Risalah Data Keselamatan Safety data sheet

Transcription

1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/20 1. Pengenalan bahan kimia dan pembekal Irgazin Yellow K 2060 FP Nama bahan kimia: C.I. PIGMENT Yellow 110 Nombor CAS: Kegunaan: komponen pewarna Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini. Unsur label dan pernyataan berjaga-jaga: Produk tidak memerlukan label amaran bahaya menurut kriteria GHS. Bahaya lain yang tidak menyebabkan pengelasan: Produk di bawah keadaan tertentu boleh mengakibatkan letupan debu.

2 Mukasurat (Page): 2/20 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Isoindolinon 4. Langkah-Langkah Pertolongan Cemas Nasihat am: Tanggalkan pakaian yang tercemar. Jika tersedut: Jika kesukaran berlaku selepas tersedut debu, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan. Apabila terkena kulit: Basuh bersih-bersih dengan sabun dan air. Apabila terkena mata: Basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air sambil membuka mata. Apabila tertelan: Segera basuh mulut dan kemudian minum air yang banyak. Nota kepada doktor: Gejala: Tiada tindakbalas tubuh badan manusia yang ketara yang diketahui bagi produk ini. Nota kepada doktor: Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: serbuk kering, busa Alat memadam yang tidak sesuai untuk tujuan keselamatan: karbon dioksida Maklumat tambahan: Elakkan daripada memusarkan bahan/produk kerana bahaya letupan debu. Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap.

3 Mukasurat (Page): 3/20 Maklumat lanjut: Tahap risiko ditentukan oleh bahan yang terbakar dan keadaan kebakaran. Air pemadam api yang tercemar mestilah dilupuskan mengikut peraturan rasmi. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Elakkan pembentukan debu. Gunakan pakaian pelindung diri. Langkah berjaga-jaga untuk alam sekitar: Bendung air yang tercemar/air yang digunakan untuk memadam kebakaran. Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah kecil: Kutip dengan alat yang sesuai dan lupuskan. Bagi sejumlah besar: Bendung dengan bahan pengikat debu dan lupuskan. Elakkan pertambahan debu. 7. Pengendalian dan Penyimpanan; Pengendalian Pernafasan mestilah dilindungi apabila produk dalam jumlah yang banyak disiring tanpa pengalihudaraan ekzos setempat. Perlindungan terhadap kebakaran dan letupan: Elakkan pembentukan debu. Ambil langkah berjaga-jaga terhadap luahan statik. Penyimpanan Maklumat lanjut tentang keadaan penyimpanan: Pastikan bekas tertutup rapat dan kering; simpan di tempat yang dingin. 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja Tiada had pendedahan pekerjaan yang diketahui. Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan yang sesuai bagi kepekatan yang rendah atau kesan jangka pendek: Penapis zarah jenis kecekapan sederhana untuk zarah pepejal dan cecair (misalnya EN 143 atau 149, Jenis P2 atau FFP2)

4 Mukasurat (Page): 4/20 Perlindungan tangan: Sarung tangan keselamatan kalis bahan kimia. Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): misalnya getah nitril (0.4 mm), getah kloroprena (0.5 mm), polivinilklorida (0.7 mm) dan lain-lain. Nota tambahan : Spesifikasi adalah berdasarkan ujian ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian. Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai. Perlindungan mata: Kaca mata keselamatan dengan perlindungan sisi. Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Disebabkan ciri pewarna produk, pakaian kerja yang tertutup hendaklah digunakan untuk mengelakkan kesan pewarna semasa pengendalian bahan. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: nilai ph: serbuk kuning tidak berbau Tiada maklumat berkaitan diperoleh. Tidak boleh digunakan takat mengurai: > 400 C (Arahan 92/69/EEC, A.1) takat didih: Penguraian bahan / produk tidak ditentukan. Takat kilat: Tahap penyejatan: Tidak boleh digunakan Produk ini adalah pepejal tidak meruap Kemudahbakaran (pepejal/gas): tidak sangat mudah (Arahan 92/69/EEC, A.10) terbakar Had letupan bawah: Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal. Had letupan atas: Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal. Suhu pencucuhan: > 600 C (BAM) 510 C (BAM)

5 Mukasurat (Page): 5/20 pencucuhan sendiri: Suhu: 20 C Tidak swacucuh. Suhu: > 350 C Tekanan: 1, hpa Kebolehan swapemanasan sendiri: Ia bukanlah bahan yang mampu pemanasan spontan. Jenis ujian: Swanyalaan spontan pada suhu bilik. Jenis ujian: Pencucuhan sendiri pada suhu tinggi. (Kaedah: VDI 2263, helaian 1, 1.4.1) Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: Kepekatan: Ketumpatan pukal: tidak berkenaan, pepejal dengan suhu lebur melebihi 300 C 1.81 g/cm3 (20 C) 181 kg/m3 (Arahan 92/69/EEC, A.3) Keterlarutan dalam air: < 0.03 mg/l (20 C) Pekali petakan n-oktanol/air (log Pow): 0 (23 C) Tegangan permukaan: Berdasarkan struktur kimia, aktiviti permukaan adalah tidak dijangka. Kelikatan, dinamik: Tidak boleh digunakan Jisim molar: g/mol Maklumat lain: Jika perlu, maklumat tentang parameter fizikal and kimia ada dinyatakan didalam bahagian ini. 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Elakkan pembentukan debu. Elakkan pengumpulan debu. Jauhkan dari semua sumber pencucuhan: haba, percikan api, nyalaan terbuka. Elakkan cas elektrostatik. Bahan yang perlu dielakkan: agen pengoksida yang kuat, bes kuat, asid kuat

6 Mukasurat (Page): 6/20 Kakisan kepada logam: Tiada kesan mengakis pada logam Tindak balas berbahaya: Produk mungkin mengandungi debu halus boleh meletup atau debu tersebut mungkin dihasilkan melalui geseran semasa diangkut atau dipindah. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali ditelan. Tidak toksik selepas sekali terkena kulit Tidak toksik jika tersedut. Produk belum diuji sepenuhnya. Pernyataan diambil sebahagiannya daripada produk yang mempunyai struktur dan komposisi yang sama. Data eksperimen/dikira: LD50 tikus (melalui mulut): > 5,000 mg/kg Tiada kematian diperhatikan LC50 tikus (melalui penyedutan): > 1.04 mg/l 4 h Tiada kematian diperhatikan LD50 tikus (dermal): > 2,500 mg/kg Tiada kematian diperhatikan Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kerengsaan Penilaian kesan merengsa: Tidak merengsa kepada mata dan kulit. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: tidak merengsa (lain) Kerosakkan/kerengsaan mata yang serius arnab: tidak merengsa (lain) Pemekaan pernafasan/kulit Penilaian pemekaan: Bahan tidak menyebabkan pemekaan kulit pada manusia. Data eksperimen/dikira: manusia: Tidak memeka (Ujian Patch Manusia) Kemutagenan sel germa Penilaian kemutagenan:

7 Mukasurat (Page): 7/20 Dalam kebanyakkan ujian yang dijalankan (bakteria) kesan mutagen tidak Kekarsinogenan Penilaian kekarsinogenan: Tiada data diperoleh. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Keputusan kajian haiwan tidak menunjukkan kesan gangguan kesuburan. Keputusan telah ditentukan dalam Ujian Saringan (OECD 421/422). Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Ketoksikan perkembangan Penilaian keteratogenan: Dalam kajian haiwan, bahan ini tidak menyebabkan malformasi.. Keputusan telah ditentukan dalam Ujian Saringan (OECD 421/422). Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Pengambilan bahan dengan mulut secara berulang tidak menyebabkan kesan Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Bahaya penyedutan Tidak boleh digunakan Maklumat lain yang berkaitan dengan ketoksikan Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. 12. Maklumat Ekologi Keekotoksikan Penilaian ketoksikan akuatik: Ada kemungkinan besar produk tidak memudaratkan organisma akuatik secara akut. Tiada kesan toksik dalam julat keterlarutan. Perencatan aktiviti degradasi di dalam enap cemar yang diaktifkan

8 Mukasurat (Page): 8/20 tidak dijangka akan berlaku semasa bahan berkepekatan rendah dimasukkan kedalam loji rawatan biologi. Ketoksikan kepada ikan: LC50 (96 h) > 100 mg/l, Brachydanio rerio (Garispanduan OECD 203, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Invertebrat air: EC50 (48 h) > 100 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 1, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Tiada kesan toksik dalam julat keterlarutan. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Tumbuhan akuatik: EC50 (72 h) > 100 mg/l (kadar pertumbuhan), Desmodesmus subspicatus (Garispanduan OECD 201, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Produk mempunyai keterlarutan yang rendah dalam medium ujian. Larutan Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Tiada kesan kepekatan yang diperhatikan (72 h) >= 100 mg/l (kadar pertumbuhan), Desmodesmus subspicatus (Garispanduan OECD 201, statik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Produk mempunyai keterlarutan yang rendah dalam medium ujian. Larutan Ujian kepekatan had sahaja (ujian HAD). Tiada kesan toksik dalam julat keterlarutan. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC20 (30 min) dianggarkan 810 mg/l, Enap cemar diaktifkan, domestik (Garispanduan OECD 209, aerobik) Perincian kesan toksik berkaitan dengan kepekatan nominal. Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Ketoksikan kronik kepada ikan: Tiada data diperoleh tentang ketoksikan kepada ikan. Ketoksikan kronik kepada invertebrata akuatik: Tiada data diperoleh tentang ketoksikan kepada daphnid. Penilaian ketoksikan daratan: Organisma hidupan tanah: Tiada kesan kepekatan yang diperhatikan (14 hari) >= 1,000 mg/kg, Eisenia foetida (Garispanduan OECD 207, Tanah tiruan) Perincian kesan toksik berkaitan dengan kepekatan nominal. Ujian kepekatan had sahaja (ujian HAD). Tumbuhan darat: Tiada data diperoleh.

9 Mukasurat (Page): 9/20 Bukan-mamalia darat lain: Tiada data diperoleh. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Penjerapan kepada fasa tanah pejal tidak dijangka Keterusan dan boleh keterdegradasikan Maklumat penyingkiran: 5.46 % BOD bagi COD (28 hari) (dikira) (aerobik, enap cemar diaktifkan, domestik, tidak disesuaikan) Penilaian kestabilan dalam air: Tiada data diperoleh. Potensi Biotumpukan Penilaian potensi bioakumilasi: Tiada akumulasi yang ketara dalam organisma dijangka hasil daripada pekali pengagihan n- oktanol/air (log Pow). Potensi Biotumpukan: Tiada data diperoleh. Kesan buruk lain Halogen terikat secara organik boleh terjerap (AOX): 44.2 % Maklumat tentang : chlorine Maklumat tambahan Nasihat ekotoksikologi lain: Jangan lepaskan produk ke persekitaran tanpa kawalan. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya. 14. Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan

10 Mukasurat (Page): 10/20 pengangkutan Pengangkutan laut IMDG Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan 16. Maklumat lain Terhad kepada pengguna profesional. Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

11 Mukasurat (Page): 11/20 1. Identification of the chemical and of the supplier Irgazin Yellow K 2060 FP Chemical name: C.I. PIGMENT Yellow 110 CAS Number: Use: colouring component Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: The product is under certain conditions capable of dust explosion. 3. Composition/information on ingredients Chemical nature Isoindolinone 4. First-Aid Measures General advice: Remove contaminated clothing.

12 Mukasurat (Page): 12/20 If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant reaction of the human body to the product known. Note to physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

13 Mukasurat (Page): 13/20 Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust. 7. Handling and Storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Storage Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Due to the colouring properties of the product closed work clothes should be used, to avoid stains during manipulation.

14 Mukasurat (Page): 14/20 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: powder yellow odourless No applicable information available. not applicable decomposition point: > 400 C (Directive 92/69/EEC, A.1) Boiling point: The substance / product decomposes therefore not determined. Flash point: Evaporation rate: not applicable The product is a non-volatile solid. Flammability (solid/gas): not highly flammable (Directive 92/69/EEC, A.10) Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: > 600 C (BAM) 510 C (BAM) Self ignition: Temperature: 20 C not self-igniting Test type: Spontaneous selfignition at room-temperature. Self heating ability: Temperature: > 350 C Pressure: 1, hpa It is not a substance capable of spontaneous heating. Test type: Self-ignition at high temperatures. (Method: VDI 2263, sheet 1, 1.4.1) Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: Density: Bulk density: not applicable, solid with a melting temperature over 300 C 1.81 g/cm3 (20 C) 181 kg/m3 (Directive 92/69/EEC, A.3)

15 Mukasurat (Page): 15/20 Solubility in water: < 0.03 mg/l (20 C) Partitioning coefficient n-octanol/water (log Pow): 0 (23 C) Surface tension: Based on chemical structure, surface activity is not to be expected. Viscosity, dynamic: not applicable Molar mass: g/mol Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static charge. Substances to avoid: strong oxidizing agents, strong bases, strong acids Corrosion to metals: No corrosive effect on metal. Hazardous reactions: The product may contain explosive fine dust or such dust may be produced by abrasion during transport or product transfer. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg (similar to OECD guideline 401) No mortality was observed. LC50 rat (by inhalation): > 1.04 mg/l 4 h (similar to OECD guideline 403) No mortality was observed.

16 Mukasurat (Page): 16/20 LD50 rat (dermal): > 2,500 mg/kg (similar to OECD guideline 402) No mortality was observed. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Irritation Assessment of irritating effects: Not irritating to eyes and skin. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (other) Serious eye damage/irritation rabbit: non-irritant (other) Respiratory/Skin sensitization Assessment of sensitization: The substance did not cause skin sensitization in humans. Experimental/calculated data: human: Non-sensitizing. (Human patch test) Germ cell mutagenicity Assessment of mutagenicity: In the majority of tests performed (bacteria) a mutagenic effect was not found. A mutagenic effect was also not observed in in-vivo assays. Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. The results were determined in a Screening test (OECD 421/422). The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Developmental toxicity Assessment of teratogenicity: In animal studies the substance did not cause malformations. The results were determined in a Screening test (OECD 421/422). The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

17 Mukasurat (Page): 17/20 Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Repeated oral uptake of the substance did not cause substance-related effects. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aspiration hazard not applicable Other relevant toxicity information The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. No toxic effects occur within the range of solubility. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish: LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD Guideline 203, static) The details of the toxic effect relate to the nominal concentration. Limit concentration test only (LIMIT test). No toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aquatic invertebrates: EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The details of the toxic effect relate to the nominal concentration. No toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aquatic plants: EC50 (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. Limit concentration test only (LIMIT test). No toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. No observed effect concentration (72 h) >= 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. Limit concentration test only (LIMIT test). No

18 Mukasurat (Page): 18/20 toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Microorganisms/Effect on activated sludge: EC20 (30 min) approx. 810 mg/l, activated sludge, domestic (OECD Guideline 209, aerobic) The details of the toxic effect relate to the nominal concentration. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Chronic toxicity to fish: No data available regarding toxicity to fish. Chronic toxicity to aquatic invertebrates: No data available regarding toxicity to daphnids. Assessment of terrestrial toxicity: Soil living organisms: No observed effect concentration (14 d) >= 1,000 mg/kg, Eisenia foetida (OECD Guideline 207, artificial soil) The details of the toxic effect relate to the nominal concentration. Limit concentration test only (LIMIT test). Terrestrial plants: No data available. Other terrestrial non-mammals: No data available. Mobility Assessment transport between environmental compartments: Adsorption to solid soil phase is not expected. Persistence and degradability Elimination information: 5.46 % BOD of COD (28 d) (calculated) (aerobic, activated sludge, domestic, non-adapted) Assessment of stability in water: No data available. Bioaccumulation potential Assessment bioaccumulation potential: No significant accumulation in organisms is expected as a result of the distribution coefficient of n- octanol/water (log Pow). Bioaccumulation potential: No data available. Other adverse effects Adsorbable organically-bound halogen (AOX): 44.2 %

19 Mukasurat (Page): 19/20 Information on: chlorine Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information

20 Mukasurat (Page): 20/ Other Information Restricted to professional users. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.