Lubrizol Engineered Polymers

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1 Lubrizol Engineered Polymers Innovative Thermoplastic Polyurethane (TPU) Solutions for Demanding Applications and Environments. South American Congress of Composites, Polyurethane and Engineering Plastics August 15 th, 2017 Buenos Aires, Argentina Rodrigo Chinen Technical Development Manager 2017 The Lubrizol Corporation. All rights reserved. All marks are property of the Lubrizol Corporation The Lubrizol Corporation. All rights reserved. All marks are property of the Lubrizol Corporation.

2 Agenda Company Overview What is Thermoplastic Polyurethane (TPU)? Lubrizol Solutions Overview Conclusion

3 The Lubrizol Corporation Company Overview Consolidated Revenues Worldwide Employees 6% 10% 4% 27% $6.5 Billion 40% 28% 8,300 Employees 58% 27% North America Europe Asia/ME Latin America Lubrizol is a market-driven, global specialty chemical company *2016 revenues **Employee number excludes Lubrizol Oilfield Solutions

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5 Commerical Brands Company Overview Estane TPU Estaloc RETPU Estagrip TPE Isoplast ETP Stat-Rite Carbo-Rite Pearlthane TPU Pearlthane ECO* TPU Pearlbond TPU Pearlbond ECO* TPU Pearlstick TPU Pearlcoat TPU * Bio-based content as certified in accordance with ASTM D-6866

6 Presence in Latin America Company Overview Lubrizol Sales Office Brasil Mexico Distributors and Sales Agents Asturquim (Argentina) Merquiand (Colombia) Proquimil (Brazil) Megajump (Brazil) Adizol (Chile ) Regional Support for Customers

7 Taber wt. loss (mg) TPU Abrasion Resistance What is TPU? X ABRASION RESISTANT THAN NEOPRENE

8 Tensile Strength (% of original) SAMPLE DESTROYED TPU Chemical Resistance What is TPU? 100% Oil Aging Strength Retention 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% Estane TPU COPE COPA TPV SBC ASTM Oil #1 ASTM Oil #3

9 Apparent Rigidity Modulus (Mpa) TPU Low Temp Flexibility (ASTM D1053) What is TPU? X MORE FLEXIBLE T H A N P V C C -20 C -40 C Estane TPU PVC TPV

10 Polymer Compatibility What is TPU? Deliver unique properties in alloys with polar polymers ABS, SAN Acrylic PBT PET, PETG Polycarbonate Polyesters PVC SEBS, SIBS

11 Applications of Lubrizol TPU What is TPU? Wire & Cable Industrial Equipment Robotics Athletic Footwear Specialty Fibers Clean Room Electronic Assemblies Packaging Disk Drives Food Conveying Hose & Protective Equipment Seals & Gaskets Performance Apparel Winter Sports Material Handling & Transport Protective Apparel Electronic Components Surface Protective Film Hose, Tube & Profile Soft Touch Surfaces Outdoor Gear Recreation Electronics Processing Products Tape & Reel Lubrizol technology delivers performance in high value, demanding applications Semi- Conductors

12 Lubrizol Engineered Polymers Solutions Self Healing for Eyewear Frames High Heat Resistant What do you need? Flame Retardant Hot Melt Adhesives TPU/PVC Coumpound

13 Estane VSN 9000 for Eyewear Frames Lubrizol Solutions Eyewear Frames High-end eyewear frames: Sunglasses, prescription (Rx), sports, etc. Key Features Suitable for prescription plastic frames: excellent resistance to chemicals (i.e IPA) Ability to use softer materials for over-molded parts for unique haptics and feel No need for primer Coating: better bonding to coatings Thinner lightweight frames: higher flexural modulus Ability to achieve very high gloss color (i.e piano black) without coating Ability to lower manufacturing cost due scratch: selfhealing Lower energy cost: at least 33 C (100 F) lower processing temperature Video: Self-Healing Estane VSN 9000: Unique Capability to self-heal minor scratches

14 Estane TS92AP7 High Heat Resistant TPU Lubrizol Solutions High Heat TPU Wire & Cable Markets: Automotive, Oil & Gas, Military, Alternative Energy, Communication, Transportation Key Features 125 C High temperature resistance for harsh and demanding applications Excellent chemical resistance and hydrolysis resistance Excellent biogas resistance Low temperature (-40 C) bending properties Superior abrasion and cut through resistance lasting longer and reducing overall cost Estane TS92AP7 meets the 125 C UL 1581 Temperature Rating

15 Estane Flame Retardant TPUs Lubrizol Solutions Flame Retardants Wide Flame Retardants solutions Halogenated Non-Halogenated (NHFR) Low Smoke, Zero Halogen (LSZH) Ability to Formulate a Wide Variety of Solutions

16 Lubrizol Technology to Enhance PVC Lubrizol Solutions PVC/TPU Soft TPU as an additive to PVC

17 TPU / PVC Compounds Brittleness Temp Lubrizol Solutions PVC/TPU

18 Low Melting Range Medium Melting Range High Melting Range TPU For Adhesives Lubrizol Solutions Hot Melt Adhesives Typical Hardness Range of 70A 94A (Shore Scale) Can have Amorphous or Crystalline Morphology Hot Melt TPU Adhesives Low Melting grades (60-90ºC) Medium Melting grades (90-140ºC) High Melting grades ( ºC) Melting Range (ºC)

19 Breakthrough For Thermobonding & Adhesives Film Lubrizol Solutions Hot Melt Adhesives New Solutions for Thermobonding & Adhesive Films Soft Hot Melt Soft Breathable Crystalline Film Fast & High-heat Pearlbond TM 301 EXP 50 Shore A Activation Temp. 100 C Pearlbond 360 EXP 68 Shore A Activation Temperature. 120C Pearlbond 1160 High-melt viscosity Activation Temp C Pearlbond 700 EXP Pearlbond 700HMS EXP Ultra Fast Activation Temp. >120 C Pearlbond 302 EXP 55 Shore A Activation Temp. 110 C Pearlbond 960 EXP 69+/- 3 Shore A Light stable Act. Temp<120 C Pearlbond 1160L Low-melt viscosity Activation Temp C Pearlbond 702 EXP Extremely Fast Activation Temp.>110 C Pearlbond 305 EXP 65 Shore A Activation Temp. 150 C Pearlbond 1170L Low-melt viscosity Activation Temp C Pearlbond 703 EXP Very Fast Activation Temp. >100 C

20 Conclusion Summary New Innovations, Expanding the Boundaries! Self Healing High Heat Resistant (125oC, UL 1581) Flame Retardants Hot Melt Adhesives And much more! Why Lubrizol? A Berkshire Hathaway Company Global manufacturing and technical support Experience serving the largest global consumer e industrial companies Several unique technologies and solution provider Let us be your partner!

21 Thank You Rodrigo Chinen Technical Development Manager (+55 11) The information contained herein is believed to be reliable, but no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for particular applications, how the product(s) will perform in combination with other substances or in the user s process or the results obtained. Because of the variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the products for the applications disclosed. Full-scale testing and end product performance are the responsibility of the user. Lubrizol Advanced Materials, Inc. shall not be liable for and the customer assumes all risk and liability of any use or handling of any material beyond Lubrizol Advanced Materials, Inc.'s direct control. The SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without permission of the patent owner. All and TM products listed in this presentation are owned by The Lubrizol Corporation The Lubrizol Corporation. All rights reserved 2017 The Lubrizol Corporation. All rights reserved. All marks are property of the Lubrizol Corporation.