MATERIAL SAFETY DATA SHEET 1.0 CHEMICAL PRODUCT AND COMPANY INFORMATION 2.0 HAZARDS IDENTIFICATION
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1 1.0 CHEMICAL PRODUCT AND COMPANY INFORMATION PRODUCT NAME: EM-825B OTHER/GENERIC NAMES: Glass Fabric-Reinforced, Epoxy Prepreg or bond sheet PRODUCT USE: Military: Type GFN; NEMA: FR-4 MANUFACTURER/SUPPLIER: ELITE MATERIAL CO., LTD Emergency Phone : 18 TA-Tung First Rd., EMC TAIWAN PLANT Kuan-Yin Industrial District Tel : Tao-Yuan Hsien, Taiwan ROC Fax : HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: A nonflammable, sheet material. Dust, when machined or punched may cause skin or eye irritation. Fumes, if decomposed may irritate eyes, nose, and throat. POTENTIAL HEALTH EFFECTS: EYE: Dust from milling operations may cause irritation or injury due to mechanical action. SKIN: Powder from milling operations may cause skin irritation. INGESTION: Not considered a normal route of entry INHALATION: Fibrous glass dust may be released from the fiber-glass cloth substrate when machined. ACGIH TLV is 10 mg/m3 TWA for particles <5 microns in diameter. DELAYED EFFECTS: IARC has categorized continuous filament FIBROUS GLASS (the type of fibrous glass used in textile applications such as manufacturing glass fabric for prepregging and laminate manufacture) as not classifiable with respect to human carcinogenicity (Group 3). This classification was based on the fact that the evidence from human, as well as animal, studies evaluated by IARC was insufficient to classify continuous filament fibrous glass. Fiber glass wool (primarily used for insulation in a variety of applications) was classified as a possible human carcinogen by IARC (Group 2B). This classification was primarily based on studies in which experimental animals were exposed to wool glass fibers through non-natural routes, such as injection or implantation. Ingredients on one of the OSHA Carcinogen Lists: Ingredient Name None INGREDIENT NAME Continuous Filament Fiber Glass Epoxy Resin (including inorganic filler) NTP Status IARC Status OSHA List 3.0 COMPOSITION/INFORMATION ON INGREDIENTS CAS # WEIGHT % ( ) Trace impurities and additional material names not listed above may also appear in the Regulatory Information section (#15) towards the end of the MSDS. These materials may be listed for local "Right to Know" compliance and for other reasons. Current Issue Date: 2013/05/14 Page: 1 of 5
2 4.0 FIRST AID MEASURES EYES: For dust generated during milling operations, remove contact lenses at once. Immediately flush eyes with copious amounts of water or normal saline for at least 15 minutes. If irritation persists, seek medical attention. SKIN: Wash or shower with soap and cold water to prevent fiberglass dust from entering skin pores. INGESTION: If large amounts are ingested, consult physician INHALATION: If overcome by dust, smoke, gases or fumes, remove to fresh air. If not breathing, give mouth to mouth resuscitation. Call physician. ADVICE TO PHYSICIAN: Treat symptomatically. Decomposition gases, smoke, and fumes caused by exposure of the material to high heat may include hydrogen bromide, hydrogen cyanide, carbon monoxide and aromatic hydrocarbons. Signs and symptoms of pulmonary edema may be caused by hydrogen bromide inhalation. Respiratory support may be necessary. 5.0 FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: FLASH POINT: FLASH POINT METHOD: AUTOIGNITION TEMPERATURE: 400C (752F), estimated. UPPER FLAMMABLE LIMIT: LOWER FLAMMABLE LIMIT: FLAME PROPAGATION RATE: UL-94V-0 OSHA FLAMMABILITY CLASS: EXTINGUISHING MEDIA: Water, CO2, and Dry Chemical UNUSUAL FIRE AND EXPLOSION HAZARDS: May give off toxic hydrogen bromide gas when thermally decomposed. Other hazardous gases may be hydrogen cyanide, cyanogen bromide, carbon monoxide, and carbon dioxide. SPECIAL FIRE FIGHTING PRECAUTIONS/INSTRUCTIONS: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. 6.0 ACCIDENTAL RELEASE MEASURES IN CASE OF SPILL OR OTHER RELEASE: (Wear Personal Protective Equipment as recommended) Material is considered an article. Spill or release to the environment is highly unlikely. Spills and releases may have to be reported to Federal and/or local authorities. 7.0 HANDLING AND STORAGE HANDLING: The primary exposure route is inhalation of dust when the material is machined or from fumes, smoke, vapors and gases when heated. Current Issue Date: 2013/05/14 Page: 2 of 5
3 STORAGE: Store in a dry place away from moisture, excessive heat and sources of ignition. ENGINEERING CONTROLS: A continuous supply of fresh air to the milling operations workplace together with removal of process dust through exhaust systems is recommended. Processing dust may be a fire hazard; remove periodically from exhaust hoods, duct work and other surfaces using appropriate personal protection. PERSONAL PROTECTION: SKIN PROTECTION: Gloves and coveralls should be worn when prolonged or repeated contact occurs. Clothing should be either discarded or cleaned after use. Do not wear dust contaminated clothing home. EYE PROTECTION: Use appropriate eye protection (safety glasses) when machining material. Goggles are recommended when high levels of dust are present, such as during equipment cleaning operations, changing dust collector filters, or floor sweeping operations. RESPIRATORY PROTECTION: Atmospheric levels of fibrous glass, copper, and other dusts should ADDITIONAL RECOMMENDATIONS: EXPOSURE GUIDELINES: Ingredient Name Fiber Glass Dust APPEARANCE: MOLECULAR WEIGHT: CHEMICAL FORMULA: PHYSICAL STATE: ODOR : FLASH POINT: BOILING POINT: MELTING POINT: Not Applicable. EVAPORATION RATE: VAPOR DENSITY (AIR=1): be maintained below recommended exposure guidelines through the use of appropriate ventilation systems and dust reduction methods. When dust levels cannot be reduced below exposure levels or for special operations where high levels may be present, the use of a NIOSH approved dust respirator is required. Amber, gold or yellow sheets Solid. None under normal conditions. When heated to decomposition temperatures, the acrid odor of hydrogen bromide is distinctly present. SPECIFIC GRAVITY (WATER=1): 1.75 ± 0.25 WATER SOLUBILITY: % VOLATILE: ph: 8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION CAS. NO. ( ) ACGIH TLV OSHA PEL 10 mg/m3 9.0 PHYSICAL AND CHEMICAL PROPERTIES Insoluble. PARTITION COEFFICIENT(N-OCTANOL/WATER,LOG KOW): Other Limit Current Issue Date: 2013/05/14 Page: 3 of 5
4 10.0 STABILITY AND REACTIVITY STABILITY: INCOMPATIBILITIES: REACTIVITY: Stable under recommended conditions of storage. Not determined. Not reactive under recommended conditions of handling, storage and processing. HAZARDOUS POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION: CO, CO2 HBr, Oxides of nitrogen, HCN, Br2CO 11.0 TOXICOLOGICAL INFORMATION IMMEDIATE (ACUTE) EFFECTS: Dust may cause eye, skin and respiratory irritation DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS: IARC has categorized continuous filament FIBROUS GLASS (the type of fibrous glass used in textile applications such as manufacturing glass fabric for prepregging and laminate manufacture) as not classifiable with respect to human carcinogenicity (Group 3). This classification was based on the fact that the evidence from human, as well as animal, studies evaluated by IARC was insufficient to classify continuous filament fibrous glass. Fiber glass wool (primarily used for insulation in a variety of applications) was classified as a possible human carcinogen by IARC (Group 2B). This classification was primarily based on studies in which experimental animals were exposed to wool glass fibers through non-natural routes, such as injection or implantation. OTHER DATA: The thermal degradation products, such as hydrogen bromide, will cause both acute and chronic effects. Not Biodegradable 12.0 ECOLOGICAL INFORMATION 13.0 DISPOSAL INFORMATION RCRA HAZARDOUS WASTE: Product is not a RCRA Hazardous Waste. WASTE DISPOSAL: Disposal must be made in accordance with all applicable Local, State, and Federal regulations. Copper should be recycled. While the material as shipped is not classified as a RCRA waste, use or alteration of the product such as fabricating into a printed circuit board with other materials such as lead solder may change the RCRA classification of the mixture and require alternative disposal procedures TRANSPORTATION INFORMATION DOT HAZARD CLASS: Not Regulated. PROPER SHIPPING NAME:Not Regulated. IDENTIFICATION NUMBERNot Listed REGULATORY INFORMATION TSCA INVENTORY STATUSThe resin system components used to make this (article)material are on the OTHER TSCA ISSUES: TSCA inventory list. The material ( article) itself is not required to be on the list. SARA TITLE III/CERCLA REPORTABLE QUANTITIES(RQs) AND THRESHOLD PLANNING Current Issue Date: 2013/05/14 Page: 4 of 5
5 QUANTITIES(TPQs): EMC INGREDIENT N,N-dimethylformamide SECTION 311 HAZARD CLASS: SARA 313 TOXIC CHEMICALS: INGREDIENT N,N-dimethylformamide STATE RIGHT TO KNOW: SARA/CERCLA RQ(lbs./kg) ADDITIONAL REGULATORY INFORMATION: TPQ(lbs./kg) 100 CAS NO. 1968/12/2 COMMENTS SARA EHS Trace amounts of N,N-dimethylformamide may be present in the material as a result of the manufacturing process. If present, the level is typically less than 0.1% w/w The brominated epoxy resins use to produce this material do not contain nor degrade to form polybrominated biphenyls(pbb), polybrominated biphenylene oxides(pbbo), or polybrominated biphenylene ethers(pbbe). The fire retardancy is obtained from polymeric resins based on the monomer Tetrabromobisphenol A. WHMIS CLASSIFICATION (CANADANot a controlled substance FOREIGN INVENTORY STATUS: 16.0 OTHER INFORMATION The method of manufacture of this article does insure that the proprietary ingredient is an integral part of the polymeric resin and is not present in its free state except in trace amounts. Elite Material Co., Ltd. believes the information and recommendations presented in this Material Safety Data Sheet are accurate as of the date of the document. Elite Material Co., Ltd. makes no representation or warranty as to the completeness or accuracy of the information. This information is supplied with the condition that persons receiving it will make their own determination as to its suitability for their purpose prior to use. For additional information on recommended uses and procedures for use of the material, please contact our Quality Department(I) at 18 Ta-Tung First Rd., Kuan-Yin Industrial District Tao-Yuan Hsien, Taiwan ROC Tel : Fax : Current Issue Date: 2013/05/14 Page: 5 of 5
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