Safety Data Sheet. Manganese Sulfate Monohydrate
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1 Safety Data Sheet Product Name: Manganese Sulfate Monohydrate. Product Form: Substance. Synonyms: : Manganese Sulfate : Manganese Monosulfate : Manganese ( ll ) Sulfate Monohydrate : Manganese (2+) Sulfate Monohydrate Product Use: For further manufacturing of feed. For fertilizer. CAS Number: Formula: MnSO4. H2O Company Identification: Origination Inc McKnight Road North Maplewood, MN For information, call: Emergency Number: For CHEMTREC assistance, call: For International CHEMTREC assistance, call: GHS US STOT RE 2: H373 Aquatic Chronic 2: H411 NFPA (SCALE 0 4) Health 1 Fire 0 Reactivity 0 Labeling according to GHS-US Hazard pictograms (GHS-US): GHS08 GHS09 Signal word (GHS-US): Warning Hazard statements (GHS-US): H373 May cause damage to organs (central nervous system) through prolonged or repeated exposure (inhalation) H411 - Toxic to aquatic life with long lasting effects. Precautionary statements (GHS-US) : Do not breathe dust, fume.
2 Avoid release to the environment Avoid contact with eyes Avoid prolonged or repeated contact with skin Avoid ingestion Wear protective clothing, eye protection, protective gloves and dust mask. Dispose of contents / container accordingly to the current regulation Substance type: Mono-constituent Name Product Identifier % Probable Contaminants Manganese Sulfate Monohydrate (CAS No.) >=95 None First-aid measures general: When in doubt or if symptoms are observed, get medical advice. Never give anything by mouth to an unconscious person. First-aid measures after inhalation: If Inhaled: Remove to fresh air and keep at rest in a position comfortable for breathing. Medical examination necessary even merely on suspicion of intoxication. First-aid measures after skin contact: After contact with skin, wash immediately with plenty of water and soap. Wash contaminated clothing before reuse. First-aid measures after eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. First-aid measures after ingestion: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Most important symptoms and effects, both acute and delayed Symptoms / injures: Conjunctival redness. Burns. Indication of any immediate medical attention and special treatment needed: In case of doubt or persistent symptoms, consult always a physician. Extinguishing Media Suitable extinguishing media: Water fog or spray. Unsuitable extinguishing media: High power water jet Special hazards arising from the substance or mixture Fire hazard: Under fire conditions, hazardous fumes will be present. Explosion hazard: Not explosive. Reactivity: The product is stable at normal handling and storage conditions. Advice for Firefighters
3 Precautionary measures fire: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Protection during firefighting: In case of fire: Wear self-contained breathing apparatus. Personal precautions, protective equipment and emergency procedures General measures: See protective measures under point 7 and 8. Prevent unauthorized access. For non-emergency personnel Emergency procedures: Evacuate area. Protective equipment: Use personal protective equipment as required. For emergency responders Protective equipment: Use personal protective equipment as required. Wear breathing apparatus if exposed to Vapours / dusts /aerosols. Emergency procedures: Remove persons to safety. Environmental precautions: Avoid release to the environment. Methods and material for containment and cleaning up For containment: Collect spillage. Methods for cleaning up: Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Clean contaminated objects and areas thoroughly observing Environmental regulations. Reference to other sections: Treat the recovered material as prescribed in the section on waste disposal. See protective measures under point 7 and 8. Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for Safe Storage, Including Any Incompatibilities Technical measures: Keep container tightly closed and in a well-ventilated place. Storage conditions: Store in original container. Specific end use(s): No additional information available. Manganese sulfate monohydrate ( ) USA ACGIH ACGIH TWA (mg / m3) 0,2 mg/m³ USA OSHA Ceiling limit value (mg / m3) 5 mg/m³
4 Exposure Controls Appropriate engineering controls: Technical measures and the application of suitable work processes have priority over personal protection equipment. Personal protective equipment: Gloves. Safety glasses. Protective clothing. Dust formation: dust mask. Hand protection: Wear suitable gloves. Eye protection: Chemical goggles or face shield. Skin and body protection: Wear suitable protective clothing and gloves. Respiratory protection: If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn. Environmental exposure controls: Do not allow uncontrolled discharge of product into the environment. Avoid release to the environment. Physical state: Solid Molecular weight: g/mole Appearance: Powder and/or prills. Color: White to cream. Odor: Odorless. Odor threshold: Not applicable ph: 6,5 (450g/L) à 20 C Melting point: 450 C Freezing point: No data available Boiling point: No data available Flash point: Not applicable Flammability (solid, gas): Non-flammable. Explosive limits: Not explosive. Vapor pressure: No data available Relative vapor density at 20 C: No data available e Relative density: 2,93 at 22 C Solubility: Water: 45 % Self-ignition temperature: Non-flammable. Decomposition temperature: 850 C Viscosity, kinematic: No data available Viscosity, dynamic: No data available Explosive properties: Not explosive. Oxidizing properties: Not oxidizing. Evaporation rate: No data available. Partition Coefficient n-octanol / water: No data available. Others: Hygroscopic
5 Reactivity: The product is stable at normal handling and storage conditions. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: Under fire conditions, hazardous fumes will be present. Conditions to avoid: Extremely high temperatures. Incompatible materials: Strong oxidizers. Hazardous decomposition products: Under fire conditions, hazardous fumes will be present. Acute toxicity: Not classified. Manganese Sulfate Monohydrate ( ) LD50 oral rat LC50 inhalation rat (mg/l) > 2000 mg/kg > 4,98 mg/l Skin corrosion/irritation: Not classified. Serious eye damage/irritation: Not Classified (Based on available data, the classification criteria are not met). Respiratory or skin sensitization: Not classified. Germ cell mutagenicity: Not classified. Carcinogenicity: Not classified. Reproductive toxicity: Not classified. Specific target organ toxicity (single exposure): Not classified (Based on available data, the classification criteria are not met). Specific target organ toxicity (repeated exposure): May cause damage to organs (central nervous system) through prolonged or repeated exposure (inhalation). Aspiration hazard: Not classified (Based on available data, the classification criteria are not met). Toxicity: No additional information available. Persistence and Degradability: Manganese Sulfate Monohydrate ( ) LC50 fishes 1 Ecology - water 14,5 mg/l Toxic to aquatic life with long lasting effects Persistence and degradability: No additional information available. Bioaccumulative potential: Not established Mobility in soil: No additional information available. Results of PBT and vpvb assessment: No additional information available.
6 Other information: No additional information available. Waste disposal recommendations: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/containers to comply with local and federal regulations. Ecology - waste materials: Avoid release to the environment. In accordance with IMDG / ICAO / IATA / DOT UN: 3077 UN proper shipping name Proper Shipping Name: Environmentally hazardous substance, Solid, N.O.S.. Transport document description: UN 3077 Environmentally Hazardous Substance, Solid, N.O.S., 9, III, (E) Transport hazard class Class (UN): 9. Packing Group Packing group (UN): III. Marine pollutant: Other information: No supplementary information available Special Precautions for user Overland transport: No regulated for transport Transport by sea: No additional information available Air transport: No additional information available Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC Code: Not applicable Safety, health and environmental regulations / legislation specific for the substance or mixture US Federal Regulations: No listed on the United States TSCA (Toxic Substances Control Act) No listed on SARA 304 (Emergency release notification) No listed on SARA 311,312 (Acute hazard, Chronic hazard, Fire hazard, Reactivity hazard) Listed on SARA 313 (Specific toxic chemical listings) International regulations Canada: No listed on the Canadian DSL (Domestic substances List) WHMIS Classification: Class D Division 2 Subdivision B Toxic material causing other toxic effects Chemical safety assessment: No chemical safety assessment has been carried out.
7 Prepared by: Origination, Inc. Prepared: October, 2015 Disclaimer: The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Origination be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Origination has been advised of the possibility of such damages.
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SECTION 1: IDENTIFICATION Product Name: Aluminum Metal CAS No.: 7429-90-5 Chemical Formula: Al Other Names: Aluminum, Al, Metallic Aluminum Intended Use / Restrictions on Use: For professional/industrial
: Sodium Bicarbonate-Sodium Chloride Solution
Date of issue: 01/22/2014 Revision date: 03/13/2018 Supersedes: 03/13/2018 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Sodium Bicarbonate-Sodium
: Sodium Bromide, ACS
Date of issue: 05/04/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Substance name : Sodium Bromide,
: Magnesium Chloride, Hexahydrate
SECTION 1: Identification 1.1. Identification Product form Substance name Magnesium Chloride, Hexahydrate Date of issue: 01/24/2014 Revision date: 11/08/2017 Supersedes: 11/08/2017 Version: 1.1 : Substance
: PLASTIC ADDITIVE 18 CRS
Date of issue: 28/01/2014 Revision date: Supersedes: 27/06/2013 Version: 5.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance
: Thymolphthalein, ACS
SECTION 1: Identification 1.1. Identification Product form Substance name Chemical name Thymolphthalein, ACS Date of issue: 05/08/2015 Revision date: 05/15/2018 Supersedes: 05/18/2015 Version: 1.2 : Substance
: Ferroin Oxidation-Reduction Indicator
Date of issue: 10/04/1998 Revision date: 06/27/2017 Supersedes: 09/15/2015 Version: 1.3 SECTION 1: Identification 1.1. Identification Product form Product name Product code Other means of identification
: Citric Acid, Anhydrous
SECTION 1: Identification 1.1. Identification Product form Substance name Citric Acid, Anhydrous Date of issue: 10/24/2007 Revision date: 04/04/2017 Supersedes: 06/19/2013 Version: 1.1 : Substance CAS
: Methyl Orange, 0.1% Aqueous
Date of issue: 01/31/2014 Revision date: 05/20/2014 Supersedes: 01/31/2014 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product
: Potassium Iodate-Iodide, N ( M)
Date of issue: 09/23/2013 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name. Product code : Mixture : Potassium
: None under normal conditions Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification
SECTION 1: Identification 1.1. Identification Product form Date of issue: 05/11/2015 Revision date: 01/25/2017 Supersedes: 05/11/2015 Version: 1.1 : Mixtures Product name : Product code : LC26670 1.2.
: Potassium Metabisulfite
SECTION 1: Identification 1.1. Identification Product form Substance name Chemical name Potassium Bisulfite Date of issue: 04/21/2015 Revision date: 01/30/2018 Supersedes: 01/30/2018 Version: 1.1 : Substance
: Sodium Carbonate, 1.0N (0.5M)
Date of issue: 01/22/2014 Revision date: 03/20/2018 Supersedes: 03/20/2018 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Sodium Carbonate,
: CW106-SR Passivation
Date of issue: 05/18/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : 000989 : CW106-SR
ALBERDINGK U 2101 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: Identification 1.1. Identification Product form : Mixture Trade name : 1.2. Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier Manufacturer ALBERDINGK BOLEY INC
: Congo Red Indicator, 0.1% w/v
SECTION 1: Identification 1.1. Identification Product form Product name Product code Date of issue: 12/15/2014 Revision date: 04/20/2018 Supersedes: 12/15/2014 Version: 1.1 : Mixtures : : LC13360 1.2.