: Kalium, Muriat Kalium, Sylvite

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1 Kalium, Muriat Kalium, Sylvite BAHAN KIMIA TIDAK BERBAHAYA. RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA YANG BERIKUT: Peraturan (EC) No. 453/2010; US 29CFR ; Peraturan Produk Terkawal Kanada; Piawaian Industri Jepun JIS Z 7253:2012; Pemakluman Awam Kementerian Pekerjaan dan Buruh Korea No ; China GBT ; Malaysia P.U. (A) 143/1997. Tarikh dikeluarkan: 27/03/2018 Versi: 1.1 SEKSYEN 1: Tanda pengenalan bahan/campuran dan syarikat/pembuat 1.1. Pengenalpastian produk Bentuk produk Nama dagang : Bahan No.-CAS : : Kalium, Muriat Kalium, Sylvite 1.2. Penggunaan yang dikenal pasti relevan bagi bahan atau campuran dan yang tidak digalakkan Penggunaan yang dikenal pasti relevan Fungsi atau kategori penggunaan Penggunaan-penggunaan yang tidak digalakkan Tiada maklumat tambahan didapati 1.3. Butir-butir pembekal lembaran data keselamatan Canpotex, Limited #400, 111-2nd Avenue South Saskatoon, Saskatchewan Canada S7K 3R7 T - +1 (306) :30-16:30 CST : Baha. Proses dan kegunaan industri 1.4. Nombor panggilan kecemasan Nombor kecemasan : Bahan tidak berbahaya. Peraturan yang berkaitan dengan nombor gerak balas kecemasan mengikut negara tidak diguna pakai. Gunakan nombor telefon syarikat Canpotex untuk maklumat lanjut. SEKSYEN 2: Bahaya yang mungkin terjadi 2.1. Klasifikasi bahan atau campuran Pengelasan menurut GHS Tak terkelas Kesan buruk kepada fisikokimia, kesihatan manusia dan alam sekitar Tidak memberi kesan buruk kepada kesihatan atau alam sekitar dijangka akan berlaku dengan penggunaan di bawah keadaan biasa Elemen-elemen label Pelabelan menurut GHS Pelabelan tidak berkenaan 2.3. Lain-lain bahaya Bahan/campuran ini tidak memenuhi kriteria PBT peraturan REACH lampiran XIII Bahan/campuran ini tidak memenuhi kriteria vpvb peraturan REACH lampiran XIII Bahaya lain yang tidak membawa kepada klasifikasi : Tiada di bawah keadaan biasa. SEKSYEN 3: Komposisi/maklumat tentang bahan-bahan 3.1. Bahan-bahan Jenis bahan Nama : Mono-juzuk : Kalium klorida Nama Pengenalpastian produk % Pengelasan menurut GHS Kalium klorida (No.-CAS) (No.-EC) (No.- KE) KE Jepun CSCL #1-228 Natrium klorida (No.-CAS) (No.- EC) (No.- KE) KE Jepun CSCL # Campuran Tidak berkaitan Tak terkelas Tak terkelas 27/03/2018 MS (Bahasa Melayu) SDS Ruj.: Canpotex_kcl_ /16

2 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA SEKSYEN 4: Langkah-langkah bantuan kecemasan 4.1. Langkah-langkah bantuan kecemasan Pertolongan cemas selepas penyedutan Pertolongan cemas selepas terkena kulit Pertolongan cemas selepas terkena mata Pertolongan cemas selepas tertelan 4.2. Gejala dan kesan paling penting, akut dan tertunda Gejala/luka selepas penyedutan Gejala/luka selepas terkena kulit Gejala/luka selepas terkena mata Gejala/luka selepas tertelan : Jika dihidu dan jika bernafas sukar, keluarkan mangsa ke udara bersih dan biarkan berehat dalam kedudukan yang selesa untuk bernafas. : Tidak dijangka membentangkan bahaya kulit yang ketara di bawah syarat-syarat yang dijangka daripada penggunaan biasa. Bersihkan kulit daripada zarah bebas. Basuh perlahan-lahan dengan sabun dan air yang banyak. : SEKIRANYA TERKENA MATA: Basuh berhati-hati dengan air selama beberapa minit. Keluarkan kanta lekap sekiranya boleh. Basuh lagi. : Tidak dijangka membentangkan bahaya pemakanan yang ketara di bawah syarat-syarat yang dijangka daripada penggunaan biasa. : Jika tersedut boleh menyebabkan: kerengsaan, batuk, sesak nafas : Tiada tanda-tanda atau gejala signifikan menunjukkan sebarang bahaya kesihatan dijangka akan berlaku jika terkena kulit. : Tiada tanda-tanda atau gejala signifikan menunjukkan sebarang bahaya kesihatan yang buruk dijangka akan berlaku jika mata terdedah kepada bahan. : Seperti mana-mana produk yang tidak direka untuk ditelan, produk ini boleh menyebabkan perut sakit jika ditelan dalam kuantiti yang besar Tanda sebarang perhatian perubatan segera dan rawatan khas yang diperlukan Semua rawatan perlu berdasarkan tanda-tanda dan gejala kesusahan dalam pesakit yang diperhatikan. SEKSYEN 5: Langkah-langkah membasmi kebakaran 5.1. Jenis pemadam yang sesuai Jenis pemadam yang sesuai Media pemadam tidak sesuai : Gunakan media pemadaman yang sesuai untuk kebakaran di sekeliling : Tiada yang diketahui Bahaya khas bahaya yang timbul daripada bahan atau campuran Bahaya kebakaran 5.3. Nasihat untuk anggota bomba Perlindungan semasa kebakaran : Tiada bahaya kebakaran atau letupan yang tertentu Langkah-langkah keselamatan berkaitan orang perseorangan Untuk bukan pasukan penyelamat Tiada maklumat tambahan didapati Untuk pasukan penyelamat Peralatan pelindung 6.2. Langkah-langkah perlindungan alam sekitar Halang daripada memasuki pembetung dan takungan air awam Kaedah dan bahan-bahan untuk pembendungan dan pembersihan Langkah-langkah pembersihan : Jangan memasuki kawasan api tanpa peralatan perlindungan yang betul, termasuk perlindungan pernafasan. Pakai alat pernafasan bebas yang. Pakai api / api pakaian tahan / perencat. EN469. SEKSYEN 6: Langkah-langkah apabila berlaku kebocoran yang tidak disengajakan 6.4. Rujukan kepada seksyen lain Rujukan kepada bahagian lain (8, 13). SEKSYEN 7: Pengendalian dan penyimpanan 7.1. Langkah berjaga-jaga untuk pengendalian yang selamat Langkah-langkah kebersihan : Elakkan semua sentuhan pada mata dan kulit dan jangan sedut wap dan kabut. : Sentiasa berada di arah hadap angin. Kumpul tumpahan. Tumpahan besar: kaup tumpahan pepejal dan masukkan ke dalam bekas bertutup. Kurangkan penjanaan habuk. : Sentiasa basuh tangan anda serta-merta selepas mengendalikan produk ini, dan basuh sekali lagi sebelum meninggalkan tempat kerja Keadaan yang perlu untuk memastikan penyimpanan selamat, termasuk perhatian kepada sebarang ketidakserasian Syarat-syarat penyimpanan Bahan-bahan pembungkusan 7.3. Penggunaan(-penggunaan) akhir khusus Baha. Proses dan kegunaan industri. : Simpan di tempat yang dialihudarakan dengan baik. Simpan di tempat sejuk. Simpan di dalam bekas bertutup. Simpan di tempat kering. : Jangan simpan di dalam bekas logam yang boleh kakis: aluminium, keluli karbon. 27/03/2018 MS (Bahasa Melayu) EN (English) 2/16

3 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA SEKSYEN 8: Kawalan pendedahan/perlindungan diri 8.1. Parameter kawalan Kalium, Muriat Kalium, Sylvite ( ) sebagai debu/zarah lengai Total yang tidak dikawal selia China GBZ FR - Ministère du Travail IT - Associazone Italiana Degli Igienisti Industriali Netherlands - Ministerie van Sociale Zaken en Werkgelegenheid Saskatchewan 容许浓度时间加权平均 Kepekatan Dibenarkan (PC) Valeur limite de Moyenne d Exposition (Nilai Had Pendedahan Tempat Kerja) Valori limite (sulla base di ACGIH TLVs) (Nilai Had Ambang (berdasarkan TLV ACGIH)) Maximaal Aanvarde Concentratie (MAC) (Kepekatan Maksimum Dibenarkan (MAC)) CAD SK OEL (Had Pendedahan Pekerjaan di Saskatchewan, Canada.) 8 mg/m³ TWA 5 mg/m³ TWA 3 mg/m³ TWA 5 mg/m³ TWA 10 mg/m³ TWA boleh disedut 3 mg/m³ TWA peringkat boleh sedut UK - Health & Safety Executive Had Pendedahan Tempat Kerja (WEL) 4 mg/m³ TWA US - OSHA Had Pendedahan Dibenarkan (PEL) 15 mg/m³ TWA boleh disedut 5 mg/m³ TWA peringkat boleh sedut Kalium klorida ( ) DNEL/DMEL (Pekerja) Akut - kesan sistemik, kulit Akut - kesan sistemik, penyedutan Jangka panjang - kesan sistemik, kulit Jangka panjang - kesan sistemik, penyedutan DNEL/DMEL (General population) Akut - kesan sistemik, kulit Akut - kesan sistemik, penyedutan Akut - kesan sistemik, lisan Jangka panjang - kesan sistemik, lisan Jangka panjang - kesan sistemik, penyedutan Jangka panjang - kesan sistemik, kulit PNEC (Air) PNEC aqua (air tawar) PNEC aqua (air laut) PNEC aqua (terputus-putus, air tawar) PNEC (STP) PNEC loji rawatan kumbahan Natrium klorida ( ) DNEL/DMEL (Pekerja) Akut - kesan sistemik, kulit Akut - kesan sistemik, penyedutan Jangka panjang - kesan sistemik, kulit Jangka panjang - kesan sistemik, penyedutan DNEL/DMEL (General population) Akut - kesan sistemik, kulit Akut - kesan sistemik, penyedutan Akut - kesan sistemik, lisan Jangka panjang - kesan sistemik, lisan Jangka panjang - kesan sistemik, penyedutan Jangka panjang - kesan sistemik, kulit 910 mg/kg hari 5320 mg/m³ 303 mg/kg hari 1064 mg/m³ 910 mg/kg hari 1365 mg/m³ 455 mg/kg hari 91 mg/kg hari 273 mg/m³ 182 mg/kg hari 0.1 mg/l 0.1 mg/l 1 mg/l 10 mg/l 296 mg/kg hari 2069 mg/m³ 296 mg/kg hari 2069 mg/m³ 127 mg/kg hari 443 mg/m³ 127 mg/kg hari 127 mg/kg hari 443 mg/m³ 127 mg/kg hari 27/03/2018 MS (Bahasa Melayu) EN (English) 3/16

4 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA 8.2. Kawalan pendedahan Kawalan kejuruteraan yang sesuai Perlindungan tangan Perlindungan mata Perlindungan kulit dan badan Perlindungan saluran pernafasan : Elakkan penyebaran debu di udara (iaitu, penjelasan permukaan debu dengan udara mampat). Memberi ekzos tempatan atau pengudaraan bilik umum untuk mengurangkan pendedahan kepada habuk. : Sarung tangan kulit. EN374 : Kaca mata keselamatan. Jika terjadi debu: gogal pelindung. EN166 : Pakaian kedap : Gunakan alat pernafasan menulen udara dilengkapi dengan kartrij zarah penapisan. Di mana pendedahan melalui pernafasan mungkin berlaku daripada penggunaan, peralatan perlindungan pernafasan yang disarankan. EN 136/140 SEKSYEN 9: Ciri-ciri fizikal dan kimia 9.1. Maklumat penting tentang sifat-sifat fizikal dan kimia Bentuk jirim Rupa Jisim molekul Warna Bau Had bau ph : Pepejal : Untilan kering boleh serak : 74.6 g/mol : Putih ke merah/coklat : Tidak berbau atau berbau sedikit larutan ph : 5% (5.4-10) Kadar penyejatan relatif (butil asetat=1) Takat cair / julat cair : C Titik beku : C Takat didih Punca pancaran api Suhu swanyalaan Suhu penguraian Kemudahbakaran (pepejal, gas) tekanan wap Ketumpatan wap relatif pada 20 C : Tidak mudah bakar Ketumpatan relatif : Air = 1 Ketumpatan Kelarutan Log Pow Log Kow kepekatan, kinematik Kepekatan, dinamik Ciri-ciri letupan Sifat-sifat pengoksidaan Had letupan 9.2. Lain-lain maklumat : kg/m³ (Ketumpatan pukal) : Terlarut di dalam air. Air: % : Ciri letupan debu: <63µm; kemudahan letupan: St 1; tenaga pencucuhan minimum (mj): Tidak Berkenaan. Takat pemejalwapan : C Kandungan VOC : < 0.5 % maklumat tambahan SEKSYEN 10: Kestabilan dan kereaktifan Kereaktifan Asid kuat Kestabilan kimia Stabil dalam keadaan biasa Kemungkinan tindak balas berbahaya Pempolimeran berbahaya tidak akan berlaku. : Serupa dengan garam, mungkin mengkakis sesetengah logam apabila ada kelembapan. 27/03/2018 MS (Bahasa Melayu) EN (English) 4/16

5 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA Keadaan yang perlu dielakkan Bahan tidak serasi Bahan tidak serasi Asid kuat, boron triklorida, boron trifluorida, kalium dikromat, kalium permanganat, asid sulfurik Produk penguraian merbahaya Tiada hasil penguraian berbahaya yang diketahui. SEKSYEN 11: Maklumat tentang ketoksikan Maklumat tentang kesan ketoksikan Ketoksikan akut Kalium klorida ( ) LD50 mulut tikus Natrium klorida ( ) LD50 mulut tikus Kulit tikus LD50 LC50 penyedutan tikus (mg/l) LC50 penyedutan tikus (Kabus/Debu - mg/l/4jam) Kakisan/radang kulit Kerosakan/radang mata yang serius Saluran pernafasan atau kulit menjadi peka Sel kuman mutagen Karsinogen Ketoksikan pembiakan Ketoksikan organ sasaran khusus (pendedahan sekali) Ketoksikan organ sasaran khusus (pendedahan berulang kali) Bahaya resapan Gejala/luka selepas penyedutan Gejala/luka selepas terkena kulit Gejala/luka selepas terkena mata Gejala/luka selepas tertelan Kemungkinan cara pendedahan 3020 mg/kg 3550 mg/kg > mg/kg > 42 mg/l/4h 1 jam 10.5 mg/l/4jam : Jika tersedut boleh menyebabkan: kerengsaan, batuk, sesak nafas : Tiada tanda-tanda atau gejala signifikan menunjukkan sebarang bahaya kesihatan dijangka akan berlaku jika terkena kulit. : Tiada tanda-tanda atau gejala signifikan menunjukkan sebarang bahaya kesihatan yang buruk dijangka akan berlaku jika mata terdedah kepada bahan. : Seperti mana-mana produk yang tidak direka untuk ditelan, produk ini boleh menyebabkan perut sakit jika ditelan dalam kuantiti yang besar. : Dermis; Tersedut SEKSYEN 12: Maklumat ekologi Ketoksikan Kalium klorida ( ) LC50 ikan 1 EC50 Dafnia 1 ErC50 (ganggang) NOEC (kronik) Natrium klorida ( ) LC50 ikan 1 EC50 Dafnia 1 NOEC (akut) NOEC kronik ikan 880 mg/l Pimephales promelas 96 jam jam > 100 mg/l 500 mg/l 7 hari 5840 mg/l 96 jam; Lepomis macrochirus 4136 mg/l 48 jam 1500 mg/l Dafnia; 7 hari 252 mg/l 33 hari Butir-butir tentang pelupusan Tiada maklumat tambahan didapati Keupayaan/potensi pengumpulan bio Tiada maklumat tambahan didapati 27/03/2018 MS (Bahasa Melayu) EN (English) 5/16

6 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA Pergerakan di dalam tanah Kalium, Muriat Kalium, Sylvite( ) Ekologi - tanah Komponen campuran ini larut sepenuhnya di dalam air. Sekatan kepada tanah Hasil penilaian PBT dan vpvb Kalium, Muriat Kalium, Sylvite( ) Bahan/campuran ini tidak memenuhi kriteria PBT peraturan REACH lampiran XIII Bahan/campuran ini tidak memenuhi kriteria vpvb peraturan REACH lampiran XIII Kesan-kesan berbahaya yang lain Tiada maklumat tambahan didapati SEKSYEN 13: Langkah-langkah pelupusan Kaedah rawatan sisa Kaedah rawatan sisa Cadangan pelupusan sisa Kod katalog bahan sisa Eropah (EWC) SEKSYEN 14: Maklumat pengangkutan Mengikut kehendak daripada ADR / RID / ADNR / IMDG / IATA No.UN Bukan bahan yang berbahaya mengikut undang-undang pengangkutan : Ambil semua langkah berjaga-jaga yang perlu bagi mengelakkan produk terlepas dengan tidak sengaja ke longkang dan alur alir akibat bekas pecah atau sistem pemindahan : Melupuskan dengan cara yang selamat mengikut peraturan-peraturan tempatan / kebangsaan. : Bagi pelupusan di dalam EC, kod yang sesuai menurut European Waste Catalogue (Katalog Sisa Eropah- EWC) hendaklah digunakan Arahan rasmi untuk pengangkutan Arahan rasmi untuk pengangkutan (ADR) Arahan rasmi untuk pengangkutan (IMDG) Arahan rasmi untuk pengangkutan (IATA) Arahan rasmi untuk pengangkutan (ADN) Arahan rasmi untuk pengangkutan (RID) Kelas(-kelas) bahaya pengangkutan ADR Kelas(-kelas) bahaya pengangkutan (ADR) IMDG Kelas(-kelas) bahaya pengangkutan (IMDG) IATA Kelas(-kelas) bahaya pengangkutan (IATA) ADN Kelas(-kelas) bahaya pengangkutan (ADN) RID Kelas(-kelas) bahaya pengangkutan (RID) Kumpulan pembungkus Kumpulan pembungkusan (ADR) Kumpulan pembungkusan (IMDG) Kumpulan pembungkusan (IATA) Kumpulan pembungkusan (ADN) Kumpulan pembungkusan (RID) Bahaya-bahaya kepada alam sekitar Berbahaya kepada persekitaran Pencemar laut Lain-lain maklumat : Tak : Tak : Tidak ada maklumat tambahan didapati Peringatan khas bagi pengguna Tidak berkaitan Pengangkutan secara pukal mengikut Lampiran II MARPOL 73/78 dan Kod IBC Tidak berkaitan 27/03/2018 MS (Bahasa Melayu) EN (English) 6/16

7 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA SEKSYEN 15: Maklumat pengawalseliaan Peraturan/undang-undang keselamatan, kesihatan dan persekitaran khusus untuk bahan atau campuran Undang-undang EU Tiada sekatan mengikut Lampiran REACH XVII Kalium, Muriat Kalium, Sylvitetiada di dalam kriteria senarai REACH Kalium, Muriat Kalium, Sylvitetiada di dalam Lampiran XIV senarai REACH Kandungan VOC : < 0.5 % Jerman VwVwS, Rujukan Lampiran : Kelas bahaya kepada air (WGK) 1, pencemar air yang lembut (Klasifikasi mengikut VwVwS, Lampiran 2) Peraturan-peraturan tempatan Semua komponen adalah tersenarai pada inventori EEC, Inventori Eropah Bagi Bahan Kimia Komersial Sedia Ada (EINECS). Semua ramuan adalah tersenarai pada Senarai Bahan Domestik (DSL). Semua ramuan adalah tersenarai pada Inventori Akta Kawalan Bahan Toksik (TSCA). Tersenarai pada IECSC (Inventori Bahan Kimia Sedia Ada yang Dikeluarkan atau Diimport di China) Tersenarai pada KECI (Inventori Bahan Kimia Sedia Ada Korea) Tersenarai pada inventori ENCS Jepun (Inventori Bahan Kimia Sedia Ada & Baharu) Amerika Syarikat Peraturan Produk ini telah dikaji semula menurut Kategori Bahay Agensi Perlindungan Alam Sekitar ("EPA") yang diisytiharkan di bawah Seksyen 311 dan 312 Akta Pindaan dan Pemberian Kebenaran Superfund 1986 (SARA tajuk III) dan dianggap, di bawah definisi terpakai, memenuhi yang berikut:: Kebakaran: Tidak; Penjanaan Tekanan: Tidak; Reaktiviti: Tidak; Akut: Tidak; Kronik: Tidak 40 CFR Bahagian 355 Bahan Berbahaya Ekstrim: Tiada 40 CFR Bahagian 370 Laporan Kimia Berbahaya: Tiada CERCA/ RCRA Tiada Penilaian tahap keselamatan bahan Tiada maklumat tambahan didapati SEKSYEN 16: Lain-lain maklumat Keterangan mengenai perubahan: Tarikh semakan: 27/03/2018 Tarikh dokumen asal terbitan: 06/04/2015 ACGIH ADR ADN ATE CAS CERCA CFR CLP CSCL DMEL DNEL EC EC50 EURLW GBT GHS IATA IBC IMDG KECI LD50 ACGIH (Persidangan Juruhigin Industri Kerajaan Amerika) Perjanjian Eropah berkenaan Pengangkutan Antarabangsa Barang Berbahaya melalui Jalan Raya Perjanjian Eropah berkenaan Pengangkutan Antarabangsa Barang Berbahaya melalui Laluan Air Pedalaman Anggaran Ketoksikan Akut Nombor CAS (Perkhidmatan Sari Kimia) Akta Gerak Balas Persekitaran, Pampasan & Liabiliti Komprehensif Kod Peraturan Persekutuan Pengelasan dan Pelabelan Bahan Kimia Undang-undang Kawalan Bahan Kimia Jepun Paras Kesan Minimum yang Dirumuskan Paras Tiada Kesan yang Dirumuskan Kesatuan Eropah Kepekatan berkesan median Kod katalog bahan sisa Eropah Piawaian Kebangsaan China Sistem Terharmoni Global (Klasifikasi dan Pelabelan Bahan Kimia). Persatuan Pengangkutan Udara Antarabangsa Bekas Pukal Pertengahan Barang Bahaya Maritim Antarabangsa Inventori Bahan Kimia Sedia ada Korea Dos Maut untuk 50% daripada populasi ujian MARPOL Konvensyen Antara Bangsa Pencegahan Pencemaran daripada Kapal, 1973 seperti pindaan mengikut Protokol /03/2018 MS (Bahasa Melayu) EN (English) 7/16

8 Kalium, Muriat Kalium, Sylvite RISALAH DATA KESELAMATAN TIDAK DIPERLUKAN OLEH PERATURAN ANTARA BANGSA NOEC OSHA PBT PNEC RCRA Tiada Kepekatan Boleh Diperhatikan Pentadbiran Keselamatan dan Kesihatan Pekerjaan Bertahan Menumpuk Secara Biologi Toksik Paras Tiada Kesan Diramalkan Akta Pemuliharaan dan Pemulihan Sumber REACH Pendaftaran, Penilaian, Kebenaran dan Pengehadan Peraturan Bahan Kimia (EC) No 1907/2006 RID SDS TSCA TWA vpvb VOC Perundangan berkenaan Pengangkutan Antarabangsa Barang Berbahaya melalui Kereta Api Akta Kawalan Bahan Toksik Purata Berwajaran Masa Sangat Bertahan dan Sangat Menumpuk Secara Biologi Sebatian Organik Meruap Sumber data : ACGIH (Persidangan Juruhigin Industri Kerajaan Amerika) Pusat Kesihatan dan Keselamatan Pekerjaan Kanada. Boleh dicapai di: China GBZ Had pendedahan pekerjaan untuk agen berbahaya di tempat kerja: Agen berbahaya kimia. Senarai Bahan Berdaftar Agensi Bahan Kimia Eropah (ECHA) Persatuan Perlindungan Kebakaran Kebangsaan. Panduan Perlindungan Kebakaran untuk Bahan Berbahaya; edisi ke-10. Organisasi Kerjasama dan Pembangunan Ekonomi (OECD; carian kimia echemportal. Boleh dicapai di Kaedah pengelasan yang digunakan: data komponen Bahaya kesihatan NFPA Bahaya kebakaran NFPA Reaktiviti NFPA : 0 - Pendedahan dalam keadaan api akan menawarkan tidak lebih dari itu bahaya bahan-bahan mudah terbakar biasa. : 0 - Bahan-bahan yang tidak akan terbakar. : 0 - Biasanya stabil, walaupun di bawah keadaan pendedahan kebakaran, dan tidak reaktif dengan air Asal SDS disediakan oleh: The Redstone Group, LLC 6077 Frantz Rd. Suite 206 Dublin, OH USA T Maklumat ini adalah berdasarkan pengetahuan semasa kami dan keterangan produk diberikan semata-mata untuk tujuan kesihatan, keselamatan dan persekitaran. Ia tidak harus dianggap sebagai menjamin sebarang sifat tertentu produk 27/03/2018 MS (Bahasa Melayu) EN (English) 8/16

9 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY THE FOLLOWING INTERNATIONAL REGULATIONS: Regulation (EC) No. 453/2010; US 29CFR ; Canadian Controlled Products Regulation; Japanese Industrial Standard JIS Z 7253:2012; Korean Ministry of Employment and Labor Public Notice No ; China GBT ; Malaysia P.U. (A) 143/1997. Date of issue: 27/03/2018 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Substance CAS No : : Potash, Muriate of Potash, Sylvite 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Canpotex, Limited #400, 111-2nd Avenue South Saskatoon, Saskatchewan Canada S7K 3R7 T - +1 (306) :30-16:30 CST : Fertilizer. Industrial processings & uses Emergency telephone number Emergency number : Non-hazardous material. Regulations that pertain to country specific emergency response numbers do not apply. Use Canpotex company phone number for additional information. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to GHS Not classified Adverse physicochemical, human health and environmental effects No adverse health or environmental effects are expected to occur as a result of normal conditions of use Label elements Labelling according to GHS No labeling applicable 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH, annex XIII. This substance/mixture does not meet the vpvb criteria of REACH, annex XIII. Other hazards not contributing to the classification : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substances Substance type Name : Mono-constituent : Potassium chloride Name Product identifier % Classification according to GHS Potassium chloride (CAS No) (EC no) (KE no) KE Japan CSCL #1-228 Sodium chloride (CAS No) (EC no) (KE no) KE Japan CSCL # Not classified Not classified 27/03/2018 MS (Bahasa Melayu) SDS Ruj.: Canpotex_kcl_ /16

10 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. : Not expected to present a significant skin hazard under anticipated conditions of normal use. Brush off loose particles from skin. Gently wash with plenty of soap and water. : If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Not expected to present a significant ingestion hazard under anticipated conditions of normal use Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Inhalation may cause: irritation, coughing, shortness of breath Indication of any immediate medical attention and special treatment needed All treatments should be based on observed signs and symptoms of distress in the patient. : No significant signs or symptoms indicative of any health hazard are expected to occur as a result of skin contact. : No significant signs or symptoms indicative of any adverse health hazard are expected to occur as a result of eye exposure. : Like any product not designed to be ingested, this product may cause stomach distress if ingested in large quantities. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : None known Special hazards arising from the substance or mixture Fire hazard : No particular fire or explosion hazard Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Wear a self-contained breathing apparatus. Wear fire/flame resistant/retardant clothing. EN469. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel No additional information available For emergency responders Protective equipment : Avoid all eyes and skin contact and do not breathe vapour and mist Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections Reference to other sections (8, 13). : Stay upwind. Collect spillage. Large spills: scoop solid spill into closing containers. Minimize generation of dust. SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Always wash your hands immediately after handling this product, and once again before leaving the workplace Conditions for safe storage, including any incompatibilities Storage conditions : Store in a cool and well-ventilated place. Store in a closed container. Store in a dry place. Packaging materials : Do not store in corrodable metal: aluminum, carbon steel Specific end use(s) Fertilizer. Industrial processings & uses. 27/03/2018 MS (Bahasa Melayu) EN (English) 10/16

11 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Potash, Muriate of Potash, Sylvite ( ) as Total inert dust/particulate not otherwise regulated China GBZ FR - Ministère du Travail IT - Associazone Italiana Degli Igienisti Industriali Netherlands - Ministerie van Sociale Zaken en Werkgelegenheid Saskatchewan 容许浓度时间加权平均 Permissible Concentration (PC) Valeur limite de Moyenne d Exposition (Workplace Exposure Limit Values) Valori limite (sulla base di ACGIH TLVs) (Threshold Limit Values (based on ACGIH TLVs)) Maximaal Aanvarde Concentratie (MAC) (Maximum Allowable Concentration (MAC)) CAD SK OEL (Occupational Exposure Limit in Saskatchewan, Canada.) 8 mg/m³ TWA 5 mg/m³ TWA 3 mg/m³ TWA 5 mg/m³ TWA 10 mg/m³ TWA inhalable 3 mg/m³ TWA respirable fraction UK - Health & Safety Executive Workplace Exposure Limits (WEL) 4 mg/m³ TWA US - OSHA Permissible Exposure Limits (PEL) 15 mg/m³ TWA inhalable 5 mg/m³ TWA respirable fraction Potassium chloride ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal Acute - systemic effects, inhalation Long-term - systemic effects, dermal Long-term - systemic effects, inhalation DNEL/DMEL (General population) Acute - systemic effects, dermal Acute - systemic effects, inhalation Acute - systemic effects, oral Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant Sodium chloride ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal Acute - systemic effects, inhalation Long-term - systemic effects, dermal Long-term - systemic effects, inhalation DNEL/DMEL (General population) Acute - systemic effects, dermal Acute - systemic effects, inhalation Acute - systemic effects, oral Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal 910 mg/kg bodyweight/day 5320 mg/m³ 303 mg/kg bodyweight/day 1064 mg/m³ 910 mg/kg bodyweight 1365 mg/m³ 455 mg/kg bodyweight 91 mg/kg bodyweight/day 273 mg/m³ 182 mg/kg bodyweight/day 0.1 mg/l 0.1 mg/l 1 mg/l 10 mg/l 296 mg/kg bodyweight/day 2069 mg/m³ 296 mg/kg bodyweight/day 2069 mg/m³ 127 mg/kg bodyweight 443 mg/m³ 127 mg/kg bodyweight 127 mg/kg bodyweight/day 443 mg/m³ 127 mg/kg bodyweight/day 27/03/2018 MS (Bahasa Melayu) EN (English) 11/16

12 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection : Avoid dispersal of dust in the air (ie, clearing dust surfaces with compressed air). Provide local exhaust or general room ventilation to minimize exposure to dust. : Leather gloves. EN374 : Safety glasses. In case of dust production: protective goggles. EN166 : Impervious clothing : Use air-purifying respirator equipped with particulate filtering cartridges. Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. EN 136/140 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Dry flowable granules Molecular mass : 74.6 g/mol Colour : White to red/brown Odour : Odourless to slight Odour threshold ph ph solution : 5% (5.4-10) Relative evaporation rate (butylacetate=1) Melting point : C Freezing point : C Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) : Non-flammable Vapour pressure Relative vapour density at 20 C Relative density : water = 1 Density : kg/m³ (Bulk density) Solubility : Soluble in water Water: % Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties : Dust explosion characteristics: <63µm; explosibility: St 1; minimum ignition energy (mj): N/A Oxidizing properties Explosive limits 9.2. Other information Sublimation point : C VOC content : < 0.5 % Additional information : Similar to salt, may be corrosive to some metals in the presence of moisture. SECTION 10: Stability and reactivity Reactivity Strong acids Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Incompatible materials. 27/03/2018 MS (Bahasa Melayu) EN (English) 12/16

13 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS Incompatible materials Strong acids, boron trichloride, boron trifluoride, potassium dichromate, potassium permanganate, sulfuric acid Hazardous decomposition products No dangerous decomposition products known. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Potassium chloride ( ) LD50 oral rat Sodium chloride ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 3020 mg/kg 3550 mg/kg > mg/kg > 42 mg/l/1 hour 10.5 mg/l/4h Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Likely routes of exposure: : Inhalation may cause: irritation, cough, shortness of breath. : No significant signs or symptoms indicative of any health hazard are expected to occur as a result of skin contact. : No significant signs or symptoms indicative of any adverse health hazard are expected to occur as a result of eye exposure. : Like any product not designed to be ingested, this product may cause stomach distress if ingested in large quantities. : Dermal, inhalation SECTION 12: Ecological information Toxicity Potassium chloride ( ) LC50 fishes 1 EC50 Daphnia 1 ErC50 (algae) NOEC (chronic) 880 mg/l Pimephales promelas 96 hr hr > 100 mg/l 500 mg/l 7 day Sodium chloride ( ) LC50 fishes 1 EC50 Daphnia 1 NOEC (acute) NOEC chronic fish 5840 mg/l 96 hour; Lepomis macrochirus 4136 mg/l 48 hr 1500 mg/l Daphnia; 7 day 252 mg/l 33 day Persistence and degradability No additional information available Bioaccumulative potential No additional information available Mobility in soil Potash, Muriate of Potash, Sylvite ( ) Ecology - soil Mixture components are completely soluble in water. Partitions to soil. 27/03/2018 MS (Bahasa Melayu) EN (English) 13/16

14 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS Results of PBT and vpvb assessment Potash, Muriate of Potash, Sylvite ( ) This substance/mixture does not meet the PBT criteria of REACH, annex XIII. This substance/mixture does not meet the vpvb criteria of REACH, annex XIII Other adverse effects No additional information available SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations EURLW code SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / IATA UN number Not considered a dangerous good for transport regulations : Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems. : Dispose in a safe manner in accordance with local/national regulations. : For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 27/03/2018 MS (Bahasa Melayu) EN (English) 14/16

15 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Potash, Muriate of Potash, Sylvite is not on the REACH Candidate List Potash, Muriate of Potash, Sylvite is not on the REACH Annex XIV List VOC content : < 0.5 % Germany Water hazard class (WGK) : 1 - slightly hazardous to water International regulations All components are listed on the European Inventory of Existing Commercial Chemical Substances (EINECS). All ingredients are listed in the Canadian Domestic Substances List (DSL). Uncontrolled product according to WHMIS classification criteria. This document has been prepared in accordance with the SDS requirements of the WHMIS Controlled Products Regulation (CPR). All ingredients are listed in the US Toxic Substances Control Act (TSCA). All ingredients are listed on the Chinese Inventory of Existing Chemical Substances (IECSC). All ingredients are listed on KECI (Chemical Inventory of Korea). All ingredients are listed on the Japanese ENCS (Existing & New Chemicals Substances) inventory United States regulations This product has been reviewed according to the Environmental Protection Agency ( EPA ) Hazard Categories promulgated under Section 311 and 312 of the Superfund Amendment and reauthorization Act of 1986 (SARA title III) and is considered, under applicable definitions, to meet the following: Fire: No; Pressure Generating: No; Reactivity: No; Acute: No; Chronic: No 40 CFR Part 355 Extreme Hazardous Substances: None 40 CFR Part 370 Hazardous Chemical Report: None CERCA/ RCRA : Not listed Chemical safety assessment No additional information available SECTION 16: Other information Indication of changes: Revision date:27/03/2018 Original document date of issue: 06/04/2015 Abbreviations and acronyms: ACGIH ADR ADN ATE CAS CERCA CFR CLP CSCL DMEL DNEL EC EC50 EURLW GBT GHS IATA IBC IMDG KECI LD50 ACGIH (American Conference of Governmental Industrial Hygienists) European Agreement concerning the International Carriage of Dangerous Goods by Road European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways Acute Toxicity Estimate (Chemical Abstracts Service) number Comprehensive Environmental Response, Compensation & Liability Act (United States) Code of Federal Regulations Classification and Labeling of Chemicals Japanese Chemical Substances Control Law Derived Minimal Effect level Derived-No Effect Level European Communities Median effective concentration European List of Waste (LoW) code Chinese national standard Globally Harmonized System (of Classification and Labeling of Chemicals). International Air Transport Association Intermediate Bulk Container International Maritime Dangerous Goods Korean Existing Chemical Inventory Lethal Dose for 50% of the test population MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of /03/2018 MS (Bahasa Melayu) EN (English) 15/16

16 Potash, Muriate of Potash, Sylvite NON-HAZARDOUS CHEMICAL. SAFETY DATA SHEET IS NOT REQUIRED BY INTERNATIONAL REGULATIONS. NOEC OSHA PBT PNEC RCRA No Observable Effect Concentration Occupational Safety & Health Administration Persistent Bioaccumulative Toxic Predicted No Effect Level Resource Conservation and Recovery Act REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID SDS TSCA TWA vpvb VOC Regulations concerning the International Carriage of Dangerous Goods by Rail Toxic Substances Control Act Time Weighted Average Very Persistent and Very Bioaccumulative Volatile Organic Compound Data sources : ACGIH (American Conference of Governmental Industrial Hygienists). Canadian Centre for Occupational Health and Safety. Accessed at: China GBZ Occupational exposure limits for hazardous agents in the workplace: Chemical hazardous agents. European Chemicals Agency (ECHA) Registered Substances list. National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th edition. The Organisation for Economic Co-operation and Development (OECD; echemportal chemical searches. Accessed at Other information NFPA health hazard NFPA fire hazard NFPA reactivity : Method of classification used: component data. : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Original SDS Prepared By: The Redstone Group, LLC 6077 Frantz Road Suite 206 Dublin OH USA T This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 27/03/2018 MS (Bahasa Melayu) EN (English) 16/16

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