Extended Safety Data Sheet N-PENTANE T

Transcription

1 Page 1/ en Extended Safety Data Sheet T Last data update : Document type Safety data sheets Exposure Scenario Exposure Scenario Exposure Scenario Exposure Scenario Exposure Scenario Name Last data update Version Page T N-Pentane_Distribution of substance N-Pentane_Formulation and (re)packing of substances and mixtures N-Pentane_Blowing agent N-Pentane_Other uses by consumers N-Pentane_Use in Cleaning Agents - Consumer

2 Page 2/37 Page : 1 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : T Trade name : NOVEXPANS n-pentane T Common chemical name : Pentane CAS nr : EC Number : REACH registration numbe : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Aerosol jet / Blowing agent 1.3. Details of the supplier of the : safety data sheet 20 rue de Bourgogne BP SAINT-PRIEST Cedex France Tel : +33 (0) Fax : +33 (0) ContactFDS@inventec.dehon.com 1.4 Emergency telephone number : EMERGENCY TELEPHONE NUMBER (24h/24) : + 33 (0) Anti-poison Center : INRS/ORFILA (France) : +33 (0) Anti-poison Centre (Spain) : Anti-poison Centre (Belgium) : Anti-poison Centre (Netherlands) : Anti-poison Centre (United Kingdom) : Poisons Information Centre (Hungary) : SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 ( CLP) Physical hazards Health hazards : Flammable liquids - Category 1 (Flam. Liq. 1) - H224 : Aspiration hazard - Category 1 (Asp. Tox. 1) - H304 Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 (STOT SE 3) ; H336 Environmental hazards : Hazardous to the aquatic environment - Chronic hazard - Category 2 (Aquatic Chronic 2) - H Directive EEC/67/548 or 1999/45/ : F+; R12 CE Xn; R65 R66 R67 N; R Label elements Hazard pictograms M M MÄ MÅ Signal words : Danger Tel : +33 (0) Fax : +33 (0)

3 Page 3/37 Page : 2 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 2 Hazards identification (continued) Hazard statements Precautionary statements : Prevention Response Supplemental hazard information 2.3. Other hazards : H224: Extremely flammable liquid and vapour H304: May be fatal if swallowed and enters airways H336: May cause drowsiness or dizziness H411: Toxic to aquatic life with long lasting effects : P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P243: Take precautionary measures against static discharge P273: Avoid release to the environment : P301 + P331: IF SWALLOWED: Do not induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304 + P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing P311: Call a POISON CENTER or doctor/physician : EUH066: Repeated exposure may cause skin dryness or cracking SECTION 3 Composition/information on ingredients 3.1./3.2. Substance / Preparation : Substance. Components contributing to the hazard : Substance name Contents CAS No EC No Index No Ref REACH Classification n-pentane : >= 94 % F+; R12 Xn; R65 R66 R67 N; R Flam. Liq. 1;H224 Asp. Tox. 1;H304 STOT SE3; H336 EUH066 Aquatic Chronic 2;H411 SECTION 4 First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion Protection of first-aiders 4.2. Most important symptoms and effects, both acute and delayed : Move the affected person to the fresh air In the event of coughing and slight breathlessness: Call a doctor : Remove all contaminated clothing and footwear Wash immediately with plenty of soap and water If case of redness or irritation, call a doctor : Rinse immediately with plenty of water (for at least 15 minutes) If irritation persists, consult an eye specialist : Do NOT give the affected person anything to drink, even if he is fully conscious Never attempt to induce vomiting Transport to hospital immediately. : Do not enter without an appropriate protective equipment - self-contained breathing apparatus - protective clothing Tel : +33 (0) Fax : +33 (0)

4 Page 4/37 Page : 3 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 4 First aid measures (continued) Acute symptoms : Nausea Headaches Drowsiness Dizziness Central Nervous System depressant Anoxia (asphyxia). Loss of consciousness Possible effects following exposure: Drying up of the skin 4.3. Indication of any immediate : No information available medical attention and special treatment needed SECTION 5 Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam Powders Carbon dioxide (CO2) Water spray Unsuitable extinguishing media : None to our knowledge. If there is a fire close by, use suitable extinguishing agents 5.2. Special hazards arising from the : No information available substance or mixture 5.3. Advice for firefighters Specific fire fighting methods : Cool down the containers exposed to heat with a water spray Contain the extinguishing fluids by bunding (the product is hazardous for the environment) Protection of fire-fighters : Self-contained breathing apparatus Impermeable boots and protective equipment SECTION 6 Accidental release measures 6.1. Personal precautions, protective : Avoid contact with skin and eyes equipment and emergency procedures Do not attempt to take action without suitable protective equipment Do not breathe vapours Remove all sources of ignition In case of important spillage : Local evacuation is necessary (for people in close proximity to the spillage area) Only qualified personnel equipped with suitable protective equipment may intervene 6.2. Environmental precautions : Do not discharge into drains or rivers Contain the spilled material by bunding (product is hazardous for the environment) Clean up methods : 6.3. Methods and material for containment and cleaning up - Neutralization : Absorb spillage with: - inert absorbent material. - Cleaning/decontamination : Wash with a solution of % ethanol Then wash with water and detergent - Disposal : Dispose of contaminated material at an authorized site. 6.4 Reference to other sections : For further information refer to section 8 "Exposure controls/personal protection" Tel : +33 (0) Fax : +33 (0)

5 Page 5/37 Page : 4 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 6 Accidental release measures (continued) SECTION 7 Handling and storage 7.1. Precautions for safe handling Technical measures : Vapour extraction at source Use non-sparking tools Earth the equipment Precautions : Work in a well-ventilated area Avoid the build-up of electrostatic charge Industrial hygiene : Do not drink, eat or smoke in the workplace Always wash hands after handling the product Separate working clothes from town clothes 7.2. Conditions for safe storage, including any incompatibilities Storage conditions - Recommended : Store : - the container tightly closed - away from direct sunlight - in a cool, well-ventilated area - away from any source of ignition Incompatible products : Oxidizing materials Oxidizing materials Packaging materials - Recommended : Stainless steel Polyethylene Polypropylene Polyester Teflon - Not suitable : Rubbers SECTION 8 Exposure controls/personal protection 8.1. Control parameters Engineering measures : Extraction to remove vapours at their source. Ensure good ventilation of the work station Occupational Exposure Limits : n-pentane : USA (OSHA) : PEL - TWA (8h; mg/m³) : 2950 n-pentane : USA (OSHA) : PEL - TWA (8h; ppm) : 1000 n-pentane : USA (NIOSH) : REL - TWA (8h; mg/m³) : 350 n-pentane : USA (NIOSH) : REL - TWA (8h; ppm) : 120 n-pentane : United Kingdom : WEL - TWA (8h; mg/m³) : 1800 n-pentane : United Kingdom : WEL - TWA (8h; ppm) : 600 n-pentane : France : LEP - VME (8h; mg/m³) : 3000 n-pentane : France : LEP - VME (8h; ppm) : 1000 n-pentane : Germany : MAK - TWA (8h; mg/m³) : 3000 n-pentane : Germany : MAK - TWA (8h; ppm) : Exposure controls Personal protection : - Respiratory protection : In the event of insufficient ventilation: Filtering respiratory protective device with an AX gas canister Tel : +33 (0) Fax : +33 (0)

6 Page 6/37 Page : 5 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 8 Exposure controls/personal protection (continued) - Hand protection : Nitrile-rubber protective gloves - Eye protection : Safety spectacles with side shields - Skin protection : Handling product in large quantities: Protective non-flammable clothing SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties 9.1.a. Appearance Physical state : Liquid Colour : Colourless 9.1.b. Odour : weak hydrocarbons 9.1.c. Odour threshold : No data 9.1.d. ph : Not applicable 9.1.e. Melting point / Freezing point : -130 C 9.1.f. Initial boiling point - boiling : C range * 9.1.g. Flash point : -40 C 9.1.i. Flammability : Not applicable 9.1.j. Explosion limits (lower - upper) Explosion limits - lower : 1.4 % (volume) Explosion limits - upper : 7.8 % (volume) 9.1.k. Vapour pressure : 56.5 kpa at 20 C 9.1.l. Vapour density : m. Density : kg/dm³, at 20 C 0.59 kg/dm³, at 50 C 9.1.n. Solubility -in water : < 1 g/l Practically insoluble - in organic solvents : Miscible (in all proportions) with : - acetone - benzene. - ethanol - organic solvents 9.1.o. Partition coefficient : n-octanol / : No data water 9.1.p. Auto-ignition temperature : 260 C 9.1.q. Thermal decomposition : No information available 9.1.r. Viscosity : No data 9.1.s. Explosive Properties : Not explosive material according to EC criteria 9.1.t. Oxidising properties : Non oxidizing material according to EC criteria 9.2. Other information Critical temperature : : C Critical pressure : : 3370 KPa Tel : +33 (0) Fax : +33 (0)

7 Page 7/37 Page : 6 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 9 Physical and chemical properties (continued) SECTION 10 Stability and reactivity Reactivity : Chemical stability : Stable at ambient temperature and under normal conditions of use Possibility of hazardous : - reactions Conditions to avoid : Incompatible materials : - oxidizing materials. - strong oxidizing agents Hazardous decomposition : On combustion or on thermal decomposition (pyrolysis) releases : products : Carbon oxides (CO, CO2) SECTION 11 Toxicological information Information on toxicological effects Acute toxicity : May be fatal if swallowed and enters airways. On ingredients n-pentane : Rat inhalation LC50 [mg/l/4h] : > 5 : Rat oral LD50 [mg/kg] : > 2000 Skin corrosion/irritation : No information available Serious eye damage/irritation : No information available Respiratory or skin sensitization : No sensitizing effect is known Germ cell mutagenicity : No mutagenic effect Carcinogenicity : No carcinogenic effect Reproductive toxicity : No teratogenic effect STOT-single exposure : May cause drowsiness or dizziness. STOT-repeated exposure : No specific data Aspiration hazard : No specific data Other information : Repeated exposure may cause skin dryness or cracking SECTION 12 Ecological information Toxicity : Toxic to aquatic life with long lasting effects Persistence and degradability : No information available Bioaccumulative potential : No information available Mobility in soil Volatility : Extremely volatile Results of PBT and vpvb : No information available assessment Other adverse effects : - Tel : +33 (0) Fax : +33 (0)

8 Page 8/37 Page : 7 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 13 Disposal considerations Waste treatment methods WASTE FROM PRODUCT : Destruction/Disposal CONTAMINATED PACKAGING : Destruction/Disposal NOTE : Dispose of in accordance with relevant local regulations : Destroy at an authorised site : The user's attention is drawn to the possible existence of specific european, national or local regulations regarding disposal SECTION 14 Transport information UN number : UN UN proper shipping name : PENTANES Transport hazard class(es) : 3 Hazard Label(s) : 3 Ióp Packing group : Environmental hazards : Environmentally hazardous material :YES Marine pollutant : YES Special precautions for user Rail/road (RID/ADR) : Classification code : F1 Hazard identification number : 33 Tunnel restriction code : (D/E) Sea transport : EmS Nr : F-E, S-D Segregation group : - Air transport (OACI/IATA) : Cargo aircraft: Packing instruction: 303 Quantity: 30L Passenger aircraft: Packing instruction: 302 Quantity: 1L Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code NOTE : The above regulatory prescriptions are those valid on the date of publication of this sheet However, given the possible evolution of transport regulations for hazardous materials, in case the present sheet is dating back to more than 12 months ago, it would be advisable to check their validity with your commercial agency Tel : +33 (0) Fax : +33 (0)

9 Page 9/37 Page : 8 / 8 MATERIAL SAFETY DATA SHEET Version : 9 Date : 14 / 1 / 2015 Supersedes : 25 / 9 / 2014 T SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture France : Classified Installations : applicable Professional diseases(table(s) nr 84) : applicable Germany : : WGK (Water-endangermant class) : 2 US : NFPA Hazard Rating : - Reactivity : 0 - Flammability : 4 - Health : Chemical safety assessment SECTION 16 Other information Further information Text of R-Phrases in 3 : Product for industrial use only For more information regarding the use of this product, please refer to our technical information or contact the sales department in your region This safety data sheet has been written in conformity with the regulation (UE) 453/2010. : R12 : Extremely flammable. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 : Harmful : may cause lung damage if swallowed R66 : Repeated exposure may cause skin dryness or cracking R67 : Vapours may cause drowsiness and dizziness. Text of H-Phrases in 3 : EUH066 - Repeated exposure may cause skin dryness or cracking H224 - Extremely flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H336 - May cause drowsiness or dizziness H411 - Toxic to aquatic life with long lasting effects * Update : Modifications are indicated by an asterisk (*) This sheet complements the technical sheets but does not replace them. The information given is based on our knowledge of the product, at the time of publication. It is given in good faith. Besides, the attention of the user is drawn to the possible risks incurred by using the product for any other use than that for which it was intended. In no way does this exempt the user from knowing and applying all the regulations controlling his activity. He alone will take on the responsibility for taking the precautions involved by the use of the product. The aim of all the mandatory regulations mentionned is just to help the user to fulfil his obligations regarding the use of hazardous products. This information must not be considered exhaustive. It does not exempt the user from ensuring that other obligations than those mentioned could apply, related to the storage and use of the product, this being his sole responsibility. End of document Tel : +33 (0) Fax : +33 (0)

10 ANNEX Distribution of substance Page : 1/5 Date : 05/09/ ES1 1 Title : Distribution of substance List of all use descriptors related to the life cycle stage : Sector of use (SU): SU3 : Industrial uses: Uses of substances as such or in preparations at industrial sites SU8 : Manufacture of bulk, large scale chemicals (including petroleum products) SU9 : Manufacture of fine chemicals Process category (PROC): PROC1 : Use in closed process, no likelihood of exposure PROC2 : Use in closed, continuous process with occasional controlled exposure PROC3 : Use in closed batch process (synthesis or formulation) PROC4 : Use in batch and other process (synthesis) where opportunity for exposure arises PROC8a : Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC8b : Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9 : Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC15 : Use as laboratory reagent Environmental release category (ERC): ERC1 : Manufacture of substances ERC2 : Formulation of preparations ERC3 : Formulation in materials ERC4 : Industrial use of processing aids in processes and products, not becoming part of articles ERC5 : Industrial use resulting in inclusion into or onto a matrix ERC6a : Industrial use resulting in manufacture of another substance (use of intermediates) ERC6b : Industrial use of reactive processing aids ERC6c : Industrial use of monomers for manufacture of thermo-plastics ERC6d : Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers ERC7 : Industrial use of sub-stances in closed systems Specific Environmental Release Category (SPERC): ESVOC 1.1b.v1 : Manufacture of the substance and subsequent recycling/ recovery, including material transfers, storage, and maintenance Processes, tasks, activities covered : Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, distribution and associated laboratory activities.

11 ANNEX Distribution of substance Page : 2/5 Date : 05/09/ ES1 2 OPERATIONALCONDITIONS AND RISK MANAGEMENT MEASURES 2.1 Conditions affecting human health exposure Product characteristic: Liquid Vapour Pressure > 10 kpa at STP (Standard conditions for temperature and pressure) Frequency and duration of use/exposure: Covers daily exposures up to 8 hours (unless stated differently) Covers percentage substance in the product up to 100 % Other given operational conditions affecting workers exposure: Assumes a good basic standard of occupational hygiene is implemented Assumes use at not more than 20 C above ambient tem perature Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) PROC1 General exposures (closed systems) PROC2 PROC3 General exposures (open systems) Process sampling PROC4 PROC3 No other specific measures identified. Laboratory activities PROC15 Bulk transfers (closed systems) PROC8b Clear transfer lines prior to de-coupling. Bulk transfers (open systems) PROC8b No other specific measures identified. Drum and small package filling Equipment cleaning and maintenance Storage PROC9 PROC8a PROC1 PROC2 No other specific measures identified. Handle substance in an enclosed system.

12 ANNEX Distribution of substance Page : 3/5 Date : 05/09/ ES1 2.2 Conditions affecting environmental exposure Product characteristics : Predominantly hydrophobic. Substance is complex UVCB (substances of unknown or variable composition, complex reaction products or biological materials) Readily biodegradable Amounts used: Annual site tonnage (tonnes/year) : 2700 tons/day (see Msafe) Fraction of EU tonnage used in region : 0.1 Fraction of Regional tonnage used Locally : 1 Maximum daily site tonnage (kg/d) : 360 kg/day Regional use tonnage (tonnes/year) : 3600 tons/yr Frequency and Duration of use: Continuous release. Emission Days (days/year) : 20 days/yr Environment factors not influenced by risk management: Local freshwater dilution factor : 10 Local marine water dilution factor : 100 Other given operational conditions affecting environmental exposure: Release fraction to air from process (initial release prior to RMM) : 1e-04 Release fraction to soil from process (initial release prior to RMM) : 1e-005 Release fraction to wastewater from process (initial release prior to RMM) : 1e-005 Technical conditions and measures at process level (source) to prevent release: Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil: If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of : 0 % No secondary wastewater treatment required. Risk from environmental exposure is driven by freshwater. Treat air emissions to provide a typical removal (or abatement?) efficiency of : 90 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of : 0 %

13 ANNEX Distribution of substance Page : 4/5 Date : 05/09/ ES1 Organizational measures to prevent/limit release from site: Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant: Assumed domestic sewage treatment plant effluent flow is : 2000 m 3 /day Estimated substance removal from wastewater via domestic sewage treatment is : 96.9 % Not applicable as there is no release to wastewater. The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is : kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is : 96.9 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations 3 EXPOSURE ESTIMATION AND REFERENCE TO ITS SOURCE 3.1 Worker exposure Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. 3.2 Environmental exposure The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model.

14 ANNEX Distribution of substance Page : 5/5 Date : 05/09/ ES1 4 GUIDANCE TO DU TO EVALUATE WHETHER HE WORKS INSIDE THE BOUNDARIES SET BY THE ES 4.1 Worker exposure Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. 4.2 Environmental exposure Further details on scaling and control technologies are provided in factsheet Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Maximum Risk Characterisation Ratio for Air Emisions [RCRair] : 0 Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] : Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. This exposure scenario is made based on information provided by our suppliers, at the time of publication. The information and recommendations are offered for the user's consideration and examination. Appropriate warnings and safe-handling procedures should be provided to handlers and users End of document

15 ANNEX Formulation and (re)packing of substances and mixtures Page : 1/5 Date : 05/09/ ES2 1 Title : Formulation and (re)packing of substances and mixtures List of all use descriptors related to the life cycle stage : Sector of use (SU): SU3 : Industrial uses: Uses of substances as such or in preparations at industrial sites SU10 : Formulation [mixing] of preparations and/or re-packaging (excluding alloys) Process category (PROC): PROC1 : Use in closed process, no likelihood of exposure PROC2 : Use in closed, continuous process with occasional controlled exposure PROC3 : Use in closed batch process (synthesis or formulation) PROC4 : Use in batch and other process (synthesis) where opportunity for exposure arises PROC5 : Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC8a : Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC8b : Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9 : Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC14 : Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC15 : Use as laboratory reagent Environmental release category (ERC): ERC2 : Formulation of preparations Specific Environmental Release Category (SPERC): ESVOC 2.2.v1 : Formulation & packing of mixtures in batch or continuous operations, including storage, materials transfers, large and small scale packing, and maintenance Processes, tasks, activities covered : Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and small scale packing, sampling, maintenanance and associated laboratory activities.

16 ANNEX Formulation and (re)packing of substances and mixtures Page : 2/5 Date : 05/09/ ES2 2 OPERATIONALCONDITIONS AND RISK MANAGEMENT MEASURES 2.1 Conditions affecting human health exposure Product characteristic: Liquid Vapour Pressure > 10 kpa at STP (Standard conditions for temperature and pressure) Duration, frequency and amount : Covers daily exposures up to 8 hours (unless stated differently) Covers percentage substance in the product up to 100 % Other given operational conditions affecting workers exposure: Assumes a good basic standard of occupational hygiene is implemented Assumes use at not more than 20 C above ambient tem perature Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) PROC1 General exposures (closed systems) PROC2 PROC3 No other specific measures identified. General exposures (open systems) Batch processes at elevated temperatures. Operation is carried out at elevated temperature (> 20 C above ambient temperature). Process sampling PROC4 PROC3 PROC3 Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Formulate in enclosed or ventilated mixing vessels. Laboratory activities Bulk transfers Mixing operations (open systems) Manual Transfer from / pouring from containers Drum/batch transfers Production of preparations or articles by tabletting, compression, extrusion, pelettisation Drum and small package filling Equipment cleaning and maintenance Storage PROC15 PROC8b PROC5 PROC8a PROC8b PROC14 PROC9 PROC8a PROC1 PROC2 No other specific measures identified. Handle substance in an enclosed system.

17 ANNEX Formulation and (re)packing of substances and mixtures Page : 3/5 Date : 05/09/ ES2 2.2 Conditions affecting environmental exposure Product characteristics : Predominantly hydrophobic. Substance is complex UVCB (substances of unknown or variable composition, complex reaction products or biological materials) Readily biodegradable Amounts used: Annual site tonnage (tonnes/year): 65 tons/day (see Msafe) Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 1 Maximum daily site tonnage (kg/d): kg/day Regional use tonnage (tonnes/year): 3400 tons/yr Frequency and Duration of use: Continuous release. Emission Days (days/year): 300 days/yr Environment factors not influenced by risk management: Local freshwater dilution factor : 10 Local marine water dilution factor : 100 Other given operational conditions affecting environmental exposure: Release fraction to air from process process (after typical onsite RMMs consistent with EU Solvent Emissions Directive requirements) : Release fraction to soil from process (initial release prior to RMM): 1e-04 Release fraction to wastewater from process (initial release prior to RMM): 2e-04 Technical conditions and measures at process level (source) to prevent release: Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil: If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of : 0 % No secondary wastewater treatment required. Risk from environmental exposure is driven by freshwater sediment. Treat air emissions to provide a typical removal (or abatement?) efficiency of: 0 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of: 77.2 % Organizational measures to prevent/limit release from site: Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed.

18 ANNEX Formulation and (re)packing of substances and mixtures Page : 4/5 Date : 05/09/ ES2 Conditions and measures related to municipal sewage treatment plant: Assumed domestic sewage treatment plant effluent flow is : 2000 m 3 /day Estimated substance removal from wastewater via domestic sewage treatment is : 96.9 % Not applicable as there is no release to wastewater. The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is : kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is : 96.9 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations 3 EXPOSURE ESTIMATION AND REFERENCE TO ITS SOURCE 3.1 Worker exposure Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. 3.2 Environmental exposure The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.

19 ANNEX Formulation and (re)packing of substances and mixtures Page : 5/5 Date : 05/09/ ES2 4 GUIDANCE TO DU TO EVALUATE WHETHER HE WORKS INSIDE THE BOUNDARIES SET BY THE ES 4.1 Worker exposure Predicted exposures are not expected to exceed the DNEL/DMEL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. 4.2 Environmental exposure Further details on scaling and control technologies are provided in factsheet Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Maximum Risk Characterisation Ratio for Air Emisions [RCRair] : Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] : Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. This exposure scenario is made based on information provided by our suppliers, at the time of publication. The information and recommendations are offered for the user's consideration and examination. Appropriate warnings and safe-handling procedures should be provided to handlers and users End of document

20 ANNEX Blowing agent Page : 1/5 Date : 05/09/ ES3 1 Title: Blowing agent List of all use descriptors related to the life cycle stage: Sector of use (SU): SU3: Industrial uses: Uses of substances as such or in preparations at industrial sites Process category (PROC): PROC1: Use in closed process, no likelihood of exposure PROC3: Use in closed batch process (synthesis or formulation) PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC12: Use of blowing agents in manufacture of foam Environmental release category (ERC): ERC4: Industrial use of processing aids in processes and products, not becoming part of articles Specific Environmental Release Category (SPERC): ESVOC 4.9.v1: Use as a blowing agent, including material transfers, curing, storage and maintenance Processes, tasks, activities covered: Use as a blowing agent for rigid and flexible foams, including transfer of product, mixing and injection, curing, cutting, storage and packaging.

21 Page : 2/5 ANNEX Date : 05/09/ ES3 Blowing agent 2 OPERATIONALCONDITIONS AND RISK MANAGEMENT MEASURES 2.1 Conditions affecting human health exposure Product characteristic: Liquid Duration, frequency and amount: Covers daily exposures up to 8 hours (unless stated differently) Covers percentage substance in the product up to 100 % Other given operational conditions affecting workers exposure: Assumes a good basic standard of occupational hygiene is implemented Assumes use at not more than 20 C above ambient tem perature Contributing Scenarios / Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed): Bulk transfers PROC8b Mixing operations (closed systems) Extrusion and expansion of polymer Cutting and planing Collection and recycling of chips, chunks, etc.. Product packaging Storage PROC1 PROC12 No other specific measures identified. Mixing operations (closed systems) Intermediate storage of polymers Centrifugation including drain Treatment involving heating Manufacturing of article by molding Operation is carried out at elevated temperature (> 20 C above ambient temperature) PROC3 PROC12 Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Semi-bulk packaging PROC8b Drying and storage Cutting by heating wire - Manual PROC12 Mixing operations (closed systems) Drum and small package filling Filling and preparation of equipment from drums or containers Foaming Compression Cutting by heating wire PROC3 PROC9 PROC12 No other specific measures identified.

22 ANNEX Blowing agent Page : 3/5 Date : 05/09/ ES3 2.2 Conditions affecting environmental exposure Product characteristics: Predominantly hydrophobic. Substance is complex UVCB (substances of unknown or variable composition, complex reaction products or biological materials) Duration, frequency and amount: Annual site tonnage (tonnes/year): 430 tons/day (see Msafe) Continuous release. Emission Days (days/year): 100 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 1 Maximum daily site tonnage (kg/d): kg/day Regional use tonnage (tonnes/year): 1500 tons/yr Environment factors not influenced by risk management: Local freshwater dilution factor: 10 Local marine water dilution factor: 100 Other given operational conditions affecting environmental exposure: Release fraction to air from process (initial release prior to RMM): 1 Release fraction to soil from process (initial release prior to RMM): 0 Release fraction to wastewater from process (initial release prior to RMM): 3e-04 Technical conditions and measures at process level (source) to prevent release: Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil: If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of: 0 % No secondary wastewater treatment required. Risk from environmental exposure is driven by freshwater sediment. Treat air emissions to provide a typical removal (or abatement?) efficiency of: 0 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of: 0 % Organizational measures to prevent/limit release from site: Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed.

23 ANNEX Blowing agent Page : 4/5 Date : 05/09/ ES3 Conditions and measures related to municipal sewage treatment plant: Assumed domestic sewage treatment plant effluent flow is: 2000 m 3 /day Estimated substance removal from wastewater via domestic sewage treatment is: 96 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: kg/day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 96 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations 3 EXPOSURE ESTIMATION AND REFERENCE TO ITS SOURCE 3.1 Worker exposure Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. 3.2 Environmental exposure The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model.

24 ANNEX Blowing agent Page : 5/5 Date : 05/09/ ES3 4 GUIDANCE TO DU TO EVALUATE WHETHER HE WORKS INSIDE THE BOUNDARIES SET BY THE ES 4.1 Worker exposure Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. 4.2 Environmental exposure Further details on scaling and control technologies are provided in factsheet Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Maximum Risk Characterisation Ratio for Air Emisions [RCRair]: Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater]: Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. This exposure scenario is made based on information provided by our suppliers, at the time of publication. The information and recommendations are offered for the user's consideration and examination. Appropriate warnings and safe-handling procedures should be provided to handlers and users End of document

25 ANNEX Other uses by consumers Page : 1/3 Date : 05/09/ ES4 1 Title : Other uses by consumers List of all use descriptors related to the life cycle stage : Sector of use (SU): SU21: Consumer uses: Private households (= general public = consumers) Chemical Product Category (PC): PC28: Perfumes, fragrances PC39: Cosmetics, personal care products Environmental release category (ERC): ERC8a: Industrial use resulting in manufacture of another substance (use of intermediates) ERC8d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers Specific Environmental Release Category (SPERC): ESVOC 8.16.v1: Other Consumer Uses: Consumer (SU21) Processes, tasks, activities covered : Consumer uses such as carrier in cosmetics / personal care products, perfumes and perfumed products. Note: for cosmetics and personal care, only an assessment of environmental risks is required under REACH as human health is covered by other legislation. 2 OPERATIONALCONDITIONS AND RISK MANAGEMENT MEASURES 2.1 Conditions affecting human health exposure Product characteristic: Liquid Duration, frequency and amount : Not applicable Other given operational conditions affecting workers exposure: Not applicable

26 ANNEX Other uses by consumers Page : 2/3 Date : 05/09/ ES4 2.2 Conditions affecting environmental exposure Product characteristics : Predominantly hydrophobic. Substance is complex UVCB (substances of unknown or variable composition, complex reaction products or biological materials) Readily biodegradable Amounts used: Annual site tonnage (tonnes/year): tons/day (see Msafe) Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: Maximum daily site tonnage (kg/d): kg / day Regional use tonnage (tonnes/year): 72 tons/yr Frequency and Duration of use: Continuous release. Emission Days (days/year): 365 days/yr Environment factors not influenced by risk management: Local freshwater dilution factor : 10 Local marine water dilution factor : 100 Other given operational conditions affecting environmental exposure: Release fraction to air from process process (initial release prior to RMM): 0.95 Release fraction to soil from process (initial release prior to RMM): Release fraction to wastewater from process (initial release prior to RMM): Conditions and measures related to municipal sewage treatment plant: Assumed domestic sewage treatment plant effluent flow is : 2000 m 3 /day Estimated substance removal from wastewater via domestic sewage treatment is : 96 % Not applicable as there is no release to wastewater. The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is : 790 kg / day Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations

27 ANNEX Other uses by consumers Page : 3/3 Date : 05/09/ ES4 3 EXPOSURE ESTIMATION AND REFERENCE TO ITS SOURCE 3.1 Worker exposure Not applicable 3.2 Environmental exposure The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model. 4 GUIDANCE TO DU TO EVALUATE WHETHER HE WORKS INSIDE THE BOUNDARIES SET BY THE ES 4.1 Worker exposure Predicted exposures are not expected to exceed the DNEL when Operational Conditions outlined are implemented. Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. 4.2 Environmental exposure Further details on scaling and control technologies are provided in factsheet Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Maximum Risk Characterisation Ratio for Air Emisions [RCRair] : 5e-006 Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] : This exposure scenario is made based on information provided by our suppliers, at the time of publication. The information and recommendations are offered for the user's consideration and examination. Appropriate warnings and safe-handling procedures should be provided to handlers and users End of document

28 Page 28/37 ANNEX Page : 1/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer 1 Title : Use in Cleaning Agents - Consumer List of all use descriptors related to the life cycle stage : Sector of use (SU): SU21 : Consumer uses: Private households (= general public = consumers) Chemical Product Category (PC) : PC3 : Air care products PC4 : Anti-Freeze and de-icing products PC8 : Biocidal products (e.g. Disinfectants, pest control) PC9a : Coatings and paints, thinners, paint removers PC9b : Fillers, putties, plasters, modelling clay PC9c : Finger paints PC24 : Lubricants, greases, release products PC35 : Washing and cleaning products (including solvent based products) PC38 : Welding and soldering products (with flux coatings or flux cores.), flux products Environmental release category (ERC): ERC8a : Wide dispersive indoor use of processing aids in open systems ERC8d :Wide dispersive outdoor use of processing aids in open systems Specific Emission Release Category (SPERC) : ESVOC 8.4c.v1 : Use in Cleaning Agents - Consumer Processes, tasks, activities covered Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, de-icers, lubricants and air care products.

29 Page 29/37 ANNEX Page : 2/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer 2 OPERATIONALCONDITIONS AND RISK MANAGEMENT MEASURES 2.1 Conditions affecting human health exposure Product characteristic: Liquid Frequency and duration of use/exposure: Not applicable Other given operational conditions affecting consumer exposure : Not applicable Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (Aspiration Hazard) The H304 risk phrase (May be fatal if swallowed and enters airways) relates to potential for aspiration, a non-quantifiable hazard determined by physico-chemical properties (i.e. viscosity) that can occur during ingestion and also if it is vomited following ingestion. A DNEL cannot be derived. Risks from the physicochemical hazards of substances can be controlled by implementing risk management measures. For substances classified as H304, the following measures need to be implemented to control the aspiration hazard. Do not ingest. If swallowed then seek immediate medical attention. Do NOT induce vomiting. Just a sip of lamp oil - or even sucking the wick of lamps may lead to life threatening lung damage. Keep lamps filled with this liquid out of the reach of children. General measures (Flammable Liquid) Risks from the physicochemical hazards of substances can be controlled by implementing risk management measures. For flammable substances a selection of the following measures need to be implemented to control unintended ignition of flammable substances. These measures are expected to be suitable to prevent minor accidents which might occur during consumer use. Based on the implementation of a selection of handling and storage risk management measures for the identified uses, it is anticipated that there is no immediate concern as the risk should be controlled to an acceptable level. Use only with adequate ventilation. Avoid ignition sources No Smoking. Review SDS for additional advice. PC3 Air care products Air care, instant action (aerosol sprays) PC3 Air care products Air care, continuous action (solid and liquid) Covers concentrations up to 50 % Covers use up to 4 times per day Covers annual use up to 365 days/year For each use event, covers use amounts up to 0.1 grams Covers exposure up to 0.25 hour(s) Covers skin contact area up to cm 2 Covers concentrations up to 10 % Covers annual use up to 365 days/year Covers skin contact area up to 35.7 cubic cm For each use event, covers use amounts up to 0.48 grams Covers exposure up to 8 hour(s) Covers use at ambient temperatures

30 Page 30/37 ANNEX Page : 3/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer PC04 Anti-freeze and de-icing products Washing car window PC4 Anti-freeze and de-icing products Pouring into radiator PC4 Anti-freeze and de-icing products Lock de-icer PC8 Biocidal products (e.g. disinfectants, pest control) Laundry and dish washing products PC8 Biocidal products (e.g. disinfectants, pest control) Cleaners, liquids (all purpose cleaners, sanitary products, floor cleaners, glass cleaners, carpet cleaners, metal cleaners ) Covers concentrations up to 1 % Covers annual use up to 365 days/year For each use event, covers use amounts up to 0.5 grams Covers use in a one car garage (34 m 3 ) under typical ventilation. Covers use in room size of 34 m³ Covers exposure up to 0.02 hour(s) Liquid, vapour pressure > 10 kpa at STP cm 2 Covers concentrations up to 10 % Covers annual use up to 365 days/year Covers skin contact area up to 428 cm 2 For each use event, covers use amounts up to 2000 grams Covers use in a one car garage (34 m3) under typical ventilation. Covers use in room size of 34 m³ Covers exposure up to 0.17 hour(s) Covers concentrations up to 50 % Covers annual use up to 365 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 4 grams Covers use in a one car garage (34 m3) under typical ventilation. Covers use in room size of 34 m³ Covers exposure up to 0.25 hour(s) Covers concentrations up to 5 % Covers annual use up to 365 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 15 grams Covers exposure up to 0.5 hour(s) Covers concentrations up to 5 % Covers annual use up to 128 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 27 grams Covers exposure up to 0.33 hour(s)

31 Page 31/37 ANNEX Page : 4/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer PC8 Biocidal products (e.g. disinfectants, pest control) Cleaners, trigger sprays (all purpose cleaners, sanitary products, glass cleaners) PC9A Coatings and paints, thinners, paint removers Waterborne latex wall paint PC9A Coatings and paints, thinners, paint removers Solvent rich, high solid, water borne paint PC9A Coatings and paints, thinners, paint removers Aerosol spray can PC9A Coatings and paints, thinners, paint removers Removers (paint-, glue-, wall paper-, sealantremover) Covers concentrations up to 15 % Covers annual use up to 128 days/year Covers skin contact area up to 428 cm 2 For each use event, covers use amounts up to 35 grams Covers exposure up to 0.17 hour(s) Covers concentrations up to 1.5 % Covers annual use up to 4 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 2760 grams Covers exposure up to 2.2 hour(s) Covers concentrations up to 27.5 % Covers annual use up to 6 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 744 grams Covers exposure up to 2.2 hour(s) Covers concentrations up to 50 % Covers annual use up to 2 days/year For each use event, covers use amounts up to 215 grams Covers use in a one car garage (34 m3) under typical ventilation. Covers use in room size of 34 m³ Covers exposure up to 0.33 hour(s) Covers skin contact area up to cm 2 Covers concentrations up to 50 % Covers annual use up to 3 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 491 grams Covers exposure up to 2 hour(s)

32 Page 32/37 ANNEX Page : 5/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer PC9B Fillers, putties, plasters, modelling clay fillers and Putty PC9B Fillers, putties, plasters, modelling clay Plasters and floor equalizers PC9B Fillers, putties, plasters, modelling clay Modelling clay PC09C Finger paints PC24 Lubricants, Greases and Release products Liquids Covers concentrations up to 2 % Covers annual use up to 12 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 85 grams Covers exposure up to 4 hour(s) Covers concentrations up to 2 % Covers annual use up to 12 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to grams Covers exposure up to 2 hour(s) Covers concentrations up to 1 % Covers annual use up to 365 days/year Covers skin contact area up to cm 2 For each use event, assumes swallowed amount of 1 grams For each use event, covers use amounts up to grams Covers exposure up to 8 hour(s) Covers concentrations up to 50 % Covers annual use up to 365 days/year Covers skin contact area up to cm 2 For each use event, assumes swallowed amount of 1.35 grams For each use event, covers use amounts up to grams Covers exposure up to 8 hour(s) Covers concentrations up to 100 % Covers use up to 1 times per day Covers annual use up to 4 days/year Covers skin contact area up to 468 cm 2 For each use event, covers use amounts up to 2200 grams Covers use in a one car garage (34 m3) under typical ventilation. Covers use in room size of 34 m³ Covers exposure up to 0.17 hour(s)

33 Page 33/37 ANNEX Page : 6/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer PC24 Lubricants, Greases and Release products Pastes PC24 Lubricants, Greases and Release products Sprays PC35 Washing and cleaning products (including solvent based products) Laundry and dish washing products PC35 Washing and cleaning products (including solvent based products) Cleaners, liquids (all purpose cleaners, sanitary products, floor cleaners, glass cleaners, carpet cleaners, metal cleaners ) PC35 Washing and cleaning products (including solvent based products) Cleaners, trigger sprays (all purpose cleaners, sanitary products, glass cleaners) Covers concentrations up to 20 % Covers annual use up to 10 days/year Covers skin contact area up to 468 cm 2 For each use event, covers use amounts up to 34 grams Covers exposure up to 4 hour(s) Covers concentrations up to 50 % Covers annual use up to 6 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 73 grams Covers exposure up to 0.17 hour(s) Covers concentrations up to 5 % Covers annual use up to 365 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 15 grams Covers exposure up to 0.5 hour(s) Covers concentrations up to 5 % Covers annual use up to 128 days/year Covers skin contact area up to cm 2 For each use event, covers use amounts up to 27 grams Covers exposure up to 0.33 hour(s) Covers concentrations up to 15 % Covers annual use up to 128 days/year Covers skin contact area up to 428 cm 2 For each use event, covers use amounts up to 35 grams Covers exposure up to 0.17 hour(s)

34 Page 34/37 ANNEX Page : 7/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer Welding and soldering products (with flux coatings or flux cores), flux products PC38 Air care products Air care, instant action (aerosol sprays) PC03 Air care products Air care, continuous action (solid and liquid) PC03 Covers concentrations up to 20 % Covers annual use up to 365 days/year For each use event, covers use amounts up to 12 grams Covers exposure up to 1 hour(s) Covers skin contact area up to cm 2 Covers concentrations up to 50 % Covers use up to 4 times per day Covers annual use up to 365 days/year For each use event, covers use amounts up to 0.5 grams Covers exposure up to 0.25 hour(s) Liquid, vapour pressure > 10 kpa at STP. Covers skin contact area up to cm 2 Covers concentrations up to 50 % Covers annual use up to 365 days/year Covers skin contact area up to 35.7 cm 2 For each use event, covers use amounts up to 0.48 grams Covers exposure up to 8 hour(s) Liquid, vapour pressure > 10 kpa at STP.

35 Page 35/37 ANNEX Page : 8/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer 2.2 Conditions affecting environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage: tons/year Continuous release. Emission Days: 365 days/year Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: Maximum daily site tonnage: kg / day Regional use tonnage: 42 tons/year Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process (initial release prior to RMM): 0.95 Release fraction to soil from process (initial release prior to RMM): Release fraction to wastewater from process (initial release prior to RMM): Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is: 2000 m 3 /day Estimated substance removal from wastewater via domestic sewage treatment is: 96 % Not applicable as there is no release to wastewater. The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 480 kg / day Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations

36 Page 36/37 ANNEX Page : 9/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer 3 EXPOSURE ESTIMATION AND REFERENCE TO ITS SOURCE 3.1 Worker exposure Not applicable 3.2 Environmental exposure The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[ee2] 4 GUIDANCE TO DU TO EVALUATE WHETHER HE WORKS INSIDE THE BOUNDARIES SET BY THE ES 4.1 Worker exposure Estimated consumer exposures are not expected to exceed DNELs when the identified operating conditions are adopted. [ConsG1] Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[g23] 4.2 Environmental exposure Further details on scaling and control technologies are provided in factsheet Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Maximum Risk Characterisation Ratio for Air Emissions [RCRair] 3e-006 Maximum Risk Characterisation Ratio for Wastewater Emissions [RCRwater] This exposure scenario is made based on information provided by our suppliers, at the time of publication. The information and recommendations are offered for the user's consideration and examination. Appropriate warnings and safe-handling procedures should be provided to handlers and users End of document

37 Page 37/37 ANNEX Page : 10/10 Date : 08/04/ ES5 Use in Cleaning Agents - Consumer