Test Report No CH02 Date: June 30, 2017 Page 1 of 9

Transcription

1 Test Report No CH02 Date: June 30, 2017 Page 1 of 9 Samtech Inc. 520 Park East Blvd. New Albany, IN United States The following sample(s) was/were submitted and identified by/on behalf of the client as: Polyimide Film Model/Part #: Kapton Color: Dark Amber Sample Received Date: 6/23/2017 Testing Period: 6/23/2017-6/30/2017 Test Requested : Please refer to the test results. Test Method & Results : Please refer to next page(s). Result Summary : Test Requested 1. RoHS Directive 2011/65/EU Annex II [amended by Directive (EU) 015/863] 2. Halogen content (Cl, Br, F, I) of the submitted sample(s) with reference to BS EN 14582: European Regulation (EC) No. 1907/2006 (REACH) Annex XVII and its amendments Phthalates content (Formerly Directive 2005/84/EC) Comment PASS See test results PASS Signed for and on behalf of SGS North America, Inc. Prepared By: Manoj Aluri Sr. Laboratory Supervisor, Chemistry Laboratory Evan Mishner Report Writer, Chemistry Laboratory

2 Test Report No CH02 Date: June 30, 2017 Page 2 of 9 1. RoHS Directive 2011/65/EU Annex II [amended by Directive (EU) 2015/863] Test Item(s): Unit Test Method Results MDL Limit 1 Cadmium(Cd) mg/kg With reference to IEC ND Lead (Pb) mg/kg 5:2013 (Determination of Cd and Pb by ND ICP-OES and /or ICP-MS) Mercury (Hg) mg/kg With reference to IEC :2013 (Determination of Hg by ICP- ND OES and/ or ICP-MS) Hexavalent Chromium (CrVI) mg/kg With reference to IEC 62321:2008 (Determination of CrVI by UV- ND* VIS) Sum of PBBs mg/kg ND Monobromobiphenyl mg/kg ND 5 - Dibromobiphenyl mg/kg ND 5 - Tribromobiphenyl mg/kg ND 5 - Tetrabromobiphenyl mg/kg ND 5 - Hexabromobiphenyl mg/kg ND 5 - Pentabromobiphenyl mg/kg ND 5 - Heptabromobiphenyl mg/kg ND 5 - Octabromobiphenyl mg/kg ND 5 - Nonabromobiphenyl mg/kg With reference to IEC ND 5 - Decabromobiphenyl mg/kg 6:2015 ND 5 - Sum of PBDEs mg/kg (Determination of PBB and ND Monobromodiphenyl ether mg/kg PBDE by GC-MS) ND 5 - Dibromodiphenyl ether mg/kg ND 5 - Tribromodiphenyl ether mg/kg ND 5 - Tetrabromodiphenyl ether mg/kg ND 5 - Pentabromodiphenyl ether mg/kg ND 5 - Hexabromodiphenyl ether mg/kg ND 5 - Heptabromodiphenyl ether mg/kg ND 5 - Octabromodiphenyl ether mg/kg ND 5 - Nonabromodiphenyl ether mg/kg ND 5 - Decabromodiphenyl ether mg/kg ND 5 - Bis (2-ethylhexyl) phthalate mg/kg ND (DEHP) IEC :2017 Butyl benzyl phthalate (BBP) mg/kg (Determination of DEHP, BBP, ND Dibutyl phthalate (DBP) mg/kg DBP and DIBP by GC-MS) ND Diisobutyl phthalate (DIBP) mg/kg ND Conclusion / / PASS / /

3 Test Report No CH02 Date: June 30, 2017 Page 3 of 9 Sample Description: 1. Polyimide Film Dark Amber Style# Kapton Note: (a) mg/kg = ppm;0.1wt% = 1000ppm (b) ND= not detected (c) MDL = Method Detection Limit (d) - = not regulated (e) * = Total Chromium analysis by ICP-MS and/or ICP-OES was not detected in submitted sample. Therefore, Hexavalent Chromium determination using UV-Visible Spectroscopy was not performed ,25

4 Test Report No CH02 Date: June 30, 2017 Page 4 of 9 2. Halogen content (Cl, Br, F, I) of the submitted sample(s) with reference to BS EN 14582:2016 With reference to BS EN 14582:2016 Characterization of waste Halogen and sulfur content Oxygen Combustion in closed systems and determination methods. Analysis was performed by Ion Chromatography. Test Items Halogen Chlorine (Cl) CAS # Halogen Bromine (Br) CAS # Halogen Fluorine (F) CAS # Halogen Iodine (I) CAS # Unit Method Detection Limit mg/kg mg/kg mg/kg 50 ND mg/kg 50 ND 1 Sample Description: 1. Polyimide Film Dark Amber Style# Kapton Note: 1. mg/kg = ppm 2. ND = Not Detected, reported when the reading is less than the detection limit value.

5 Test Report No CH02 Date: June 30, 2017 Page 5 of 9 3 European Regulation (EC) No. 1907/2006 (REACH) Annex XVII and its amendments Phthalates content (Formerly Directive 2005/84/EC) Method : With reference to IEC :2017(Determination of DEHP, BBP, DBP and DIBP by GC-MS). Test Item Result (%) Detection Permissible 1 Limit (%) Limit (%) Dibutyl Phthalate (DBP) ND Benzylbutyl Phthalate (BBP) ND Bis-(2-ethylhexyl) Phthalate (DEHP) ND DBP + BBP + DEHP < Diisononyl Phthalate (DINP) ND Di-n-octyl Phthalate (DNOP) ND Diisodecyl Phthalate (DIDP) ND DINP + DNOP + DIDP < Comment PASS Sample Description : 1. Polyimide Film Dark Amber Style# Kapton Note : 1. % = percentage by weight 2. ND = Not Detected 3. < = less than

6 Test Report No CH02 Date: June 30, 2017 Page 6 of 9 Flowchart for ROHS Testing: Cutting / Preparation Pb, Cd, Hg, Cr Acid Digestion with appropriate acid Weigh Sample Alkaline Extraction Cr 6+ (See note 3) PBBs, PBDEs Solvent Extraction Solution Filtration Residue a. Dry Ashing b. Dissolution by HNO 3/HCl Filtration, ph, Clean-up Add reagent for color development UV-VIS Concentrate / Dilute extracted solution Clean-up with florisil column Solution ICP-MS/ICP-OES GC-MS Note : 1. For Cr(VI), spot test is adopted for metal sample. 2. The Cd, Pb, Hg contents test on polymeric samples were dissolved totally by preconditioning method according to above flow chart. 3. Cr 6+ is performed only when total Cr is detected

7 Test Report No CH02 Date: June 30, 2017 Page 7 of 9 Halogen Testing Flow Chart Sample cutting / preparation Sample measurement Combustion in Oxygen Bomb Dissolved in absorption Filtration Analyzed by Ion Chromatography Data Analysis

8 Test Report No CH02 Date: June 30, 2017 Page 8 of 9 Flowchart for Phthalates Cutting/ Preparation Weighing Solvent Extraction Concentrate / Dilute extracted solution Filtration GC-MS

9 Test Report No CH02 Date: June 30, 2017 Page 9 of 9 Sample Photo: SGS authenticates the photo on the original report only *** End of Report ***