfer the spilled material and absorbent to an appropriate waste disposal container. Finish cleaning by flushing the contaminated surface with water and allowing it to run to the foul sewer. Dispose of according to all federal, state and local applicable regulations. Do not ingest. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Exposure controls/personal protection Ingredient Sulfur Canada Occupational exposure limits Exposure limits ACGIH TLV (). TWA 0 mg/m³ 8 hour(s). Form Nuisance dust. OSHA PEL (). TWA 5 mg/m³ 8 hour(s). Form Nuisance dust. TWA (8 hours) STEL (5 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations Sulfur US ACGIH [a] AB 4/ Form [a]nuisance dust. Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands Eyes Personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended A respirator is not needed under normal and intended conditions of product use. Use gloves appropriate for work or task being performed. Recommended Neoprene, PVC, vinyl or rubber. Safety eyewear should be used when there is a likelihood of exposure. Recommended Safety glasses with side shields. KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 3/7

4 8. Exposure controls/personal protection Skin Environmental exposure controls Lab coat. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Physical and chemical properties Physical state Color Liquid. Yellow. [Light] Molecular weight Molecular formula S 8 ph Neutral. Boiling/condensation point Not available. Specific gravity.5 Vapor pressure 2.3 kpa (7.5 mm 20 C Solubility Miscible in water. 0. Stability and reactivity Chemical stability Conditions to avoid Materials to avoid Hazardous decomposition products Possibility of hazardous reactions The product is stable. No specific data. Reactive or incompatible with the following materials oxidizing materials and acids. Decomposition products may include the following materials sulfur oxides (SO 2, SO 3 etc.) Under normal conditions of storage and use, hazardous reactions will not occur. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur.. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Sulfur LD50 Oral Rat >8437 mg/kg - Chronic toxicity No specific data. 2. Ecological information Environmental effects Not established Aquatic ecotoxicity Product/ingredient name Result Species Exposure Sulfur Acute EC50 >5000 ppm Fresh water Daphnia - Daphnia magna - <24 hours 48 hours Acute LC50 <4 ppm Fresh water Fish - Lepomis macrochirus 96 hours Toxicity of the products of biodegradation Products of degradation The products of biodegradation are more toxic than the original product. Products of degradation sulfur oxides (SO2, SO3 etc.). KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 4/7

5 3. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 4. Transport information DOT/TDG/IMDG/IATA Not regulated. 5. Regulatory information HCS Classification U.S. Federal regulations Clean Air Act Section 2(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) Not regulated. inventory (TSCA 8b) All components are listed or exempted. SARA 302/304/3/32 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/3/32 hazardous chemicals Sulfur SARA 3/32 MSDS distribution - chemical inventory - hazard identification Sulfur Fire hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 3 No products were found. Clean Air Act (CAA) 2 accidental release prevention No products were found. Clean Air Act (CAA) 2 regulated flammable substances No products were found. Clean Air Act (CAA) 2 regulated toxic substances No products were found. Not listed Not listed Not listed Not listed Not listed State regulations Connecticut Carcinogen Reporting None of the components are listed. Connecticut Hazardous Material Survey None of the components are listed. Florida substances None of the components are listed. Illinois Chemical Safety Act None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act None of the components are listed. Louisiana Reporting None of the components are listed. Louisiana Spill None of the components are listed. Massachusetts Spill None of the components are listed. Massachusetts Substances The following components are listed Sulfur Michigan Critical Material None of the components are listed. Minnesota Hazardous Substances None of the components are listed. KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 5/7

6 5. Regulatory information New Jersey Hazardous Substances The following components are listed Sulfur New Jersey Spill None of the components are listed. New Jersey Toxic Catastrophe Prevention Act None of the components are listed. New York Acutely Hazardous Substances None of the components are listed. New York Toxic Chemical Release Reporting None of the components are listed. Pennsylvania RTK Hazardous Substances The following components are listed Sulfur Rhode Island Hazardous Substances None of the components are listed. California Prop. 65 No products were found. Canada WHMIS (Canada) Canadian lists Not controlled under WHMIS (Canada). CEPA Toxic substances None of the components are listed. Canadian ARET None of the components are listed. Canadian NPRI None of the components are listed. Alberta Designated Substances None of the components are listed. Ontario Designated Substances None of the components are listed. Quebec Designated Substances None of the components are listed. Canada inventory All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. International regulations International lists Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals Australia inventory (AICS) All components are listed or exempted. China inventory (IECSC) All components are listed or exempted. Japan inventory Not determined. Korea inventory All components are listed or exempted. New Zealand Inventory of Chemicals (NZIoC) All components are listed or exempted. Philippines inventory (PICCS) All components are listed or exempted. Not listed Not listed Not listed 6. Other information Label requirements MAY BE HARMFUL IF SWALLOWED. Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards 0 KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 6/7

7 6. Other information Caution HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health 0 Flammability Instability Special References - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. ANSI Z400., MSDS Standard, Canada Gazette Part II, Vol. 22, No. 2. Registration SOR/88-64, 3 December 987. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Manufacturer's Material Safety Data Sheet. Date of issue 03/0/20 Date of previous issue /5/2009 Version 6 Notice to reader HANDLE PRODUCT WITH DUE CARE AND AVOID UNNECESSARY CONTACT. THIS INFORMATION IS SUPPLIED UNDER U.S. OSHA S RIGHT TO KNOW (29 CFR ) AND CANADA S WHMIS REGULATIONS. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THESE ARE THE ONLY HAZARDS THAT EXIST. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE BUT IT IS NOT OFFERED AS A PRODUCT SPECIFICATION. NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATA, THE HAZARDS CONNECTED WITH THE USE OF THE PRODUCT, OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, IS MADE AND CHEMTRADE AND ITS AFFILIATES ASSUME NO RESPONSIBILITY. CHEMTRADE IS A MEMBER OF THE CIAC (CHEMISTRY INDUSTRY ASSOCIATION OF CANADA) AND ADHERES TO THE CODES AND PRINCIPLES OF RESPONSIBLE CARE. KMK Regulatory Services Inc. Tel GHS-7769 ( )/+-450-GHS-7767 ( ); Services Réglementaires KMK Inc. 7/7