SAFETY DATA SHEET TRI-STAR CLEARLY SOFT

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Laundry softener Restrictions on use : Reserved for industrial and professional use. Product dilution information :.6 % -.11 % Company : Ecolab Co. 515 Tomken Road Mississauga, Ontario Canada L4W 2X Emergency health information : (US/Canada), (outside US) Issuing date : 2/15/217 Section: 2. HAZARDS IDENTIFICATION GHS Classification Reproductive toxicity (Inhalation) : Category 2 Not a hazardous substance or mixture. GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Precautionary Statements : Warning : Suspected of damaging fertility or the unborn child if inhaled. : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. : Prevention: / 1

2 Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) Amines (incl. ethanolamines) propan-2-ol Silicones octamethylcyclotetrasiloxane No hazardous ingredients Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : No special precautions are necessary for first aid responders. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment / 1

3 Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Risk of explosion. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus : Use personal protective equipment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Do not flush into surface water or sanitary sewer system. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Do not flush into surface water or sanitary sewer system. Section: 7. HANDLING AND STORAGE Advice on safe handling : Wash hands thoroughly after handling / 1

4 Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 1 C to 4 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis propan-2-ol TWA 2 ppm CAD AB OEL 492 mg/m3 STEL 4 ppm CAD AB OEL 984 mg/m3 TWA 2 ppm CAD BC OEL STEL 4 ppm CAD BC OEL VME 4 ppm OEL (QUE) 983 mg/m3 STEV 5 ppm OEL (QUE) 1,23 mg/m3 propan-2-ol TWA 2 ppm ACGIH STEL 4 ppm ACGIH TWA 4 ppm NIOSH REL 98 mg/m3 STEL 5 ppm NIOSH REL 1,225 mg/m3 TWA 4 ppm 98 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : Wear eye protection/face protection. : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling / 1

5 Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : opaque, off-white colourless Odour : Perfumes, fragrances Perfumes, fragrances ph : , 1 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 117 C closed cup, Does not sustain combustion. : > 1 C Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : insoluble / 1

6 Section: 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : Bases : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Suspected of damaging fertility or the unborn child if inhaled. Experience with human exposure Eye contact Skin contact Ingestion Inhalation / 1

7 Eye contact Skin contact Ingestion Inhalation Toxicity Product Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute inhalation toxicity : Acute toxicity estimate : > 5, mg/kg : No skin irritation : No eye irritation : propan-2-ol 4 h LC5 rat: > 3 mg/l Silicones 4 h LC5 rat: 978 mg/l octamethylcyclotetrasiloxane 4 h rat: 36 mg/l Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components : Toxic to aquatic life. Harmful to aquatic life with long lasting effects. : 96 h LC5: 7.14 mg/l / 1

8 Toxicity to daphnia and other aquatic invertebrates : propan-2-ol LC5 Daphnia magna (Water flea): > 1, mg/l Persistence and degradability Poorly biodegradable Not applicable - inorganic Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea transport (IMDG/IMO) / 1

9 Not dangerous goods Section: 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR. NPRI Components Canadian PBT Chemicals : propan-2-ol : This product contains the following components on the DSL that are classified as Persistent, Bioaccumulative and/or Toxic (PBT) under CEPA: octamethylcyclotetrasiloxane decamethylcyclopentasiloxane The components of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : not determined United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : not determined New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : On the inventory, or in compliance with the inventory Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China Inventory of Existing Chemical Substances : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory : not determined Section: 16. OTHER INFORMATION / 1

10 Health Health Instability Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: 1 HEALTH * FLAMMABILITY 1 PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 2/15/217 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 1