Safety Data Sheet. according to Regulation (EC) No 1907/2006. MultiEx EXP-6030 WCL

Transcription

1 Product code: Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Electronics cleaner for spray and immersion plants 1.3. Details of the supplier of the safety data sheet Company name: Street: Karl-Arnold-Str. 12 Place: D Willich Telephone: Telefax: info@kolb-ct.com Contact person: Herr Linker Telephone: christian.linker@kolb-ct.com Internet: Responsible Department: Labor/ QS 1.4. Emergency telephone number: +49/ (0) 23 24/ (EU) (Australia) (USA) Further Information Australia: USA: kolb Cleaning Technology AP PTY LTD kolb USA LLC 6/150 Canterbury Road 410 Sunset, Unit C NSW 2200 Bankstown Longmont CO Phone: Phone Mobile Mobile: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: Causes serious eye irritation Label elements Regulation (EC) No. 1272/2008 Signal word: Pictograms: Warning Hazard statements H319 Causes serious eye irritation. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention.

2 Product code: Page 2 of Other hazards No information available. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Cleaner on the basis of (according to EC Detergents Regulation 648/2004): glycols, Alkyle propylene glycole, stabilizers Hazardous components EC No Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity Dipropylene glycol monomethyl ether, Isomerengem 60 - < 65 % (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether < 30 % Eye Irrit. 2; H dipropylene 10 - < 15 % Full text of H and EUH statements: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information In case of allergic symptoms, especially in the breathing area, seek medical advice immediately. After inhalation Provide fresh air. Do not leave affected person unattended. After contact with skin Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with plenty of water and soap. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. After ingestion Rinse mouth immediately and drink plenty of water. Let water be drunken in little sips (dilution effect) Most important symptoms and effects, both acute and delayed Observe risk of aspiration if vomiting occurs Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media

3 Product code: Page 3 of 8 Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. alcohol resistant foam. Dry extinguishing powder. Carbon dioxide (CO2). Unsuitable extinguishing media Atomized water. Water mist 5.2. Special hazards arising from the substance or mixture Non-flammable. non 5.3. Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Wear a self-contained breathing apparatus and chemical protective clothing. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment. Special danger of slipping by leaking/spilling product. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions Do not allow to enter into surface water or drains. Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Prevent spread over a wide area (e.g. by containment or oil barriers) Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Advice on storage compatibility 7.3. Specific end use(s) Electronics cleaner for spray and immersion plants SECTION 8: Exposure controls/personal protection 8.1. Control parameters

4 Product code: Page 4 of 8 Exposure limits (EH40) Substance ppm mg/m³ fibres/ml Category Origin (2-methoxymethylethoxy) propanol TWA (8 h) WEL - - STEL (15 min) WEL (2-Butoxyethoxy)ethanol TWA (8 h) WEL 8.2. Exposure controls STEL (15 min) WEL Protective and hygiene measures Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Eye/face protection Suitable eye protection: goggles. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Skin protection Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Lower explosion limits: Upper explosion limits: Auto-ignition temperature Solid: Gas: Decomposition temperature: Oxidizing properties Not oxidising. Vapour pressure: liquid colourless neutral not measurable [see also 9.2 ] C Test method

5 Density (at 20 C): Water solubility: Solubility in other solvents Partition coefficient: Viscosity / kinematic: (at 20 C) Vapour density: Evaporation rate: 9.2. Other information Solid content: Product code: Page 5 of 8 0,95 g/cm³ full soluble in water. 24 mm²/s not subject to the requirements of 4 of the Hazardous Substances Ordinance (GefStoffV) SECTION 10: Stability and reactivity Reactivity not known Chemical stability The substance is chemically stable under recommended conditions of storage, use and temperature Possibility of hazardous reactions not known Conditions to avoid not known Incompatible materials not known Hazardous decomposition products Carbon dioxide, Carbon monoxide SECTION 11: Toxicological information Information on toxicological effects

6 Product code: Page 6 of 8 Acute toxicity Exposure route Dose Dipropylene glycol monomethyl ether, Isomerengem oral dermal LD LD Species Ratte Kanincheb (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether oral dermal dipropylene oral dermal LD LD LD LD50 >2000 Rat Rabbit Ratte kaninchen Additional information on tests The mixture is classified as hazardous according to Directive 1999/45/EC. SECTION 12: Ecological information Source Method Toxicity The product is not: Ecotoxic Aquatic toxicity Dose [h] [d] Species Source Dipropylene glycol monomethyl ether, Isomerengem Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 >10000 ErC50 >969 EC h Pimephales promelas (Amerikan. Elritze) 96 h Alge 48 h Daphnia magna (Wasserfloh) Crustacea toxicity NOEC 12 Daphnia magna (Wasserfloh) 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether Acute algae toxicity ErC50 > 100 Acute crustacea toxicity dipropylene Acute fish toxicity Acute crustacea toxicity EC50 > 100 LC50 >100 EC50 >100 Scenedesmus sp. 48 h Daphnia magna 96 h 48 h Method Persistence and degradability Biodegradable according to RVO

7 Product code: Page 7 of Method Value d Evaluation Dipropylene glycol monomethyl ether, Isomerengem OECD 301E >70% 28 biologisch abbaubar dipropylene Zahn-Wellens-Test (Methode C.9) 25% 28 schwer biologisch abbaubar Source Bioaccumulative potential The product has not been tested. Partition coefficient n-octanol/water Dipropylene glycol monomethyl ether, Isomerengem -0,6 Log Pow (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether 0,56 (25 C) dipropylene 0,42 BCF dipropylene Mobility in soil Biodegradable according to RVO Results of PBT and vpvb assessment The product has not been tested Other adverse effects No information available. Further information Avoid release to the environment. SECTION 13: Disposal considerations BCF Species Source Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals; wastes not otherwise specified Contaminated packaging Wash with plenty of water. Completely emptied packages can be recycled. SECTION 14: Transport information Land transport (ADR/RID) UN proper shipping name: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No information available. No dangerous good in sense of these transport regulations. no

8 Product code: Page 8 of Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Restrictions on use (REACH, annex XVII): Entry 55: 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether 2004/42/EC (VOC): Additional information 30 % (285 g/l) To follow: 850/2004/EC, 79/117/EEC, 689/2008/EC National regulatory information Employment restrictions: Water contaminating class (D): Chemical safety assessment Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). 1 - slightly water contaminating Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant H and EUH statements (number and full text) H319 Causes serious eye irritation. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)