MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Product Trade Name: Revision Date: 02-Jan CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Trade Name: Synonyms: None Chemical Family: Organic acid Application: Reagent Manufacturer/Supplier Prepared By Halliburton Energy Services P.O. Box 1431 Duncan, Oklahoma Emergency Telephone: (281) Chemical Compliance Telephone: COMPOSITION/INFORMATION ON INGREDIENTS Substances CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA Citric acid % 3. HAZARDS IDENTIFICATION Hazard Overview May cause eye, skin, and respiratory irritation. 4. FIRST AID MEASURES Inhalation Skin Eyes Ingestion Notes to Physician If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Wash with soap and water. Get medical attention if irritation persists. In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Under normal conditions, first aid procedures are not required. Not Applicable Page 1 of 5

2 5. FIRE FIGHTING MEASURES Flash Point/Range (F): Min: > 200 Flash Point/Range (C): Min: > 93 Flash Point Method: Autoignition Temperature (F): Autoignition Temperature (C): Flammability Limits in Air - Lower (%): Flammability Limits in Air - Upper (%): Fire Extinguishing Media Special Exposure Hazards All standard firefighting media. Decomposition in fire may produce toxic gases. Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. NFPA Ratings: Health 1, Flammability 0, Reactivity 0 HMIS Ratings: Health 1, Flammability 0, Reactivity 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautionary Measures Use appropriate protective equipment. Environmental Precautionary Measures Procedure for Cleaning / Absorption Prevent from entering sewers, waterways, or low areas. Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove. 7. HANDLING AND STORAGE Handling Precautions Storage Information Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing before reuse. Store away from oxidizers. Store away from alkalis. Keep container closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Respiratory Protection Hand Protection Skin Protection Eye Protection Other Precautions Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation. Dust/mist respirator. (N95, P2/P3) Impervious rubber gloves. Rubber apron. Chemical goggles; also wear a face shield if splashing hazard exists. Eyewash fountains and safety showers must be easily accessible. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Yellow Odor: Odorless ph: 1.3 Page 2 of 5

3 9. PHYSICAL AND CHEMICAL PROPERTIES Specific 20 C (Water=1): C (lbs./gallon): 9.41 Bulk 20 C (lbs/ft3): Boiling Point/Range (F): 219 Boiling Point/Range (C): 103 Freezing Point/Range (F): Freezing Point/Range (C): Vapor 20 C (mmhg): Vapor Density (Air=1): Percent Volatiles: <50 Evaporation Rate (Butyl Acetate=1): Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): VOCs (lbs./gallon): Viscosity, 20 C (centipoise): Viscosity, 20 C (centistokes): Partition Coefficient/n-Octanol/Water: Molecular Weight (g/mole): STABILITY AND REACTIVITY Stability Data: Hazardous Polymerization: Conditions to Avoid Incompatibility (Materials to Avoid) Hazardous Decomposition Products Additional Guidelines Stable Will Not Occur None anticipated Strong oxidizers. Strong alkalis. Carbon monoxide and carbon dioxide. Not Applicable 11. TOXICOLOGICAL INFORMATION Principle Route of Exposure Inhalation Skin Contact Eye Contact Ingestion Aggravated Medical Conditions Chronic Effects/Carcinogenicity Other Information Eye or skin contact, inhalation. May cause respiratory irritation. May cause skin irritation. Causes severe eye irritation which may damage tissue. Irritation of the mouth, throat, and stomach. None known. No data available to indicate product or components present at greater than 1% are chronic health hazards. None known. Toxicity Tests Oral Toxicity: Dermal Toxicity: Inhalation Toxicity: Page 3 of 5

4 Primary Irritation Effect: Carcinogenicity Genotoxicity: Reproductive / Developmental Toxicity: 12. ECOLOGICAL INFORMATION Mobility (Water/Soil/Air) Persistence/Degradability Readily biodegradable Bio-accumulation Ecotoxicological Information Acute Fish Toxicity: Acute Crustaceans Toxicity: Acute Algae Toxicity: Chemical Fate Information Other Information 13. DISPOSAL CONSIDERATIONS Disposal Method Contaminated Packaging Disposal should be made in accordance with federal, state, and local regulations. Follow all applicable national or local regulations. 14. TRANSPORT INFORMATION Land Transportation DOT Canadian TDG ADR Air Transportation ICAO/IATA Sea Transportation IMDG Page 4 of 5

5 Other Transportation Information Labels: None 15. REGULATORY INFORMATION US Regulations US TSCA Inventory EPA SARA Title III Extremely Hazardous Substances EPA SARA (311,312) Hazard Class EPA SARA (313) Chemicals EPA CERCLA/Superfund Reportable Spill Quantity EPA RCRA Hazardous Waste Classification California Proposition 65 MA Right-to-Know Law NJ Right-to-Know Law PA Right-to-Know Law All components listed on inventory or are exempt. Acute Health Hazard This product does not contain a toxic chemical for routine annual "Toxic Chemical Release Reporting" under Section 313 (40 CFR 372).. If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA. All components listed do not apply to the California Proposition 65 Regulation. Canadian Regulations Canadian DSL Inventory All components listed on inventory or are exempt. WHMIS Hazard Class E Corrosive Material 16. OTHER INFORMATION The following sections have been revised since the last issue of this MSDS Additional Information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. ***END OF MSDS*** Page 5 of 5