Safety data sheet. according to Regulation (EC) No 1907/2006 (REACH) Printing date Version number 1

Transcription

1 Page 1/7 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: Description: Acetic acid saturated with lithium chloride Product code: scho0005 Application of the substance / the preparation: Electrolyte solution Manufacturer/Supplier: SI Analytics GmbH Hattenbergstr Mainz Deutschland Tel.: Further information obtainable from: msds@si-analytics.com Emergency telephone number: (Giftnotruf München) 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC?@A?@A C; Corrosive R34: Causes burns. R10: Flammable. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the " in the latest valid version. Classification system: The classification is according to the latest editions of the -lists, and extended by company and literature data. Label elements Labelling according to guidelines: The product has been classified and marked in accordance with Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product:?@a C Corrosive Hazard-determining components of labelling: acetic acid Risk phrases: 10 Flammable. 34 Causes burns. Safety phrases: 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). (Contd. on page 2)

2 Page 2/7 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: acetic acid EINECS: Index number: CAS: EINECS: Additional information: For the wording of the listed risk phrases refer to section First aid measures Description of first aid measures After inhalation: Take affected persons into fresh air and keep quiet. Seek immediate medical advice. After skin contact: Wash off with plenty of water. Remove contaminated clothes. Seek immediate medical advice. After eye contact: Rinse opened eye for several minutes under running water. Protect unharmed eye. Call a doctor immediately. After swallowing: Make victim drink water immediately (2 glasses at most). Do not induce vomiting (risk of perforation and aspiration) Call a doctor immediately. 5 Firefighting measures C R35 R10 (Contd. of page 1) % lithium chloride Xn R22; Xi R36/ % Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture Development of corrosive and flammable vapors in the event of fire. Vapours can form an explosive mixture with air above 40 C. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Additional information Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Use respiratory protective device against the effects of fumes/dust/aerosol. Keep away from ignition sources. Environmental precautions: Suppress gases/fumes/haze with water spray. Do not allow larger amounts to enter sewer, surface waters or ground water. Methods and material for containment and cleaning up: Dilute with water and neutralise with e.g. caustic soda solution, sodium bicarbonate, calcium carbonate. (Contd. on page 3)

3 Page 3/7 Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the material collected according to regulations. (Contd. of page 2) 7 Handling and storage Handling: Precautions for safe handling Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). Use solvent-proof equipment. Prevent formation of aerosols. Information about fire - and explosion protection: Keep away from sources of ignition and hot surfaces. Protect against electrostatic charges. Vapours can form an explosive mixture with air above 40 C. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Provide acid-resistant floor. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Keep container tightly sealed. Store receptacle in a well ventilated area. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: acetic acid (50-100%) IOELV 25 mg/m³, 10 ppm Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Do not eat or drink while working. Storing food in the working area is prohibited. Change contaminated clothing. Wash hands before breaks and at the end of work. Use skin protection cream for skin protection. Respiratory protection: Only required when fog or aerosols are generated. Recommended filter device for short term use: Combination filter E-P2 Protection of hands: Material of gloves Butyl rubber, BR Recommended thickness of the material: 0,5 mm Eye protection: Tightly sealed goggles (Contd. on page 4)

4 Page 4/7 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Colour: Odour: Fluid Colourless Pungent Change in condition Melting point/melting range: ca. 16 C Boiling point/boiling range: ca. 119 C Flash point: Ignition temperature: 485 C Danger of explosion: Explosion limits: Lower: 4,0 Vol % Upper: 17,0 Vol % Vapour pressure at 25 C: Density: Solubility in / Miscibility with water: 40 C (geschlossener Tiegel) Vapours can form an explosive mixture with air above 40 C. 50 hpa 1,09 g/cm³ Fully miscible. Segregation coefficient (n-octanol/water): -0,2 log POW (Eisessig) Viscosity: Kinematic at 25 C: 10 Stability and reactivity 1,51 mm²/s (Contd. of page 3) Reactivity Chemical stability Thermal decomposition / conditions to be avoided: Vapours can form an explosive mixture with air above 40 C. Possibility of hazardous reactions Violent reactions with strong alkalines an oxidants (e. g. chrome(vi) oxide, chromosulfuric acid, potassium permanganate, sodium peroxide, perchloric acid, phosphoros halides, hydrogen peroxide). Reactions with anhydrides/water, alcohols, halogens, halogen compounds, non-metal halides and ethylene glycol. Risk of polymerisation with acetaldehyde. Reacts with base metals forming hydrogen. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: acetic acid Oral LD mg/kg (Rat) Dermal LD mg/kg (Rabbit) Inhalative LC50 11,4 mg/l, 4 h (Rat) (IUCLID) lithium chloride Oral LD mg/kg (Rat) (Contd. on page 5)

5 Page 5/7 Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Severe irritations, risk of cornea cloudness, risk of blindness. Sensitization: No sensitizing effects known. (Contd. of page 4) Additional toxicological information: The product shows the following dangers according to the calculation method of the General Classification Guidelines for Preparations as issued in the latest version: Corrosive Swallowing causes severe burns of the mouth and throat and implies a risk of perforation of the oesophagus and the stomach. Risk of kidney damage. 12 Ecological information Toxicity Acquatic toxicity: acetic acid EC50 47 mg/l, 24 h (Daphnia magna) (IUCLID) LC50 75 mg/l, 96 h (Lepomis macrochirus) (IUCLID) Persistence and degradability The organic part of the mixture is easily biodegradable. Behaviour in environmental systems: Bioaccumulative potential Due to the distribution coefficient n-octanol/water a worth-mentioning accumulation in organisms is not expected. Additional ecological information: General notes: Detrimental effect due to shift of ph value. Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS separately collected fractions (except 15 01) * acids Uncleaned packaging: Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Packagings that may not be cleansed are to be disposed of in the same manner as the product. Recommended cleansing agents: Water, if necessary together with cleansing agents. (Contd. on page 6)

6 Page 6/7 14 Transport information Land transport ADR/RID (cross-border) daco}dcgx ADR/RID class: 8 (CF1) Corrosive substances. Danger code (Kemler): 83 UN-Number: 2789 Packaging group: II Hazard label: 8+3 UN proper shipping name: 2789 ACETIC ACID, GLACIAL Tunnel restriction code E Maritime transport IMDG: daco}dcgx IMDG Class: 8 UN Number: 2789 Label 8+3 Packaging group: II EMS Number: F-E,S-C Marine pollutant: No Segregation groups Acids Proper shipping name: ACETIC ACID, GLACIAL Air transport ICAO-TI and IATA-DGR: daco}dcgx ICAO/IATA Class: 8 UN/ID Number: 2789 Label 8+3 Packaging group: II Proper shipping name: ACETIC ACID, GLACIAL 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information (Contd. of page 5) Relevant phrases R10 Flammable. R22 Harmful if swallowed. R35 Causes severe burns. R36/38 Irritating to eyes and skin. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods (Contd. on page 7)

7 Page 7/7 IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent (Contd. of page 6)