: DCA16 Iodine Print Enhancer

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Product code 1.2. Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier : Mixtures : : DCA16 : Crime Scene Investigation SIRCHIE 100 Hunter Place Youngsville, NC USA T ; F ; Emergency telephone number Emergency number : CHEMTREC: SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids H225 Highly flammable liquid and vapour Category 2 Skin corrosion/irritation H315 Causes skin irritation Category 2 Carcinogenicity Category 2 H351 Suspected of causing cancer Specific target organ H336 May cause drowsiness or dizziness toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 H373 May cause damage to organs through prolonged or repeated exposure Full text of H statements : see section GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS02 GHS07 GHS08 : H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure : P210 - Keep away from heat, open flames, hot surfaces. - No smoking. P233 - Keep container tightly closed. P260 - Do not breathe vapors. P261 - Avoid breathing vapors. P264 - Wash hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing 12/22/2017 EN (English US) Page 1

2 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures P308+P313 - If exposed or concerned: Get medical advice/attention. P314 - Get medical advice/attention if you feel unwell. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use ABC-powder, foam, dry extinguishing powder to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Name Product identifier % GHS-US classification cyclohexane (CAS-No.) < 90 Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 chloroform (CAS-No.) < 9 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Inhalation), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Carc. 2, H351 STOT RE 2, H373 alpha-naphthoflavone (CAS-No.) < 1 Not classified Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/effects 4.3. Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. 12/22/2017 EN (English US) 2/8

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Safety glasses. Gloves. EN 149. Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment Emergency procedures : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials SECTION 8: Exposure controls/personal protection 8.1. Control parameters Not applicable alpha-naphthoflavone ( ) Not applicable : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Heat sources. Sources of ignition Appropriate engineering controls 8.3. Individual protection measures/personal protective equipment Personal protective equipment: Dust/aerosol mask. Gloves. Safety glasses. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask 12/22/2017 EN (English US) 3/8

4 Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid. Color : Colorless Odor : chloroform-like Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. Vapor pressure Relative vapor density at 20 C Relative density Solubility : Insoluble in water. Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity No data available Chemical stability Stable under recommended handling and storage conditions (see section 7) Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Sparks Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. 12/22/2017 EN (English US) 4/8

5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit ATE US (oral) ATE US (gases) ATE US (vapors) ATE US (dust, mist) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity single exposure 695 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; 908 mg/kg bodyweight; Rat; OECD 401: Acute Oral Toxicity; Experimental value; 1117 mg/kg bodyweight; Rat) > mg/kg (Rabbit; No reliable data available; >3980 mg/kg bodyweight; Rabbit) mg/kg body weight ppmv/4h mg/l/4h mg/l/4h > 5000 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male/female, Experimental value) > 2000 mg/kg body weight (Equivalent or similar to OECD 402, Rabbit, Male/female, Experimental value) > mg/l air (Equivalent or similar to OECD 403, 4 h, Rat, Male/female, Experimental value) : Causes skin irritation. Based on available data, the classification criteria are not met : Suspected of causing cancer. 2B - Possibly carcinogenic to humans Based on available data, the classification criteria are not met : May cause drowsiness or dizziness. Specific target organ toxicity repeated exposure : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 2 LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) 18.2 ppm (LC50; ASTM; 96 h; Oncorhynchus mykiss; Flow-through system; Fresh water; Experimental value) mg/l (EC50; US EPA; 48 h; Daphnia magna; Static system; Salt water; Experimental value) 4.53 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-through system, Fresh water, Experimental value) 0.9 mg/l (Equivalent or similar to OECD 202, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) mg/l (Equivalent or similar to OECD 201, 72 h, Pseudokirchneriella subcapitata, Experimental value) 12/22/2017 EN (English US) 5/8

6 12.2. Persistence and degradability Persistence and degradability Not established. Persistence and degradability ThOD BOD (% of ThOD) Not readily biodegradable in water. Non degradable in the soil. Low potential for adsorption in soil g O₂/g substance Persistence and degradability Biochemical oxygen demand (BOD) ThOD Non degradable in the soil. Readily biodegradable in water g O₂/g substance g O₂/g substance Bioaccumulative potential Bioaccumulative potential Not established. BCF fish (BCF; OECD 305: Bioconcentration: Flow-Through Fish Test; 42 days; Cyprinus carpio; Flow-through system; Fresh water; Experimental value) Log Pow 1.97 (Experimental value; 20 C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). BCF fish (OECD 305: Bioconcentration: Flow-Through Fish Test, 8 week(s), Cyprinus carpio, Literature study) Log Pow 3.44 (Experimental value, Other, 25 C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Surface tension Log Koc Ecology - soil Surface tension Log Koc Ecology - soil N/m (20 C) Koc,Other; ; Experimental value; log Koc; Other; ; Experimental value May be harmful to plant growth, blooming and fruit formation N/m (20 C) 2.89 (log Koc, Other, QSAR) Low potential for adsorption in soil Other adverse effects Effect on the global warming GWPmix comment Other information : No known effects from this product. : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1145 Cyclohexane (FLAMMABLE LIQUID), 3, II 12/22/2017 EN (English US) 6/8

7 UN-No.(DOT) Proper Shipping Name (DOT) : UN1145 : Cyclohexane FLAMMABLE LIQUID Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR Packing group (DOT) Hazard labels (DOT) : II - Medium Danger : 3 - Flammable liquid Other information : No supplementary information available. Transportation of Dangerous Goods Transport by sea Air transport Transport document description (IATA) UN-No. (IATA) Proper Shipping Name (IATA) Class (IATA) Packing group (IATA) : UN UN1145 Cyclohexane, 3, II, ENVIRONMENTALLY HAZARDOUS : UN1145 : Cyclohexane : 3 - Flammable Liquids : II - Medium Danger SECTION 15: Regulatory information US Federal regulations Subject to reporting requirements of United States SARA Section International regulations CANADA EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Listed on IARC (International Agency for Research on Cancer) US State regulations U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Yes Yes No No 12/22/2017 EN (English US) 7/8

8 SECTION 16: Other information Data sources Other information Full text of H-phrases: H225 H302 H315 H319 H331 H336 H351 H373 : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Highly flammable liquid and vapour Harmful if swallowed Causes skin irritation Causes serious eye irritation Toxic if inhaled May cause drowsiness or dizziness Suspected of causing cancer May cause damage to organs through prolonged or repeated exposure SDS US (GHS HazCom 2012) The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their particular purposes. 12/22/2017 EN (English US) 8/8