SAFETY DATA SHEET. Restrictions on use : Reserved for industrial and professional use.

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Disinfectant Restrictions on use : Reserved for industrial and professional use. Product dilution information : No dilution information provided. Company : Ecolab Inc. 1 Ecolab Place St. Paul, Minnesota USA Emergency health information : (US/Canada), (outside US) Issuing date : 12/07/2017 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable aerosols : Category 2 Acute toxicity (Oral) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Warning : Flammable aerosol. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. : Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse / 9

2 Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) ethanol difluoroethane n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl n-alkyl(68% C12, 32% C14) dimethylethylbenzyl SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Pressurised container: May burst if heated. Flammable aerosols : Decomposition products may include the following materials: / 9

3 products Special protective equipment for fire-fighters Specific extinguishing methods Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Do not ingest. Avoid contact with skin and eyes. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Contents under pressure. Do not puncture. Wash hands thoroughly after handling. : Keep away from heat and sources of ignition. Keep in a cool, wellventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 5 C to 45 C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Permissible concentration Basis ethanol TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z1 1,900 mg/m3 difluoroethane TWA 1,000 ppm AIHA WEEL Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety glasses with side-shields / 9

4 Hand protection Skin protection Respiratory protection Hygiene measures : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Color Odor : aerosol : light yellow : Floral ph : , (100 %) Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC Heat of combustion : 13 C closed cup : kj/g / 9

5 SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : Acids : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eye contact Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye irritation. : Causes skin irritation. : Harmful if swallowed. : Intentional misuse by deliberate inhalation may be harmful or fatal. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : Redness, Irritation : No information available. : No symptoms known or expected. Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation / 9

6 Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Acute oral toxicity : ethanol LD50 Rat: 10,470 mg/kg n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl LD50 Rat: 850 mg/kg n-alkyl(68% C12, 32% C14) dimethylethylbenzyl LD50 Rat: mg/kg Acute inhalation toxicity : ethanol 4 h LC50 Rat: 117 mg/l Test atmosphere: vapor difluoroethane 4 h LC50 Rat: > 437,500 mg/l Test atmosphere: gas n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl LC50 Rat: > mg/l Test atmosphere: dust/mist n-alkyl(68% C12, 32% C14) dimethylethylbenzyl 4 h LC50 Rat: > mg/l Test atmosphere: dust/mist Acute dermal toxicity : ethanol LD50 Rabbit: > 15,800 mg/kg n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl LD50 Rabbit: 2,300 mg/kg n-alkyl(68% C12, 32% C14) dimethylethylbenzyl LD50 Rabbit: 1,501 mg/kg SECTION 12. ECOLOGICAL INFORMATION / 9

7 Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : This product has no known ecotoxicological effects. : ethanol 96 h LC50 Pimephales promelas: > 100 mg/l : n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl 48 h EC50: 0.47 mg/l n-alkyl(68% C12, 32% C14) dimethylethylbenzyl 48 h EC50 Daphnia: mg/l Toxicity to algae : n-alkyl (60% C14, 30% C16, 5% C12, 5% C18) dimethyl benzyl NOEC: mg/l Persistence and degradability Not applicable - Biocide Biodegradable Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations / 9

8 SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) UN number : 1950 Description of the goods : Aerosols Class : 2.1 Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Marine pollutant : no SECTION 15. REGULATORY INFORMATION TSCA - 5(a) Significant New Use Rule List of Chemicals The following substance(s) is/are subject to a Significant New Use Rule: sodium nitrite EPA Registration number : EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards SARA 302 SARA 313 : Fire Hazard Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains one or several components that are not on the Canadian DSL nor NDSL. Australia Inventory of Chemical Substances (AICS) : / 9

9 Health Instability SAFETY DATA SHEET New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory (TCSI) : SECTION 16. OTHER INFORMATION NFPA: Flammability HMIS III: 3 HEALTH FLAMMABILITY 3 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 12/07/2017 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 9