SAFETY DATA SHEET REGAIN. Section: 1. PRODUCT AND COMPANY IDENTIFICATION. Product name : REGAIN. Other means of identification : Not applicable.

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1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Floor Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : 0.8 % % Company : Ecolab Co Tomken Road Mississauga, Ontario Canada L4W 2X Emergency health information : (US/Canada), (outside US) Issuing date : 04/13/2016 Section: 2. HAZARDS IDENTIFICATION GHS Classification Skin corrosion : Category 1A Serious eye damage : Category 1 Specific target organ toxicity - : Category 3 (Respiratory system) single exposure Skin corrosion : Category 1A Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Danger : Causes severe skin burns and eye damage. May cause respiratory irritation. : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.if ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.if INHALED: Remove person to fresh air and keep / 12

2 comfortable for breathing. Immediately call a POISON CENTER/doctor.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Other hazards : Danger : Causes severe skin burns and eye damage. : Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.if ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.if INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) monoethanolamine butoxyethanol alcohols, c12-16, ethoxylated ethylenediamine tetraacetate Sodium silicate sodium hydroxide Chemical Name CAS-No. Concentration: (%) monoethanolamine butoxyethanol / 12

3 alcohols, c12-16, ethoxylated ethylenediamine tetraacetate sodium hydroxide Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible / 12

4 Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Risk of explosion. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling / 12

5 Conditions for safe storage : Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 C to 50 C Advice on safe handling Conditions for safe storage : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis monoethanolamine STEL 6 ppm CAD AB OEL 15 mg/m3 TWA 3 ppm CAD AB OEL 7.5 mg/m3 TWA 3 ppm CAD BC OEL STEL 6 ppm CAD BC OEL VME 3 ppm OEL (QUE) 7.5 mg/m3 STEV 6 ppm OEL (QUE) 15 mg/m3 monoethanolamine TWA 3 ppm ACGIH STEL 6 ppm ACGIH TWA 3 ppm NIOSH REL 8 mg/m3 STEL 6 ppm NIOSH REL 15 mg/m3 TWA 3 ppm OSHA Z1 6 mg/m3 2-butoxyethanol TWA 20 ppm CAD AB OEL 97 mg/m3 TWA 20 ppm CAD BC OEL VME 20 ppm OEL (QUE) 97 mg/m3 2-butoxyethanol TWA 20 ppm ACGIH TWA 5 ppm NIOSH REL 24 mg/m3 TWA 50 ppm OSHA Z1 240 mg/m3 sodium hydroxide (c) 2 mg/m3 CAD AB OEL C 2 mg/m3 CAD BC OEL C 2 mg/m3 OEL (QUE) sodium hydroxide Ceiling 2 mg/m3 ACGIH Ceiling 2 mg/m3 NIOSH REL TWA 2 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards / 12

6 Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Wear eye protection/face protection. : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : Wear eye protection/face protection. : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : light green light green Odour : ammoniacal slight ph : , 100 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate : Not applicable / 12

7 Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : 1.04 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC Section: 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : Metals Organic materials Acids : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion : Causes serious eye damage. : Causes severe skin burns. : Causes digestive tract burns / 12

8 Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : May cause respiratory tract irritation. May cause nose, throat, and lung irritation. : Health injuries are not known or expected under normal use. : Causes serious eye damage. : Causes severe skin burns. : Causes digestive tract burns. : May cause nose, throat, and lung irritation. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Corrosion : Redness, Pain, Corrosion : Corrosion, Abdominal pain : Respiratory irritation, Cough : Redness, Pain, Corrosion : Redness, Pain, Corrosion : Corrosion, Abdominal pain : Respiratory irritation, Cough Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure : Acute toxicity estimate : > 5,000 mg/kg : 4 h Acute toxicity estimate : > 10 mg/l : Acute toxicity estimate : > 5,000 mg/kg / 12

9 STOT - repeated exposure Aspiration toxicity Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components Toxicity to fish : Harmful to aquatic life. : 2-butoxyethanol 96 h LC50: 1,474 mg/l alcohols, c12-16, ethoxylated 96 h LC50 Fish: 1.5 mg/l ethylenediamine tetraacetate 96 h LC50 Fish: 121 mg/l Sodium silicate 96 h LC50: 210 mg/l Components Toxicity to daphnia and other aquatic invertebrates : monoethanolamine 48 h EC50 Daphnia: 65 mg/l 2-butoxyethanol 48 h EC50: 690 mg/l sodium hydroxide 48 h EC50: 40 mg/l Components Toxicity to algae : 2-butoxyethanol 72 h EC50: 911 mg/l Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available / 12

10 Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Section: 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR. NPRI Components : 2-butoxyethanol 2,2'-iminodiethanol Nitrilotriaceticacid[NTA] Salt The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory / 12

11 Health Health Instability Instability SAFETY DATA SHEET New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : On the inventory, or in compliance with the inventory Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China Inventory of Existing Chemical Substances : On the inventory, or in compliance with the inventory Section: 16. OTHER INFORMATION NFPA: Flammability HMIS III: 0 HEALTH FLAMMABILITY 0 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: 0 HEALTH FLAMMABILITY 0 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 04/13/2016 version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS / 12

12 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 12

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