Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard - United States, Canada, Mexico Date Version 05/15/ Material Safety Data Sheet T10 Electrolyte 1. Product and company identification Product name Trade name Material uses Code Supplier/Manufacturer MSDS authored by In case of emergency 2. Hazards identification T10 Electrolyte Electrolyte Formula T10 Electrolyte solution. T10 Marking Methods, Inc. 301 S. Raymond Avenue Alhambra, CA Tel (626) KMK Regulatory Services Inc. CHEMTREC, U.S International Emergency overview Physical state Liquid. Color Clear. Odor Not available. Signal word WARNING! Hazard statements CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Precautionary measures Do not get in eyes. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Inhalation No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Skin Slightly irritating to the skin. Eyes Severely irritating to eyes. Risk of serious damage to eyes. Potential chronic health effects Chronic effects Contains material that may cause target organ damage, based on animal data. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Target organs Contains material which may cause damage to the following organs kidneys, upper respiratory tract, skin, eyes. Over-exposure signs/symptoms Inhalation No specific data. 1/8

2 2. Hazards identification Ingestion Skin Eyes Medical conditions aggravated by overexposure See toxicological information (Section 11) No specific data. Adverse symptoms may include the following irritation redness Adverse symptoms may include the following pain or irritation watering redness Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. 3. Composition/information on ingredients United States Name CAS number % Glycerol Sodium phosphate, tribasic Canada Name CAS number % Glycerol Sodium phosphate, tribasic Mexico Classification Name CAS number UN number % IDLH H F R Special Glycerol Not regulated Sodium phosphate, tribasic UN There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids. In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention if symptoms occur. Move exposed person to fresh air. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. No specific treatment. Treat symptomatically. 2/8

3 5. Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters No specific fire or explosion hazard. Use an extinguishing agent suitable for the surrounding fire. None known. No specific fire or explosion hazard. 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Decomposition products may include the following materials carbon dioxide carbon monoxide phosphorus oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Provide adequate ventilation. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Spill Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see section 1 for emergency contact information and section 13 for waste disposal. 7. Handling and storage Handling Storage Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure controls/personal protection United States Ingredient Exposure limits Glycerol ACGIH TLV (United States, 1/2011). TWA 10 mg/m³ 8 hour(s). Form Inhalable fraction OSHA PEL (United States, 6/2010). TWA 5 mg/m³ 8 hour(s). Form Respirable fraction TWA 15 mg/m³ 8 hour(s). Form Total dust Sodium phosphate, tribasic AIHA WEEL (United States, 10/2011). STEL 5 mg/m³ 15 minute(s). Canada 3/8

4 8. Exposure controls/personal protection Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations Sodium phosphate, tribasic US AIHA 10/ Glycerol US ACGIH 1/ [a] AB 4/ [3] [b] BC 9/ [b] [c] ON 7/ [a] QC 9/ [b] [3]Skin sensitization Form [a]inhalable fraction [b]mist [c]respirable mist Mexico Occupational exposure limits Ingredient Exposure limits Glycerol NOM-010-STPS (Mexico, 9/2000). LMPE-PPT 10 mg/m³ 8 hour(s). Form mist Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands Eyes Skin Environmental exposure controls 9. Physical and chemical properties Personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. No special ventilation requirements. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Not required under normal conditions of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Ensure a MSHA/NIOSH-approved respirator or equivalent is used. Use gloves appropriate for work or task being performed. Recommended Natural rubber (latex). Safety eyewear should be used when there is a likelihood of exposure. Recommended Safety glasses with side shields. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended Lab Coat. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Physical state Flash point Burning time Burning rate Auto-ignition temperature Flammable limits Color Odor Taste Liquid. Not available. Not applicable. Not applicable. Not available. Not available. Clear. Not available. Not available. 4/8

5 9. Physical and chemical properties Molecular weight Not applicable. Molecular formula ph Boiling/condensation point Melting/freezing point Critical temperature Relative density Vapor pressure Vapor density Volatility Odor threshold Evaporation rate SADT Viscosity Ionicity (in water) Dispersibility properties Solubility Physical/chemical properties comments Not applicable to C (212 F) 0 C (32 F) Not available Not available. >1 [Air = 1] 0% (v/v) Not available. Not available. Not available. Not available. Not available. Not available. Complete. Not available. 10. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions The product is stable. No specific data. Reactive or incompatible with the following materials oxidizing materials and acids. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. 11. Toxicological information Acute toxicity Product/ingredient name Result Species Dose Exposure Glycerol LD50 Dermal Rabbit >10 g/kg - LD50 Oral Rat mg/kg - Chronic toxicity Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Glycerol Eyes - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Sensitizer Skin Respiratory Carcinogenicity 5/8

6 11. Toxicological information Mutagenicity Teratogenicity Reproductive toxicity 12. Ecological information Ecotoxicity Aquatic ecotoxicity No known significant effects or critical hazards. Product/ingredient name Result Species Exposure Sodium phosphate, tribasic Acute LC ug/l Fresh water Fish - Gambusia affinis - Adult 96 hours Glycerol Acute LC mg/l Fish 96 hours Persistence/degradability 13. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14. Transport information International transport regulations DOT / TDG / Mexico / IMDG / IATA Not regulated by any transport mode. 15. Regulatory information United States HCS Classification U.S. Federal regulations Irritating material Target organ effects TSCA 8(a) IUR Exempt/Partial exemption Not determined United States inventory (TSCA 8b) All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals Glycerol; Sodium phosphate, tribasic SARA 311/312 MSDS distribution - chemical inventory - hazard identification Glycerol Immediate (acute) health hazard, Delayed (chronic) health hazard; Sodium phosphate, tribasic Delayed (chronic) health hazard 6/8

7 15. Regulatory information Clean Water Act (CWA) 311 Sodium phosphate, tribasic Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) Not listed Not listed Not listed Not listed Not listed State regulations Massachusetts The following components are listed Glycerol New York The following components are listed Sodium phosphate, tribasic New Jersey The following components are listed Glycerol; Sodium phosphate, tribasic Pennsylvania The following components are listed Glycerol; Sodium phosphate, tribasic California Prop. 65 No products were found. Canada WHMIS (Canada) Class E Corrosive material Canadian lists Canadian NPRI None of the components are listed. CEPA Toxic substances None of the components are listed. Canada inventory This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Mexico Classification All components are listed or exempted. Health 0 Flammability 2 1 Reactivity Special 16. Other information Label requirements Hazardous Material Information System (U.S.A.) CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Caution HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health 2 * Flammability 0 Physical hazards 1 Health 2 Flammability 0 Instability 1 7/8

8 16. Other information Reprinted with permission from NFPA , Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Canada WHMIS (Canada) History Date of issue mm/dd/yyyy Date of previous issue 05/15/ /15/2011 Version 3 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 8/8