: Floranid Master Extra

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Fertilizer 1.3 Details of the supplier of the safety data sheet Company : COMPO EXPERT GmbH Gildenstraße 38 D Münster Telephone : / Telefax : +49 (0)251/ address : info@compo.de 1.4 Emergency telephone number Central Safety & Environment Telephone: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Classification(67/548/EEC,1999/45/EC) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements Labelling(REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Labelling according to EC Directives (1999/45/EC) Further information : In accordance with EC directives or respective national laws, the product does not need to be classified nor labelled. Further information : German "Hazardous Substances" legislation ( Gefahrstoffverordnung) appendix I, No. 5 (Ammonium Nitrate group C III) 2.3 Other hazards According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified. 1/14 Print Date:

2 3. Composition/information on ingredients 3.2 Mixtures Chemical nature Hazardous components : Fertilizer NPK - fertilizer contains:n,n -(2-Methylpropyliden)-bis-urea, ammonium nitrate, potasium sulfate, ammonium salt, phosphate, magnesium salt, calcium salt, trace element combination. Chemical Name CAS-No. EC-No. Registration number Ammonium Nitrate XXXX Classification (67/548/EEC) O; R 8 Xi; R36 Classification (REGULATION (EC) No 1272/2008) Ox. Sol. 3; H272 Eye Irrit. 2; H319 Concentration [%] >= 10 - < 45 iron (II) sulfate XXXX Xn; R22 Xi; R36/38 Acute Tox. 4; H302 Eye Irrit. 2; H319 Skin Irrit. 2; H315 >= 1 - <= 2 N,N''- (isobutylidene)diurea >= 10 - <= 45 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice : Wash hands with water as a precaution. If inhaled In case of skin contact In case of eye contact If swallowed : If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On inhalation of decomposition products: In case of lung irritation, first treatment with dexametason aerosol (spray). Keep patient calm, remove to fresh air, seek medical attention. : Wash off with plenty of water. : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. : Clean mouth with water and drink afterwards plenty of water. 2/14 Print Date:

3 4.2 Most important symptoms and effects, both acute and delayed Symptoms : Ingestion may provoke the following symptoms: Methaemoglobinemia 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water : Foam Dry chemical Carbon dioxide (CO2) Sand 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Can decompose at above 100 C. Thermal decomposition products: Nitrogen monoxide, nitrogen dioxide, dinitrogenoxide, ammonia Isobutyraldehyd 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Keep away from children. 6.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. Retain and dispose of contaminated wash water. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Use mechanical handling equipment. 6.4 Reference to other sections none 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Protect from contamination. Keep away from direct sunlight. 3/14 Print Date:

4 Protect against heat. Protect from moisture. Advice on protection against fire and explosion : The product is not flammable. Keep away from sources of ignition - No smoking. Keep away from combustible materials. Keep away from heat. Risk of explosion if heated under confinement. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : When stored loose do not mix with other fertilizers. Store well away from other substances. Keep away from direct sunlight. Protect against heat. Protect from contamination. Protect against humidity (product is hygroscopic and tends to cake or disintegrate) German storage class : 5.1C Ammonium nitrate and ammonium nitrate containing preparations 7.3 Specific end uses : Always read the label and product information before use. 8. Exposure controls/personal protection 8.1 Control parameters DNEL Ammonium Nitrate : End Use: Workers Potential health effects: Specific effects Exposure time: 1 d Value: 37,6 mg/m3 End Use: Workers Exposure routes: Skin contact Potential health effects: Specific effects Exposure time: 1 d Value: 21,3 mg/kg Exposure routes: Ingestion Potential health effects: Specific effects Exposure time: 1 d Value: 12,8 mg/kg Exposure routes: Ingestion Potential health effects: Specific effects Exposure time: 1 d Value: 12,8 mg/kg 4/14 Print Date:

5 Potential health effects: Specific effects Exposure time: 1 d Value: 11,1 mg/m3 iron (II) sulfate : End Use: Workers Exposure routes: Skin contact Potential health effects: Acute effects, systemic effects Exposure time: 24 h Value: 2,8 mg/kg End Use: Workers Potential health effects: Acute effects, systemic effects Value: 9,9 mg/m3 End Use: Workers Exposure routes: Skin contact Potential health effects: Chronic effects, systemic effects Exposure time: 24 h 2,8 mg/kg End Use: Workers Potential health effects: Chronic effects, systemic effects Value: 9,9 mg/m3 Exposure routes: Ingestion Potential health effects: Acute effects, systemic effects Exposure time: 24 h 1,4 mg/kg Exposure routes: Skin contact Potential health effects: Acute effects, systemic effects Exposure time: 24 h 1,4 mg/kg Potential health effects: Acute effects, systemic effects Value: 2,5 mg/m3 Exposure routes: Ingestion Potential health effects: systemic effects, Chronic effects Exposure time: 24 h 1,4 mg/kg Exposure routes: Skin contact Potential health effects: Chronic effects, systemic effects Exposure time: 24 h 1,4 mg/kg Potential health effects: Chronic effects, systemic effects 5/14 Print Date:

6 Value: 2,5 mg/m3 N,N''-(isobutylidene)diurea PNEC Ammonium Nitrate : End Use: Workers Exposure routes: Skin contact Potential health effects: systemic effects Value: 37,5 mg/m3 Continuous exposure End Use: Workers Potential health effects: systemic effects Value: 66,12 mg/m3 Continuous exposure Exposure routes: Skin contact Potential health effects: systemic effects Value: 18,75 mg/m3 Continuous exposure Potential health effects: systemic effects Value: 16,31 mg/m3 Continuous exposure Exposure routes: Ingestion Potential health effects: systemic effects Value: 9,375 mg/m3 Continuous exposure : Fresh water Value: 0,45 mg/l Marine water Value: 0,045 mg/l Ceiling Limit Value Value: 4,5 mg/l iron (II) sulfate : Water This product has no known eco-toxicological effects. Behaviour in waste water treatment plants Value: 2483 mg/l Fresh water sediment Value: mg/kg Marine sediment Value: mg/kg Soil Value: mg/kg N,N''-(isobutylidene)diurea : Fresh water Value: 0,5 mg/l Marine water Value: 0,05 mg/l Fresh water sediment 6/14 Print Date:

7 8.2 Exposure controls Value: 1,76 mg/l Marine sediment Value: 0,176 mg/l Soil Value: 10,7 mg/l Behaviour in waste water treatment plants Value: 640 mg/l Personal protective equipment Respiratory protection Hygiene measures : Breathing apparatus only if aerosol or dust is formed. : At the end of the shift the skin should be cleaned and skincare agents applied. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Retain and dispose of contaminated wash water. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Colour Odour : granular : various : odourless ph : ca. 6,2, Concentration: 100,00 g/l, 20 C Melting point/range Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapour pressure Relative vapour density Water solubility Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, dynamic Viscosity, kinematic : no data available : The product is not flammable. : soluble : not auto-flammable : > 130 C, To avoid thermal decomposition, do not overheat. 7/14 Print Date:

8 Explosive properties Oxidizing properties 9.2 Other information Bulk density : Not explosive : ca. 860 kg/m³ 10. Stability and reactivity 10.1 Reactivity Stable under recommended storage conditions Chemical stability No decomposition if stored and applied as directed., Decomposes on heating Possibility of hazardous reactions Hazardous reactions : Evolution of ammonia under influence of alkalies Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : Keep away from heat and sources of ignition. : oxidizable substances substances with an acid reaction alkaline reactive substances 10.6 Hazardous decomposition products Hazardous decomposition products : Nitrogen monoxide, nitrogen dioxide, dinitrogenoxide, ammonia Isobutyraldehyd 11. Toxicological information 11.1 Information on toxicological effects Product Acute oral toxicity : LD50: > mg/kg, rat Skin corrosion/irritation : rabbit, Result: non-irritant, OECD Test Guideline 404 Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Genotoxicity in vitro Carcinogenicity Reproductive toxicity Teratogenicity STOT - single exposure : rabbit, Result: non-irritant, OECD Test Guideline 405 : Result: non-sensitizing : Contains no hazardous ingredients according to GHS : Contains no ingredient listed as a carcinogen : No toxicity to reproduction : Contains no ingredient listed as toxic to reproduction : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. 8/14 Print Date:

9 Further information : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. : Danger of methaemoglobin formation., The product was not tested. The statement was derived from products of similar structure and composition. Components: Ammonium Nitrate : Acute oral toxicity : LD50: > mg/kg, rat, OECD Test Guideline 401 Acute inhalation toxicity : > 88,8 mg/l, No information available. Acute dermal toxicity : LD50: > mg/kg, rat, OECD Test Guideline 402 Skin corrosion/irritation : rabbit, Result: non-irritant, OECD Test Guideline 404 Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity : rabbit, Result: Irritant, OECD Test Guideline 405 : Result: Does not cause skin sensitization. Genotoxicity in vitro : Result: negative, OECD Test Guideline 471 Carcinogenicity Reproductive toxicity Teratogenicity : rat, Animal testing did not show any carcinogenic effects. : rat, Animal testing did not show any effects on fertility. : rat, Did not show teratogenic effects in animal experiments. : rat, Oral, Exposure time: 28 d, NOAEL: > mg/kg : rat, Oral, Exposure time: 52 w, NOAEL: = 256 mg/kg, OECD Test Guideline 453 : rat, by inhalation, Exposure time: 2 w, NOAEL: >= 185 mg/kg, Repeated Dose Inhalation Toxicity: 28-day or 14-day Study. iron (II) sulfate : Acute oral toxicity : LD50: > mg/kg, rat, OECD Test Guideline 401 Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization : LD50: mg/kg, rat, Calculation method : This information is not available. : LD50: > mg/kg, rat, Converted acute toxicity point estimate : Result: Skin irritation, OECD Test Guideline 404, Irritating to skin and mucous membranes : Result: Eye irritation, OECD Test Guideline 405 : Result: Did not cause sensitization on laboratory animals., OECD TG 429 : rat, Oral, Exposure time: 90 d, NOAEL: mg/kg, The product was not tested. The statement was derived from products of similar structure and composition. : rat, Oral, Exposure time: 49 d, NOAEL: 100 mg/kg : by inhalation, This information is not available. : Dermal, This information is not available. 9/14 Print Date:

10 : Remarks: No known effect. N,N''-(isobutylidene)diurea : Acute oral toxicity : LD50: > mg/kg, rat, calculated Acute dermal toxicity : LD50: > mg/kg, rat, OECD Test Guideline 402 Respiratory or skin sensitization Germ cell mutagenicity Genotoxicity in vitro Carcinogenicity Reproductive toxicity Teratogenicity STOT - single exposure : mouse, Result: Did not cause sensitization on laboratory animals., OECD Guideline 429 : In vitro tests did not show mutagenic effects : Animal testing did not show any carcinogenic effects. : Animal testing did not show any effects on fertility. : Did not show teratogenic effects in animal experiments. : Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. : Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. 12. Ecological information 12.1 Toxicity Product: Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae Toxicity to bacteria : LC50: > 100 mg/l, 96 h, Oncorhynchus mykiss (rainbow trout), OECD Test Guideline 203 : EC50: > 100 mg/l, 48 h, Daphnia magna (Water flea), Directive 84/449/EEC, C.2 : EC50: > 100 mg/l, 72 h, Scenedesmus subspicatus, DIN : EC0: ca. 640 mg/l, 16 h, Pseudomonas putida, activated sludge, no data available Components: Ammonium Nitrate : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae : LC50: > 100 mg/l, 96 h, Fish : EC50: 490 mg/l, 48 h, Daphnia : LC50: 490 mg/l : EC50: mg/l, 10 d, Selenastrum capricornutum (green algae) iron (II) sulfate : 10/14 Print Date:

11 Ecotoxicology Assessment Acute aquatic toxicity N,N''-(isobutylidene)diurea : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae Toxicity to bacteria : This product has no known eco-toxicological effects. : LC50: > mg/l, 96 h, Oncorhynchus mykiss (rainbow trout), OECD Test Guideline 203 : EC50: ca. 500 mg/l, 48 h, Daphnia magna, Directive 84/449/EEC, C.2 : EC50: > 500 mg/l, 72 h, Scenedesmus subspicatus, DIN : EC0: ca. 640 mg/l, Pseudomonas putida 12.2 Persistence and degradability Product: Biodegradability : Components: Ammonium Nitrate : Biodegradability : iron (II) sulfate : Biodegradability : N,N''-(isobutylidene)diurea : Biodegradability : 12.3 Bioaccumulative potential Product: Bioaccumulation : Components: Ammonium Nitrate : Bioaccumulation : iron (II) sulfate : Bioaccumulation : N,N''-(isobutylidene)diurea : Bioaccumulation : 12.4 Mobility in soil Product: Mobility Distribution among environmental compartments Physico-chemical removability no data available The methods for determining the biological degradability are not applicable to inorganic substances. The methods for determining the biological degradability are not applicable to inorganic substances. The product is miscible in water and readily biodegradable in both water and soil. Accumulation is not expected. Bioaccumulation is unlikely. Bioaccumulation is unlikely. Accumulation in aquatic organisms is unlikely. Bioaccumulation is unlikely. : no data available : Moderately mobile in soils : DOC reduction, ca. 85 %, OECD 301E/92/69/EWG, C.4-B, May be eliminated in purification plants 11/14 Print Date:

12 Components: iron (II) sulfate : Distribution among : Medium: Soil, immobile environmental compartments 12.5 Results of PBT and vpvb assessment Product: Assessment Components: iron (II) sulfate : Assessment N,N''-(isobutylidene)diurea : Assessment : This substance is not considered to be very persistent nor very bioaccumulating (vpvb)., This substance is not considered to be persistent, bioaccumulating nor toxic (PBT) Other adverse effects Product: Additional ecological information Components: iron (II) sulfate : Adsorbed organic bound halogens (AOX) : Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations., There is a high probability that the product is acute not harmful to aquatic organisms., information on:, Isodur : < 2 mg/kg 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Check if agriculture use is possible. Contact manufacturer. : Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport information 14.1 UN number Non-dangerous goods 14.2 Proper shipping name ADR / GGVS RID ADNR IMDG IATA-DGR 12/14 Print Date:

13 14.3 Transport hazard class ADR / GGVS RID ADNR IMDG IATA-DGR 14.4 Packing group Environmental hazards IMDG : Not a Marine Pollutant 14.6 Special precautions for user Not relevant 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Remarks 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Water contaminating class (Germany) : WGK 1 slightly water endangering Other regulations : TRGS 511 'Ammonium nitrate' 15.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this product. 16. Other information Full text of R-phrases referred to under sections 2 and 3 R 8 Contact with combustible material may cause fire. R22 Harmful if swallowed. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. Full text of H-Statements referred to under sections 2 and 3. H272 H302 H315 H319 May intensify fire; oxidiser. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 13/14 Print Date:

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