: GLASS CLEANER CONCENTRATE

Transcription

1 Date of issue: 02/23/2011 Revision date: 06/10/2014 Supersedes: 12/21/2012 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : GLASS CLEANER CONCENTRATE : GC 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Sky Blue Industries, Inc. 760 W. Exchange Road Ogden, UT USA T (801) Custom Formulation for: UHaul International (Phoenix, AZ) 1.4. Emergency telephone number : Glass and Hard Surface Cleaner Concentrate Emergency number : Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye Irrit. 2A H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) Prevention Response GHS07 : Warning : Causes serious eye irritation : Wash hands and exposed skin thoroughly after handling. Wear eye protection, protective clothing, protective gloves. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 06/13/2014 EN (English) Page 1

2 3.2. Mixture Name Product identifier % GHS-US classification 2-butoxyethanol (CAS No) Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Tetrasodium ethylenediaminetetraactetate (CAS No) Acute Tox. 4 (Inhalation:dust,mist), H332 Eye Dam. 1, H318 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. Keep upwind. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Avoid release to the environment. See Section 12 for additional Ecological information Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 06/13/2014 EN (English) 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Wash hands and exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Keep only in the original container in a cool, well ventilated place away from: Direct sunlight, Heat sources. Keep container closed when not in use. : Strong acids. Strong bases. Strong oxidizing agents. : Sources of ignition. Direct sunlight. USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm USA ACGIH Remark (ACGIH) Eye & URT irr 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, dark blue liquid Colour : Dark blue Odour : Detergent Odour threshold ph : ph solution : 5 % Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1.01 Density : 8.40 lbs/gal Solubility : Soluble in water Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic 06/13/2014 EN (English) 3/7

4 Explosive properties Oxidising properties Explosive limits 9.2. VOC content : 6.2 % (0.58% after recommended dilution) SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. Strong oxidizing agents Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat 530 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 1746 mg/kg bodyweight; Rat; Experimental value) > 2000 mg/kg bodyweight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LD50 dermal rabbit 435 mg/kg bodyweight (Rabbit; Experimental value; OECD 402: Acute Dermal Toxicity; 435 mg/kg bodyweight; Rabbit; Weight of evidence; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (vapours) ATE US (dust,mist) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE US (vapours) ATE US (dust,mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 2.17 mg/l/4h (Rat; Experimental value; 2.35 mg/l/4h; Rat; Experimental value) ,Rat; Weight of evidence 530 mg/kg bodyweight 435 mg/kg bodyweight 2.17 mg/l/4h 2.17 mg/l/4h > 2000 mg/kg (Rat) > 5000 mg/kg 4.14 mg/l/4h Dust 4.14 mg/l/4h 4.14 mg/l/4h ph: : Causes serious eye irritation. ph: Specific target organ toxicity (repeated exposure) Aspiration hazard 06/13/2014 EN (English) 4/7

5 Potential Adverse human health effects and symptoms Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : Causes serious eye irritation. SECTION 12: Ecological information Toxicity LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 ErC50 (algae) TLM fish 1 TLM other aquatic organisms 1 Threshold limit algae 1 Threshold limit algae ppm (96 h; Cyprinodon variegatus; Nominal concentration) 1700 mg/l (48 h; Daphnia sp.; Nominal concentration) 1341 ppm (96 h; Lepomis macrochirus) 1720 mg/l (24 h; Daphnia magna) 911 mg/l (72 Hr.) ,96 h; Pisces ,96 h 900 mg/l (168 h; Scenedesmus quadricauda) 35 mg/l (192 h; Microcystis aeruginosa) LC50 fishes 1 EC50 Daphnia mg/l (96 h; Lepomis macrochirus; Soft water) 625 mg/l (24 h; Daphnia magna) LC50 fish mg/l (96 h; Lepomis macrochirus; ph > 7) Threshold limit algae 1 > 100 mg/l (72 h; Scenedesmus subspicatus; Growth) Persistence and degradability GLASS CLEANER CONCENTRATE Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Not established. Readily biodegradable in water. Biodegradable in the soil. Photodegradation in the air g O₂ /g substance 2.20 g O₂ /g substance g O₂ /g substance 0.31 % ThOD Persistence and degradability Not readily biodegradable in water. Biochemical oxygen demand (BOD) < g O₂ /g substance Chemical oxygen demand (COD) g O₂ /g substance Bioaccumulative potential GLASS CLEANER CONCENTRATE Bioaccumulative potential Not established. Log Pow 0.81 (Experimental value; BASF test; 25 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Log Pow -2.6 Bioaccumulative potential Bioaccumulation: not applicable Mobility in soil Surface tension Other adverse effects Effect on ozone layer Effect on the global warming N/m (25 C) : : No known ecological damage caused by this product. : Avoid release to the environment. 06/13/2014 EN (English) 5/7

6 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. SARA Section 311/312 Hazard Classes Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard SARA Section Emission Reporting 100 % SARA Section 311/312 Hazard Classes Immediate (acute) health hazard International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations California This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive toxicity Formaldehyde ( ) Carcinogens List Developmental Toxicity Reproductive Toxicity - Female Reproductive Toxicity - Male No significance risk level (NSRL) Yes 06/13/2014 EN (English) 6/7

7 Isopropyl alcohol ( ) Sodium hydroxide ( ) U.S. - Massachusetts - Right To Know List Caprolactam ( ) Formaldehyde ( ) U.S. - Massachusetts - Right To Know List Ammonia ( ) U.S. - Massachusetts - Right To Know List Hydrogen peroxide ( ) SECTION 16: Indication of changes : HCS 2012 Compliance Update. Revision date : 06/10/2014 : None. Full text of H-phrases: see section 16: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category Acute Tox. 4 (Oral) Acute toxicity (oral), Category Eye Dam. 1 Serious eye damage/eye irritation, Category Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Flam. Liq. 4 Flammable liquids, Category Skin Irrit. 2 Skin corrosion/irritation, Category H227 Combustible liquid H302 Harmful if swallowed H311 Toxic in contact with skin H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H320 Causes eye irritation H332 Harmful if inhaled SDS US (GHS HazCom 2012) - Custom The information provided on this document is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 06/13/2014 EN (English) 7/7