Teledyne s Series 6000 Microprocessor Controlled

Transcription

1 TELEDYNE ANALYTICAL INSTRUMENTS Teledyne s Series 6000 Microprocessor Controlled Ultraviolet Photometer is designed to provide continuous on-line analytical data of critical process conditions and eliminate time consuming laboratory analysis. This analyzer can be configured to measure at any wavelength within the ultraviolet or visible portions of the electromagnetic energy spectrum. Since numerous gases and liquids have a useful absorbance peak in the ultraviolet region, a wide variety of applications are possible. Advantages Dependable microprocessor-controlled Auto calibration and auto ranging Continuous real time analysis Eliminates time-consuming lab analysis Features analysis Microprocessor based, high resolution, ultra stable electronics (no potentiometers) Three user-selectable ranges Signal & Range ID output: 0-1 VDC and 4-20 madc (isolated) Programmable auto ranging Range ID contacts (quantity 4) Form A normally open contacts, 3A@250 VAC resistive Two adjustable concentration alarm set points with programmable relay function Form C contacts, 3A@250 VAC resistive Programmable auto calibration with mode ID Form A normally open contacts Remotely operated calibration (customer supplied valves and 24 VDC signal) Self diagnostics with Form C failure contacts Full duplex RS232 communication link Alphanumeric VF display for set-up and diagnostics Power: 115/230 VAC 50/60 Hz Series 6000 Ultraviolet Photometric Analyzer Principle of Operation The analyzer s optical path (figure 1) consists of a UV source, sample cell, and detector. A filter wheel located in front of the detector continuously rotates a reference and measuring filter in and out of the optical path. The material of interest continuously flows through the sample cell where the optical energy is absorbed at the various wavelengths in accordance with its composition. The analyzer utilizes the reference wavelength to compensate for extraneous phenomena (turbidity, dirt on optics, source drift, etc.) thereby producing a high degree of stability over long periods. Built for Reliability and Performance

2 TELEDYNE ANALYTICAL INSTRUMENTS MODEL 6650 Flourescence Probe Oil-in-Water Analyzer Teledyne s Model 6650 is comprised of a versatile transmitter and probe for monitoring oil-in-water in various refineries, power plants, and offshore platforms. The system incorporates state-ofthe-art electronics and a fiber optic based, in-situ probe that detects oil-in-water. Detection of oil-in-water in process boilers, cooling towers, refineries, and offshore platforms is an important measurement from an economic and environmental standpoint. This new technology from Teledyne makes this measurement simple, and reduces the cost of ownership. Because of its in-situ measurement capabilities, the Model 6650 analyzer offers real time analysis within a second. Features * Direct measurement; no interference from turbidity No spare part replacements required for 3 years Long life UV lamp Virtually no drift No inner filter error effects fluorescence technology. TAI also offers an automatic retractor as an option for cleaning the probe, depending upon the application. Model 6650 Transmitter Teledyne s 6650 uses a highly versatile transmitter that measures the signal from our probe and sends the signal back to the transmitter. This reading is based on the amount of optical attenuation from the fiber optic in-situ probe. The transmitter is compact and designed to connect to the probe via two fiber optic cables. A local digital display is provided and the transmitter offers a 4-20 ma output signal to other devices. In addition, the transmitter is equipped with automatic calibration checking. A reference filter is inserted into the measuring beam either locally or remotely to verify operation of the transmitter. Fiber Optic Probe The Model 6650 uses a fiber optic based, in-situ probe that monitors actual concentrations of oil-in-water using UV Built for Reliability and Performance

3 APPLICATIONS Pollution abatement programs involving effluent from refineries, chemical / petrochemical plants, oil fields, steel mills, automotive production, food processing, and other industries Offshore drilling platforms, produced water, oil field water flooding, steam injection operations On-board shipping (fast analysis required <10 seconds) On-shore deballasting discharges and ballast treatment facilities Boiler return, feedwater, steam condensate, cooling water, leak detection Monitoring of airport runoff, municipal water treatment plants Wastewater and sewage treatment plants Process stream monitoring SPECIFICATIONS Transmitter Measured parameter: Range of measurement: Temperature range: Response time: Long term output drift: Repeatability: Output linearity: Lamp: Model 6650 Oil-In-Water Analyzer Oil - in - water Application dependent -40 to +50º C < 1 sec < 2% signal loss / year 1% of range Linear for given Scale Indexes LED (10 year min. life guarantee) User Display & Control Type of display: Display format: Electrical Power requirement: LED display Power consumption: 0.48 Watts Analog outputs: Analog loop resistance: Alarms: 3-1/2 digits in user defined engineering units 24 VDC (9-32 VDC) if 110 / 220 VAC is available (optional) AC / DC power supply 4-20 ma isolated Optional 500 Ohms, 24V Area classification: Z-purge for Class I, Division 2; Mechanical Transmitter weight: X-purge for Class I, Division lbs Enclosure construction: Extruded aluminum (NEMA enclosures optional) 8 H x 3-7/8 W x 71-1/2 D Probe Materials: 316 SS or Hastelloy C Temperature rating: 315.5º C (600º F) Pressure rating: Probe options: 10,000 psig 1. 6, 12 or 24 in length 2. Temperature controlled 3. Temperature thermistor 4. Pressure strain gauge TELEDYNE ANALYTICAL INSTRUMENTS A Teledyne Technologies Company Chestnut Street City of Industry, California 91748, USA Warranty Instrument is warranted for 1 year against defects in material or workmanship NOTE: Specifications and features will vary with application. The above are established and validated during design, but are not to be construed as test criteria for every product. All specifications and features are subject to change without notice. TEL: or FAX: ask_tai@teledyne.com Teledyne Analytical Instruments, A Teledyne Technologies Company. All rights reserved. Printed in the USA. 11/05LD

4 Teledyne Analytical Instruments MODEL 6600 Oil in Water Analyzer System Redesigned with modularity and lower cost in mind Rack or cabinet mounted General purpose or explosion proof Teledyne s Model 660/661 has been the industry standard in oil-in-water analysis for 30 years. The microprocessor based 6600 / 6610 improves upon our proven analog circuitry and the sample handling system. The new, compact modern design incorporates many new features at a significantly reduced cost. Critical features include: Folded optical system optimized for excellent signal-to-noise ratio and stability Increased reliability by eliminating many moving parts New sonicator homogenizes oil (in-line) in water instantly (less than one second) Improved auto-zero filter system prepares zero fluid for calibration and zeroing without long sparging cycle Specially developed software with auto calibration features Automatic self-cleaning sample cell suitable for high pressure and temperature Manual calibrations done easily with collected zero fluid from sample system using the gravity fed reservoir Manual or automatic span sensitivity easily checked with internal span flag once field calibrated Faster response time Modular design configured to meet specific application requirements The 6600 utilizes the ultraviolet absorption principle to detect and continuously measure oil concentration in water with a reproducibility that exceeds standard laboratory techniques. The automated analysis system includes a single beam, dual wavelength, UV photometric analyzer that compensates for turbidity, algae, cell window coatings, and other optical attenuation. To assure accuracy, a unique conditioning system delivers a sample representative of the true oil content of the stream. A continuous ultrasonic homogenizer (figure 2) disperses all suspended oil droplets and oil absorbed into foreign matter so the sample, to the analyzer, appears to be uniform and in true solution. OIL DETECTION AND ANALYSIS The basic oil detection UV analyzers offered by other manufacturers are single wavelength photometers a "go / no go" instrument without a sample conditioning system. Teledyne feels these lack the sophistication necessary for reliable oil detection monitoring, preferring a dual wavelength design. Attenuation of energy transmission by turbidity and cell window deposits can then be distinguished from absorption despite the presence of oil. With sample conditioning (figure 1) and automatic zeroing, our analyzers produce a truly representative solution for analysis and can compensate for background absorption found in most oil-inwater applications. DUAL WAVELENGTH Recognizing the importance of eliminating the effects of turbidity and inherent electro-optical interferences, Teledyne developed a single sample cell, chopped beam, dual-wavelength photometric analyzer unmatched in reliability and accuracy. The 6600 has been extensively field tested to show excellent correlation with the EPA gravemetric reference method The system utilizes optical filters to isolate and make energy measurements at two specific wavelength bands. The UV measuring band (centered at 254 nanometers) is extremely narrow to avoid side-band interference. A reference signal is generated at a selected wavelength region where oil does not absorb significantly. This signal is effected by the aforementioned interference as well as by absorption due to the presence of oil. Components contributing to total absorption in a typical water effluent sample are shown in figure three. Turbidity and electrooptical interferences are removed by the analyzer s design, and non-oil background is zeroed out. Since both the measuring and reference wavelengths are generated at the end of the transmission system, electro-optical interference (cell window coating, variations in source lamp, aging of detector and other electronics) effects each signal equally. The output signal is obtained by electronically generating the logarithm of the ratio of the measuring signal to the reference signal. Therefore, the output signal, linear with absorption, shows little or no affect from turbidity. Additionally, electro-optical stability is enhanced by the dual wavelength design.

5 AUTOMATIC ZERO MODE The 6600 offers an automatic zeroing feature, permitting a continuous analysis specific for oil without interference. The zeroing mode technique (application dependent) is accomplished by the automatic preparation (filtering) and periodic analysis of an oil-free fluid which contains the compounds contributing to background absorption. When this fluid is analyzed, the background absorption is measured and then zeroed out. The cycle is automatically repeated once each hour to update the oil analysis by correcting for fluctuations. This allows for a more accurate analysis of oil and grease content specifically separated from other non-oil organics that many times are also present in effluents. For very clean processes like steam or boiler return condensates, only oil free nitrogen (N 2 ) gas or air can be used for electro-optical energy background variations such as from normal source or detector anomalies over time. FIGURE 2 ZERO FLUID HOMOGENIZED SAMPLE TURBIDITY UNDISSOLVED OIL "ZERO" DISSOLVED OIL NON-OIL ORGANIC BACKGROUND PURE H 2 0 FIGURE 3 UNHOMOGENIZED HOMOGENIZED Homogenizer Function The effect of homogenization on the sample is illustrated above. Both the particulate oil and the compounds representing turbidity are of random size. Homogenization causes the oil droplets to be dispersed to such a particle size that, to the analyzer, they appear to be in true solution. Oil absorbed upon or contained within the portion represented by turbidity is also placed into solution along with the particulate oil. Turbidity has no characteristic absorption and is ratioed to zero by the analyzer. Fractions contributing to total absorption in typical water effluent The homogenized sample contains all components of the effluent stream. The UV analyzer measures the stream fractions as non-oil background, dissolved oil, and non-dissolved oil. Turbidity will be ratioed out and give no reading. The analyzer will measure the zero fluid as the non-oil fraction. Turbidity and oil have been removed from the zero fluid by coarse and ultrafine filtering. Coarse filtering removes the non-dissolved oil, while ultra-fine filtering removes the lighter dissolved oils. During the zero cycle, the analyzer is automatically adjusted to read zero. The non-oil UV absorbing background is subtracted from the total UV reading. APPLICATIONS Pollution abatement programs involving effluents from refineries, chemical / petrochemical plants, oil fields, steel mills, automotive production, food processing, and other industries Offshore drilling platforms, produced water, oil field water flooding, steam injection operations On-board shipping (fast analysis required < 10 seconds) On-shore deballasting discharges and ballast treatment facilities Boiler return, feedwater, steam condensate, cooling water, leak detection Monitoring of airport runoff, municipal water treatment plants Wastewater and sewage treatment plants Process stream monitoring Aromatic hydrocarbons like benzene, toluene, styrene, xylenes in water FEATURES Specific to oil (correlates to EPA 413.1) Microprocessor based electronics Auto calibration Remotely initiated cal / zero via customer supplied 24 VDC signal Self-diagnostics with Form C relay contacts Ratio measurement Continuous measurement Total oil readout standard, undissolved oil readout possible (with autozero filtering option) Integral alarms Self-cleaning cell Automatic turbidity compensation Full duplex RS-232 communication link Process pressure up to 150 PSIG (higher pressure possible application dependent) Sample temperature to 120 C (higher temperatures possible, application dependent) Response time under 5 seconds possible (application dependent) NEMA-4x (stainless steel standard) mounted control unit

6 SAMPLE CONDITIONING Factors associated with undissolved oil and background absorption are eliminated by sample conditioning. The 6600 incorporates conditioning components that prepare the sample so both undissolved and dissolved oils are detected and measured. A new, in-line, high frequency (20 khz) ultrasonic homogenizer minimizes the size of the oil droplets suspended while dispersing them into a more uniform molecular level in the sample so they can be measured accurately. For any photometric analytical technique measuring oil in water above 20 ppm oil requires this homogenization. Oil absorbed onto the particulate matter in the sample is also dispersed by the homogenizer. Since the response of particulate matter as a possible attenuator is automatically neutralized by the optical system and ratioed to zero by the electronics of the photometer, the characteristic absorption of the total oil can be measured. The output signal or meter readout is linearly proportional with total oil concentration. OIL AND GREASE Many environmental applications (as monitored by regulatory agencies) allow certain minimal levels of dissolved oil to remain in the water measured. The 6600 (when ordered specifically to do so) can monitor for total oil and grease recoverable or be easily switched to monitor the undissolved oil portion only. This minimizes the customer s costly requirement in energy to process water below a minimum oil concentration as dictated by local regulations before out-flowing the water as an effluent. COMPENSATION FOR BACKGROUND Many applications require compensation for background absorption due to the presence of non-oil organic and inorganic compounds that absorb UV energy. Furthermore, the concentration of these compounds will likely fluctuate, specifically in applications with multiple non-oil organics and inorganic compounds present in the background. In order to obtain an analysis specific to oil, the background absorption contributed by these compounds must be eliminated and zeroed out. The 6600 does exactly this. FIGURE 1 ZERO & SPAN IN BY-PASS BACK PRESSURE REGULATOR PSI IN F2 BY-PASS FLOWMETER LPH SAMPLE IN (2-5 LPM) GPH 15' WATER VACUUM UTILITY V1 3-WAY VALVE C BPR1 P IN V2 PUMP (2-5 LPM) GPH V10 HOMOGENIZER FC1 FLOW CONTROLLER F1 SAMPLE FLOWMETER 0-30 LPH SV2 V6 C C IN C C V5 OUT CELL BLOCK SAFETY BLOCK VALVE V7 SV1 SV3 C GRAB SAMPLE V3 SV4 SAFE VENT N2 OR AIR 90 TO 100 PSIG RETURN F1 C FILTER 3.0 MICRON V4 FILTER 0,2 MICRON F2 F3 V9 V8 NOTES: UNLESS OTHERWISE SPECIFIED. 1. USE HOMOGENIZER AND FILTER ASSEMBLIES FOR HIGH RANGE, HIGH BACKGROUND 2. USE FILTER ASSEMBLY FOR LOW RANGE, HIGH BACKGROUND 3. USE BACKFLUSH SOLENOIDS FOR LOW RANGE, VERY LOW BACKGROUND 4. USE PUMP ASSEMBLY FOR LOW PRESSURE OR NO GRAVITY FEED Sample Conditioning System A sample is fed through a V1 sample / utility valve, then through a split tee; one side as a bypass loop, the other through an inline ultrasonic homogenizer. This disperses any oil in the sample before measurement including small or large oil droplets and oil absorbed on foreign particles. A portion of the stream is conditioned to remove all oil, both dissolved and undissolved, without altering the background (boiler additives or other inorganic compounds.) When this portion is delivered to the analyzer (through SV3), the analyzer subtracts the background from the total and reads out total oil only. The analyzer is manually calibrated with a known standard on a one time basis through the indicated zero and span inlet reservoir. The specially designed sample cell can interface with process fluids up to 150 psig and 120 C (248 F)

7 OIL IN WATER ANALYZER SYSTEM Series SPECIFICATIONS Range: Noise: Zero drift: Accuracy: Reproducibility: Linearity: Power Ambient Sample Sample Signal output: Alarms: 0-10 ppm up to ppm oil in water (application dependent) Less than 1% of full scale Corrected by automatic zero Dependent upon variability of oil composition; ±2% of full scale when calibrated against same oil as being analyzed ± 1% of full scale or better ± 1% of full scale or better 115 VAC 50/60 Hz; requirements: 230 VAC, 50/60Hz (specify) 0 to 50 C; may be heated or cooled to temperature: operate in other temperatures 1 to 120 C, nominal (non-freezing), temperature: lower temperatures possible with salt waters 0 to 150 PSIG (an optional pump can be pressure: supplied when no gravity feed or sample pressure is available) Analytical measurement, 0-1 VDC and isolated 4-20 madc Dual fully adjustable concentration alarm set points with programmable relay function. OPTIONAL MODULES Homogenizer Module A high frequency (20 khz) ultrasonic homogenizer is used to minimize the size of the oil droplets while dispensing them in the sample so they can be measured accurately. Measuring samples above 20 ppm typically require this module. Filter Assembly Module required for applications with high background interference Pump Module required for applications with low pressure or no gravity feed Purge Module Z purge unit or X purge unit CONFIGURATIOßNS General purpose Class I, Div. 2, Groups B, C & D Class I, Div. 1, Groups B, C & D CE mark, CENELEC certified Data lines: Readout: Form C contacts, 3A resistive; selfdiagnostics with Form C failure alarm contact Bi-directional RS-232C serial interface Two line alphanumeric vacuum florescent display 0-10 ppm oil-in-water monitoring system for boiler / steam condensate application TELEDYNE ANALYTICAL INSTRUMENTS A Teledyne Technologies Company Chestnut Street City of Industry, California 91748, USA Warranty Instrument is warranted for 1 year against defects in material or workmanship NOTE: Specifications and features will vary with application. The above are established and validated during design, but are not to be construed as test criteria for every product. All specifications and features are subject to change without notice. TEL: or FAX: ask_tai@teledyne.com Teledyne Analytical Instruments, A Teledyne Technologies Company. All rights reserved. Printed in the USA. 11/05LD

8 E Features Teledyne Analytical Instruments Teledyne s 6400E uses a proven UV fluorescence principle coupled with state-of-the-art microprocessor technology to provide accurate and dependable measurements of low level S02. U V F l u o r e s c e n c e S O 2 A n a l y z e r Ranges are 0-50 ppb to 0-20 ppm, user selectable Dual ranges and auto ranging Microprocessor controlled for versatility Multi-tasking software allows viewing test variables while operating Continuous self checking with alarms Dual bi-directional RS-232 ports for remote operation (optional RS-485 or Ethernet) Digital status outputs indicate instrument operating condition Adaptive signal filtering optimizes response time Temperature and pressure compensation Internal Zero & Span check (optional) Internal data logging with 1 min to 365 day multiple averages Critical orifices provide flow stability 6400E Schematic Exceptional stability is achieved with the use of an optical shutter to compensate for PMT drift and a reference detector to correct for changes in UV lamp intensity. A hydrocarbon kicker and advanced optical design combine to prevent inaccuracies due to interferents. The multi-tasking software gives real time indication of many operational parameters and provides automatic alarms if diagnostic limits are exceeded. Advanced Performance The 6400E includes a built-in data acquisition capability using the analyzer s own internal memory. This allows the logging of multiple parameters including averaged or instantaneous concentration values, calibration data and operating parameters such as flow, pressure and lamp intensity. Stored data are easily retrieved through the serial port or optional Ethernet port via our software or from the front panel, allowing operators to perform predictive diagnostics and enhanced data analysis by tracking parameter trends. The 6400E combines lighter weight, rugged construction, ease of use, powerful diagnostics, modular design and outstanding performance to meet air monitoring requirements. Applications Detect low trace levels of SO2 in medical air and medical oxygen to satisfy USA and European pharmacopeia requirements. Detect trace levels of H2S in methane-rich Bio-Gas streams used as the feed for fuel cell power generation devices. The H2S impurities, which can poison the platinum based catalyst, are converted into SO2 on a 1:1 basis via Teledyne s THC converter. The resultant converted sample gas is then fed to the 6400E for continuous analysis purposes.

9 6400E FLUORESCENT SO2 ANALYZER SPECIFICATIONS Ranges: Units: Zero noise: Span noise: 0-50 ppb to 0-20,000 ppb full scale, user selectable; dual ranges and auto ranging supported ppb, ppm, µg/m3, mg/m3 <0.2 ppb (RMS) <0.5% of reading (RMS) above 50 ppb Lower Detectable Limit (LDL): 0.4 ppb Zero drift: <0.5 ppb / 24 hours, <1 ppb / 7 days Span drift: <0.5% of FS / 24 hours, <1% of FS / 7 days Lag time: 20 seconds Rise and Fall time: <120 seconds to 95% Linearity: 1% of full scale Precision: 0.5% of reading above 50 ppb Sample flow rate: 700 cm3 / min ±10% Operating temp range: 5-40 C (with EPA equivalency) Dimensions (HxWxD): 7 (178 mm) x 17 (432 mm) x 23.5 (597 mm) Weight: 35 lbs (16 kg) Power: 100V - 120V, 220V - 240V, 50/60 Hz, 250W Analog outputs: 10V, 5V, 1V, 0.1V, selectable Recorder offset: ±10% Serial outputs: Serial Port 1: RS-232 (DB-9M); Serial Port 2: standard RS-232 or optional RS-485 (DB-9F), Ethernet Status (digital): 8 outputs, 6 inputs (opto-isolated), 6 alarm outputs (optional) Current output: Optional 4-20mA, select up to three channels Approvals: USEPA EQSA , MCERTS certified Sira MC050067/00 CONFIGURATION Selectable voltage Internal pump Auto ranging and dual ranges 47mm diameter particulate filter 8 isolated digital status outputs Dual bi-directional RS-232 Specified AC voltage and frequency 100V - 115V or 220V - 240V 50 Hz or 60 Hz Output DC voltage: 10V 5V 1V 0.1V OPTIONAL EQUIPMENT Rack mount brackets (19 ) with chassis slides Rack mount brackets only 4-20mA outputs (specify up to three channels) Multi-drop RS-232 connection Ethernet port includes 7 ft. CAT-5 cable (disables one serial port) NOx optical filter (recommended for high NOx applications) Calibration options: -TFE valves for selection of customer-supplied zero and span gas - Internal zero and permeation tube oven for calibration check; requires perm tube (separate option) ACCESSORIES RS-232 Cable Expendables Kit Spare Parts Kit NOTE: The values expressed above are in accordance with EPA definitions. All error specifications are based on constant conditions. Specifications exceed US EPA and Eignungsgeprüft requirements. TELEDYNE ANALYTICAL INSTRUMENTS A Teledyne Technologies Company Chestnut Street City of Industry, California 91748, USA Warranty Instrument is warranted for 1 year against defects in material or workmanship NOTE: Specifications and features will vary with application. The above are established and validated during design, but are not to be construed as test criteria for every product. All specifications and features are subject to change without notice. TEL: or FAX: ask_tai@teledyne.com Teledyne Analytical Instruments, A Teledyne Technologies Company. All rights reserved. Printed in the USA. 05/06LD

10 TELEDYNE ANALYTICAL INSTRUMENTS FOR CO2 Purity Quality Monitoring Total Sulphides Analyzer

11 The need to continuously detect for sulfides in carbon dioxide has become increasingly important within the food and beverage market. Gas suppliers must ensure that the CO2 they provide for use in the preservation of food and drink related products meet today s exacting standards. The contamination of carbon dioxide can emanate from many sources and therefore it is essential that the CO2 used for such purposes be monitored at the CO2 generator facility, at the beverage producer facility, or both. PRINCIPLE OF OPERATION The Model 6200E Total Sulfides Analyzer utilizes proven UV fluorescent technology to continuously detect sulfides found in inert gas streams. An internal, quartz catalytic converter is employed to convert the sulfides, when mixed with scrubbed ambient air, into SO2 via high temperature oxidation. An internal vacuum pump is employed to draw both the sample and the ambient air into the converter. The converted sample gas is fed to the fluorescence chamber where it is then exposed to ultra-violet radiation. The measurement process in the reaction cell is described by the following equation: SO2 + hu1 d SO2* SO2* d SO2 + hu2 Where hu1 is the incident UV energy at 214nm and hu2 is the resultant fluorescence, which is directly proportional to the SO2 concentration in the reaction cell. The fluorescence emission is in turn sensed by the photo-multiplier tube (PMT) and amplified to provide an analog output. The result is a continuous measurement of total sulfides (i.e. H2S, CS2, COS, mercaptans, etc.) as SO2 from 0-50 ppb to 0-20 ppm. Model 6200E basic configuration

12 ELECTRONICS PLATFORM The 6200E combines the proven UV fluorescence principle with state of the art microprocessor technology to provide accurate and dependable measurement of trace levels of total sulfides. Long term stability is obtained by the use of an optical shutter to compensate for zero drift, coupled with lamp reference detector to correct for lamp drift. The multi-tasking microprocessor allows easy field ranging from 50 ppb to 20 ppm as well as providing on-line indication of instrument status. The 6200E is continuously checking operating parameters and provides alarms on out of specification conditions, including electrical and optical parameters. The easy to read display, intuitive menu structure, and ease of operation combine to make the 6200E the instrument of choice for Total Sulfides applications. The instrument includes a built-in data acquisition capability, utilizing the analyzers internal RAM. This allows logging of the measured variable concentration as well as other parameters such as calibration data, flow rates, lamp intensities or a variety of other configurable parameters. This provides the operator the ability to perform predictive diagnostics by tracking parameters over time. This stored data is available through an RS- 232C port on either an automatic timed or manual manner. THE COMPONENTS The 6200E comes complete with three 19 inch relay rack modules - the Sample Converter Module, the Analysis Module, and a Calibration Module. The Sample Converter Module comes with an SO2 scrubber, sample / ambient air filters, high temperature dilution control orifice box, and Total Reduced Sulfur (TRS) converter. The Analysis Module consists of the UV fluorescence analyzer, pressure and flow transducers, and vacuum pump. The Calibration Module consists of restrictor / orifice flow regulators and flow control system, all provided in a temperature controlled setting to ensure accurate performance. The two inlet ports allow use of two independent calibration gases which may be diluted to provide the required span gas concentration. Dilution ratios from 20:1 to 300:1 are manually set from the front panel. FEATURES High sensitivity with user selectable ranges from 0-50 ppb to 0-20 ppm Microprocessor controlled, providing advanced user interface capabilities Built-in data acquisition capability using the analyzer s own RAM Extremely high-end self diagnostic capability providing continuous self checking with continuous warning alarms Bi-directional RS-232C for remote operation Critical orifices provide flow sensitivity High temperature TRS converter Digital status outputs provide instrument condition Easy to read display Proven UV fluorescence technique

13 6200E Total Sulphides Analyzer SPECIFICATIONS Ranges: Zero noise: Span noise: LDL: Zero drift**: 0-50 ppb to 0-20,000 ppb full-scale, user selectable Dual ranges and auto-ranging supported < 0.2 ppb < 0.5% of reading (above 50 ppb) 0.4 ppb < 0.5 reading / 24hrs; 1 ppb / 7 days Span drift**: < 0.5% reading / 24 hrs; 1% of reading / 7 days Lag time: Rise time (95%): Linearity: 20 secs < 120 secs 1% of full scale Sample flow rate: 700 cc/min ± 10% Converter temperature: 1000 C Converter efficiency: > 98% above 0 C dewpoint Size (H x W x D): **At constant conditions ADDITIONAL OPTIONS Model 6200E analyzer: (7 x 17 x 23.5 ) (177.8 x 432 x mm) Dilutor / Converter module: (7 x 17 x 23.5 ) (177.8 x 432 x mm) Calibration module: (5.25 x 17 x 23.5 ) (133.3 x 432 x mm) Fluorocarbon zero / span valves 19 rack mount brackets 19 rack mount with chassis sliders 2 to 5 year warranty Converter life: 3000 ppm hours SOx scrubber efficiency: > 98% SOx scrubber life: > 1000 ppm hours Analyzer operating temperature: 5 to 40 C Power: 100 Vac 240 Vac, 50/60 Hz (user specified) Outputs: Analog: 10 V, 5 V, 1 V, 100 mv (selectable) (4-20mA isolated output optional) RS232 (I/O): Standard DB9 Contact Teledyne for details on our Carbon Dioxide Quality Control (CDQC), which is a turn-key system capable of detecting: Total Sulphides (UV Total Hydrocarbons Trace Moisture (AI2 O3) Trace Oxygen (Electrochemical) CO2 Purity (NDIR) Digital status: 12 contact closure outputs TELEDYNE ANALYTICAL INSTRUMENTS A Teledyne Technologies Company Chestnut Street City of Industry, California 91748, USA Warranty Instrument is warranted for 1 year against defects in material or workmanship NOTE: Specifications and features will vary with application. The above are established and validated during design, but are not to be construed as test criteria for every product. All specifications and features are subject to change without notice. TEL: or FAX: ask_tai@teledyne.com Teledyne Analytical Instruments, A Teledyne Technologies Company. All rights reserved. Printed in the USA. 05/06 LD

14 Process Photometers PUV3402 and PIR3502 Continuous Measurements VistaNET Connectivity Multiple Component Samples Measures Vapor or Liquid Samples Operates in IR, NIR, UV and VIS Regions Fiber Optic Option for NIR Applications Multiple Interference Compensation Capability Analyze IT Field IT Control IT Engineer IT Field IT Inform IT Operate IT Power IT Industrial IT

15 UV/VIS/NIR Fiber Optics Option Cell-In-Oven Sample System The PFO3502 Multiwave offers a fiber optic option for applications that require remote sampling capability. With this option, light is transmitted via one waveguide to the remote sample cell. A second waveguide is used to return the sample-modified light to the detector. This Fiber Optics option is effective in UV/Visible/NIR applications where: The sample stream is highly toxic. Corrosive products are analyzed. Fast response time is required. The sample is at high pressure. The Multiwave Cell-In-Oven design provides a simple and effective package for high temperature applications. The major benefit of this design is that the sample cell and sample handling components are together in one common temperature controlled enclosure. The elimination of heat trace requirements for sampling lines minimizes the risk of cold spots. This design also offers excellent accessibility for fast cell removal during maintenance. Performance Specifications Precision: ±1% of full scale Noise: ±1% of full scale at 0.02 absorption units ± 0.5 % of full scale at 0.20 absorption units Linearity: Standard ± 2 % of full scale Zero Drift: ± 0.5 % of full scale per day for IR; ± 1.0 % of full scale per/day for UV Response Time: Programmable Ambient Electronic Stability: ±1% of full scale for 18 F (10 C) in 4 hours Operating Specifications Wavelength Range: Ultraviolet nm Visible nm Near Infrared nm Fundamental Infrared um. Ambient Temperature Range: 32 to 113 F (0 45 C) Max. Cell Heat: 302 F (150 C) Electric Cell Heat: Power Consumption 450 watts maximum (temperature is application dependant) Sample Flow Rate: Typical cc/min for vapors; cc/min for liquids Sample Pressure: PSIG (0 34 bar) Voltage Input Variation: 10 % fluctuation without causing an output variation of 0.05 % of full scale Electrical Power To Analyzer: 100/115/220/230 VAC, HZ, 150W, Maximum Power Consumption 600W With Electric Heat Instrument Air Supply for Enclosure Purge (Safety): Pressure psi (3 6 bars) Flow Rate 0.5 CFM (15L/min.) Optical Purge, typically nitrogen: psi (1 2 bar) Flow Rate cc/min General Installation Protect the instrument from direct sunlight and rain at operating temperature between F (0 45 C) Dimensions Weight: approximately 80 lbs (36.28 kg) Height: 13.5 inches (342.9 mm) Depth: 10.5 inches (266.7 mm) Width: 10 inches (254 mm) per module Overall Length: (based on cell pathlength) Minimum 26.8 inches (681.4 mm) for 0.5 to 16 mm cell Maximum 65.5 inches (1665 mm) for 1 meter cell Tube Fittings Sample Inlet/Outlet: Metallic Cells Teflon Cell Size: 1/4" 1/8" Brand: Standard Gyrolok Gallek or Fluorocarbon (Swagelok available) Material: 316 SS Teflon Hastelloy C, Monel Purge Inlet and Outlet: Metal Cell Size: 1/4" NPT-F Brand: Gyrolok Material: 316 SS Power: Size: 18 AWG, 3/4" Conduit Hub Type: 3 conductors each Output Signals Analog Outputs: 4 ea ma isolated into 600 ohms max. Contact Closures: 2 ea. Relay, 3W at 0.25 A or 28 VDC, 5 ea. isolated solid state. Both relay and solid state contact closures N.O. or N.C. Digital Inputs: 8 ea., 2 ea. are dedicated Digital Outputs: 4 ea., 110 VDC, 25 watts ea., max. standard, 110 VDC, 24 VDC optional. Area Classification NEC Class I, Groups B, C, D, Division 2 without enclosure purge; Division 1 with type Y-Purge; CSA Class I, Groups B, C, D, Division 2 with type Z-Purge; Division1 with type X-Purge (CSA ) CE Zone 2, II3G; EEx pz IIB+H2 T4 to T2; CE Zone 1, II2G; EEx pd [ib] IIB+H2 T4 to T2 (LCIE 03 ATEX 6007X)

16 Process Photometers PUV3402 and PIR The Next Generation of On-Line Process Photometers. Multiwave Process Photometers are designed to provide on-line measurements of gas or liquid components, in simple or complex process streams, for process control, product quality assurance, safety, catalyst protection and area monitoring. The Multiwave is a fixed filter photometer that utilizes optical filters to make continuous measurements. The single beam, dual wavelength concept used in the Multiwave compensates for source and detector aging and the obstruction of cell windows, while allowing the sample cell to be isolated from the electronics. The Multiwave design takes the single beam, dual wavelength concept one important step further, by adding up to eight filters to the filter wheel. This improved method provides more measurement solutions than a conventional single component process photometer. The use of multiple wavelengths enables the Multiwave to compensate for numerous interferences and perform multiple component applications. The new Multiwave Process Photometers offer even more performance, operating efficiency and versatility to the user. The Multiwave line features two basic models, each offering a wide range of applications capability. PIR3502 Multiwave Photometers can be applied to Infrared and Near Infrared measurements. PUV3402 Multiwave Photometers are designed for the Ultraviolet and Visible spectral regions. Multiwave Photometers can be connected to ABB Analytical s VistaNET Process Analyzer Network, enabling data interchange from the analyzer to the DCS, seamless connectivity to the Plant LAN and remote user access. With the addition of VistaNET, all operator functions may be performed at the analyzer or from a remote PC. Optical Schematic

17 Multiwave Process Photometers Leading Applications* PIR3502 Multiwave Spectral Regions Infrared (IR) um Near Infrared (NIR) nm Visible (VIS) nm Ultraviolet (UV) nm Infrared: Near Infrared: PUV3402 Isocyanate in chloroaromatic solvent Ambient air monitoring Multicomponent monomers in polymer process Measurement of Hydrogenic Compounds (C-H, N-H, O-H) Water in organics, such as Ethylene Dichloride (EDC) Caustic in Acid Gas Scrubbers VistaNET Connectivity The VistaNET Process Analyzer Network is a local area network that supports data interchange from process analyzers to the Distributed Control System (DCS), in a dedicated and secured manner. VistaNET also provides seamless connectivity to the plant operating system (Plant LAN). Through the Multiwave Remote User Interface, the user can configure, operate, or troubleshoot the operation of the analyzer from a remote PC. With this remote access capability all operator functions may be performed. Visible: Ultraviolet: Remote configuration and observation of the Multiwave photometer, enabling technicians to use their time more efficiently. Graphic display of Absorbance vs. Concentration data, allowing the user to check the validity and linearity of calibration samples. Remote maintenance via modem multiple users can view data simultaneously and work together in troubleshooting activities. Color Measurements (ASTM, APHA, Saybolt Color Units) Multiple Wavelengths in Glycol Process Chlorine in Phosgene *Consult our Multiwave Applications Brochure for more details. Reports and Tables can be printed and reviewed at remote locations. And VistaNet is designed for use with widely used and accepted PC hardware and operating systems, including Windows 95, 98 and NT, TCP/IP and other protocols. Connecting to other network operating systems is simple and very economical*. *Consult our VistaNET Brochure for more details. Multiwave TM Process Photometer

18 Designed for Reliability and Performance PUV3402 and PIR3502 Multiwave Process Photometers are designed to meet all the significant challenges of the process environment, including ambient temperature variation, moisture, corrosive and explosive stream compositions, electrical hazards, dust and vibration. Accessibility Every major component may be easily removed and replaced, significantly reducing maintenance time. Solid State Detectors The PIR3502 and PUV3402 use solid state detectors. These detectors are thermally stable and insensitive to vibration. They require no mechanical adjustment and minimal interconnecting circuitry. They provide excellent linearity and long service life. Brushless Chopper Motor Provides good mechanical reliability and long service life. Linearizer Circuit with Up to 8 Points Ensures a ± 2 % of full scale linearity and allows the user to select the best accuracy for a specific range. Isolated Sample Cell Prevents flammable and corrosive streams from contacting electronics, permits cell heating to optimum sample conditions, allows easy access and optimum optical pathlength selection. Self-Aligning Optics Saves time during maintenance operations. Temperature Controlled Filter Assembly Eliminates temperature effects on filters, improving long term stability. Electric Cell Heating Concept The first ever Division 1/Zone 1 electrically heated sample cell. Employs a unique heat pipe concept that reduces temperature gradients across the cell, providing a more stable output and accurate temperature control. Data validation to ensure the reliability of Multiwave data. Self-diagnostics to aid in troubleshooting operations. Functional User Interface Direct user interface at the analyzer is simple and easy using the Multiwave 's front panel keyboard and display screen. And with built-in VistaNET capability, all operator functions may also be performed from a remote PC. Multiwave TM Process Photometer

19 2005 ABB Inc. BUASC The Industrial IT wordmark and all mentioned product names in the form XXXXXX IT are registered or pending trademarks of ABB. ABB has Sales & Customer Support expertise in over 100 countries worldwide. The Company s policy is one of continuous product improvement and the right is reserved to modify the information contained herein without notice. ABB Inc. 843 N. Jefferson Street Lewisburg WV USA Office: Fax:

20 Series 6000 Ultraviolet Photometric Analyzer CONFIGURATIONS 6000: General purpose wall mount 6020: Totally explosion proof suitable for use in Class I, Division 1, Groups B, C & D Alternate configurations are available; contact the factory. DETECTOR SAMPLE OUT MOTOR SAMPLE IN LENS SOURCE SPECIFICATIONS Noise: < ± 1% Drift: Less than 1% per day Diurnal: Less than 1% per 20 F Accuracy: ± 1% of full scale Ambient: 32 F to 122 F (0-50 C) non-condensing Sample cell: Stainless steel with quartz window standard. Other materials available. Reproducibility: FILTER WHEEL Optical System (figure 1) ± 1% of scale or better Electronic response: 90% in 1 second Filter wavelength: Sample pressure: Enclosure: 210 to 1000 nano-meters Quartz window - 30 psig Sapphire - 40 psig Cell length: Flow rate:.01 to 40 inches (application dependent) 50 to 1500 cc/min (6000) General purpose - sheet steel (6020) Hazardous duty - condulet Light source: Tungsten lamp, mercury, deuterium arc (application dependent) Power rating: 115/230 VAC, 50/60Hz volts, approximately 200 watts Readout: 2-line alphanumeric vacuum fluorescent display (VFD) Sensitivity:.02 to 3 absorbance units TELEDYNE ANALYTICAL INSTRUMENTS A Teledyne Technologies Company Chestnut Street City of Industry, California 91748, USA Warranty Instrument is warranted for 1 year against defects in material or workmanship NOTE: Specifications and features will vary with application. The above are established and validated during design, but are not to be construed as test criteria for every product. All specifications and features are subject to change without notice. TEL: or FAX: ask_tai@teledyne.com Teledyne Analytical Instruments, A Teledyne Technologies Company. All rights reserved. Printed in the USA. 11/05LD