Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 LOCTITE LB 8156 known as Loctite g SFDN Page 1 of 11 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE LB 8156 known as Loctite g SFDN Contains: Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Lubricant 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Serious eye damage Category 1 H318 Causes serious eye damage. Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger

2 Hazard statement: LOCTITE LB 8156 known as Loctite g SFDN Page 2 of 11 H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. Precautionary statement: Prevention Precautionary statement: Response P273 Avoid release to the environment. P280 Wear eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Lubricant Declaration of the ingredients according to CLP (EC) No 1272/2008: Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts Isoalkylphenyl phosphorothioate Ethyl 3-[[bis(1- methylethoxy)phosphinothioyl]thio]propion ate EC Number REACH-Reg No content Classification >= 0,1- < 0,3 % Aquatic Chronic 3 H >= 3- < 10 % Aquatic Chronic 2 H411 Skin Irrit. 2 H315 Eye Dam. 1 H >= 1- < 2,5 % Aquatic Chronic 2 H >= 3- < 10 % Aquatic Chronic 2 H >= 0,3- < 1 % Aquatic Acute 1 H400 Aquatic Chronic 1 H410 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. SECTION 4: First aid measures Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary.

3 LOCTITE LB 8156 known as Loctite g SFDN Page 3 of 11 Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed Prolonged or repeated contact may cause skin irritation. Causes burns Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures 5.2. Special hazards arising from the substance or mixture Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Ensure adequate ventilation Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Use only in well-ventilated areas. Vapours should be extracted to avoid inhalation. Avoid skin and eye contact. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place. Keep away from heat and direct sunlight Specific end use(s) Lubricant

4 LOCTITE LB 8156 known as Loctite g SFDN Page 4 of 11 SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 type Short term exposure limit category / Remarks 2,6-di-tert-Butyl-p-cresol 10 Time Weighted Average (TWA): [2,6-DI-TERT-BUTYL-P-CRESOL] Regulatory list EH40 WEL Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) period mg/l ppm mg/kg others 0,051 mg/l 9320 mg/kg 932 mg/kg soil 1860 mg/kg soil STP sediment (freshwater) oral aqua (marine water) aqua (intermittent releases) aqua (freshwater) sediment (marine water) 8,33 mg/kg 0,0051 mg/l 0,51 mg/l 1 mg/l 47,69 µg/kg 0,17 mg/l 99,6 µg/kg 0,0199 µg/l 0,00199 mg/l 0, mg/l 9,96 µg/kg Remarks

5 LOCTITE LB 8156 known as Loctite g SFDN Page 5 of 11 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Dermal Long term Workers Inhalation Long term general Dermal Long term general general Inhalation oral Long term Long term Workers inhalation Long term Workers Dermal Long term general general general inhalation Dermal oral Long term Long term Long term Time 0,62 mg/kg 4,37 mg/m3 0,31 mg/kg 1,09 mg/m3 0,31 mg/kg 3,5 mg/m3 0,5 mg/kg bw/day 0,86 mg/m3 0,25 mg/kg bw/day 0,25 mg/kg bw/day Remarks Biological Indices: None 8.2. controls: Respiratory protection: Use only in well-ventilated areas. Hand protection: The use of chemical resistant gloves such as Neoprene or Natural Rubber is recommended Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Grease white Odor characteristic Odour threshold ph Initial boiling point Flash point 96 C (204.8 F)

6 LOCTITE LB 8156 known as Loctite g SFDN Page 6 of 11 Decomposition temperature Vapour pressure Density (20 C (68 F)) Bulk density Viscosity (; 20 C (68 F)) Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 0,9 g/cm mpa.s Insoluble 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reacts with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Stable Incompatible materials See section reactivity Hazardous decomposition products Irritating organic vapours Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: This material is considered to have low toxicity if swallowed. May cause irritation to the digestive tract. Inhalative toxicity: Due to the low volatility of the product there are no hazards associated with inhalation under normal conditions of use Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Causes serious eye damage.

7 LOCTITE LB 8156 known as Loctite g SFDN Page 7 of 11 Acute oral toxicity: reaction products with 2,4,4-trimethylpentene Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts type Route of application time Species Method LD50 > mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) LD50 > mg/kg oral rat LD50 > mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: type Route of application time Species Method Acute dermal toxicity: reaction products with 2,4,4-trimethylpentene type Route of application time Species Method LD50 > mg/kg dermal rat OECD Guideline 402 (Acute Dermal Toxicity) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Do not empty into drains / surface water / ground water. Harmful to aquatic life with long lasting effects.

8 LOCTITE LB 8156 known as Loctite g SFDN Page 8 of 11 reaction products with 2,4,4- trimethylpentene reaction products with 2,4,4- trimethylpentene reaction products with 2,4,4- trimethylpentene Phosphorodithioic acid, O,Odi-C1-14-alkyl esters, zinc salts Phosphorodithioic acid, O,Odi-C1-14-alkyl esters, zinc salts type Acute Toxicity Study time Species Method LC50 > 71 mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 51 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC mg/l Algae 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 > 1-10 mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 1-10 mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 0,48 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation NOEC 0,316 mg/l chronic Daphnia Test) 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) Persistence and degradability Persistence and Biodegradability: No data available for the product. reaction products with 2,4,4- trimethylpentene Phosphorodithioic acid, O,Odi-C1-14-alkyl esters, zinc salts Result Route of application Degradability Method aerobic 0 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) aerobic 5 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) aerobic 4,5 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil Mobility: No data available for the product. Bioaccumulative potential: No data available for the product. LogKow Bioconcentration factor (BCF) time Species Temperature Method weeks Cyprinus carpio OECD Guideline 305 C (Bioaccumulation: Test for the Degree of Bioconcentration in Fish) 5,1

9 LOCTITE LB 8156 known as Loctite g SFDN Page 9 of Results of PBT and vpvb assessment with 2,4,4-trimethylpentene PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Disposal must be made according to official regulations. Waste code other solvents and solvent mixtures SECTION 13: Disposal considerations

10 LOCTITE LB 8156 known as Loctite g SFDN Page 10 of 11 SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packaging group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 0 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

11 LOCTITE LB 8156 known as Loctite g SFDN Page 11 of 11 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H315 Causes skin irritation. H318 Causes serious eye damage. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): Xi - Irritant Risk phrases: R36 Irritating to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.