2 Foam-Free 50 g/l dimethyl polysiloxane. 3 Fortune/Diamond 75% w/w mixed fatty acids esters of seed oil.

Transcription

1 CONTENTS PAGE PRODUCT NAME CONTAINS 2 Foam-Free 50 g/l dimethyl polysiloxane. 3 Fortune/Diamond 75% w/w mixed fatty acids esters of seed oil. 7 Glow Water conditioning agent. 9 Guard % w/w styrene/butadiene co-polymer. 12 Holdtite Carboxymethylcellulose sodium salt. Aqueous solution. 14 Intake 40% w/w propionic acid. 18 ZigZag 36.5% w/w styrene/butadiene co-polymer and 6.375% w/w polyether-modified trisiloxane. 21 Trademarks PAGE 1 ISSUE 3/14

2 FOAM-FREE HEADLAND FOAM-FREE A highly effective silicone-based agricultural/horticultural spray de-foamer for elimination of spray-tank foaming. Contains: 50 g/l dimethyl polysiloxane. Crops: Any. Pack size: 1 litre (trigger pack) Packs per pallet: 50 x 12 x 1 litre Introduction: HEADLAND FOAM-FREE is a silicone-based anti-foaming agent which can be used in any agricultural spraying situation where effective elimination of existing foam is required, or to prevent formation of foam if foaming is anticipated. Directions for Use: HEADLAND FOAM-FREE should be added to the spray tank while filling to prevent the build-up of foam. Use between 150 and 300 ml of product per 1000 litres of water. A typical 1500 litre tank will need at least 225 ml of product. Shake the container thoroughly before opening and use. Storage: Keep dry and cool in a suitable pesticide store. Protect from frost. Safety Precautions: WASH OUT CONTAINER THOROUGHLY. Empty washings into spray tank and dispose of safely. Regulatory Information: The Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or the product label. Transport: This product is not classified as hazardous for transport. Date of latest revision: December Significant changes since last issue: None. PAGE 2

3 FORTUNE/DIAMOND HEADLAND FORTUNE /DIAMOND An agricultural wetter/spreader. Contains 75% mixed fatty acid esters of seed oil and n-butanol. An emulsifiable spray adjuvant specially formulated to enhance the wetting, spreading and penetration of herbicides, fungicides and micronutrients. Crops: Numerous - see below. Pack size: 2.5, 5 or 10 litres Packs per pallet: 48 x 4 x 2.5 litres, 40 x 4 x 5 litres, 36 x 2 x 10 litres Introduction: HEADLAND FORTUNE/DIAMOND is a multi-functional spray adjuvant developed as a penetrating surfactant concentrate with superior wetting and penetrating properties. HEADLAND FORTUNE/DIAMOND works equally well with oil-based and water-based formulations due to its special emulsifier system and is ideally suited for use in multi-product tank mixes. HEADLAND FORTUNE/DIAMOND is a highly effective replacement for mineral oils used with e.g. fop and dim herbicides, Sugar Beet herbicides etc. In more than 5 years of field trials, 0.5 litres of HEADLAND FORTUNE has effectively replaced 1.0 litre of traditional mineral oil and is recommended by numerous herbicide manufacturers for application with their products. Directions for Use: HEADLAND FORTUNE/DIAMOND may be used with approved pesticides in accordance with the Conditions of Use (see below). The Conditions of Use of the partner pesticide must also be complied with. Use HEADLAND FORTUNE/DIAMOND at a concentration of % of total spray volume ( ml per 100 litres of water or pro rata). When used with Sugar Beet herbicides, this rate may be increased to 0.85% of water volume if required. Use the higher rate under difficult conditions such as high weed populations (herbicides), high disease pressures (fungicides), dense canopies, weather stress etc. Do not use HEADLAND FORTUNE/DIAMOND with any pesticide which is to be applied in or near water. Mixing: Charge the sprayer with half the recommended volume of water and the pesticide in accordance with the manufacturer s instructions. Add the required amount of HEADLAND FORTUNE/DIAMOND followed by the remaining water requirement as the last operation. Maintain agitation whilst mixing, travelling and spraying. Clean all equipment thoroughly after use. PAGE 3

4 FORTUNE/DIAMOND Compatibility: HEADLAND FORTUNE/DIAMOND is compatible with most foliar-applied pesticides. Please consult your Headland distributor for the latest information. Alternatively, up-to-date information on compatibilities may be found at The manufacturers of the following recommend the use of HEADLAND FORTUNE/DIAMOND with their products: Cheetah S, Falcon (volunteer cereals and blackgrass), Foxtrot (use in Wheat), Hawk, Laser, Lexus SX, Lexus Millenium, Topik (wild-oat and blackgrass) and Broadway Star (wild oats, ryegrass, sterile brome and broad-leaved weeds). Do not mix HEADLAND FORTUNE/DIAMOND with Shirlan or TIZCA. Storage: Keep dry and cool in a suitable pesticide store. Protect from frost - store above 5 C. If HEADLAND FORTUNE/DIAMOND is subjected to temperatures below 0 C it may thicken and become cloudy. It will return to its normal clear fluid state above 0 C. IMPORTANT INFORMATION: FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY WETTING AND SPREADING AGENT. Maximum Dose: All crops except Sugar Beet: 0.5% of water volume Sugar Beet: 0.85% of water volume Maximum number of treatments: Follow the statutory conditions of use of the pesticide. Latest Timings: On Cereals with morpholine or Follow the statutory conditions of triazole fungicides: use of the pesticide. On Sugar Beet with all approved Follow the statutory conditions of fungicides and herbicides: use of the pesticide. On crops not intended for human or Follow the statutory conditions of animal consumption: use of the pesticide. With approved pesticides on other crops - see below: Broad Bean, Dwarf French Bean First pod set Field Bean, Runner Bean: Peas: Flat pod (non-edible pods only) PAGE 4

5 FORTUNE/DIAMOND Edible Podded Peas Oilseed Rape Linseed Sugar Beet Cereals Forage Maize Brussel Sprouts Potatoes Cauliflower Apples/Pears Strawberries Raspberries Blackcurrants Cucumber Tomato Apricot, Plum, Peach Hops Other Specific Restriction: Pod set 10% potential pods 10% capsules formed 6 fully expanded leaves 1/4 inflorescence (GS52) Tip of tassel visible Lateral buds beginning to develop Tuber initiation Heads beginning to form (width up to 1 cm) Fruits 5-10 mm First fruit development First fruit set First visible green fruitlet First fruit set First fruit set on first truss First fruit set Cone set Do not use with any pesticide which is to be applied in or near water. Operator Protection: Follow the operator protection instructions for the partner pesticide. Where the personal protective equipment specified in this leaflet is different to that specified on the pesticide label, the highest level of protective equipment must be worn. Regulatory Information: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Irritant Xi Risk Phrases: R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. PAGE 5

6 FORTUNE/DIAMOND Safety Phrases: S2 Keep out of reach of children. S24 Avoid contact with skin. S37/39 Wear suitable protective gloves and eye/face protection. S57 Use appropriate containment to avoid environmental contamination. Adjuvant Authorisation Number: ADJ 0703 The (CoSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Transport: This product is not classified as hazardous for transport. Overseas registrations: HEADLAND FORTUNE/DIAMOND is approved as a pesticide adjuvant in New Zealand, Holland and the Irish Republic. Contact Headland Agrochemicals for further information. Date of latest revision: December Significant changes since last issue: None. PAGE 6

7 GLOW HEADLAND GLOW An agricultural water conditioner. A preparation of sequestering, chelating and buffering agents for softening and conditioning water used for spraying agricultural chemicals. Crops: Any. Pack size: 5 litres Packs per pallet: 40 x 4 x 5 litres Introduction: The performance of many agrochemicals and fertilisers is impeded when applied with water which is either alkaline, hard, brackish or contaminated with insoluble deposits and impurities of calcium, magnesium, bicarbonates etc. In such conditions agrochemicals and fertilisers that are prone to hydrolysis may degrade or precipitate, resulting in poor performance due to lack of active ingredients particularly when multi-product tank mixing is required. Mode of Action: HEADLAND GLOW contains a blend of chemicals that soften and condition the water and optimise the pesticide or fertiliser application: Complexed acidifiers to reduce ph and minimise hydrolysis; A long-chain polymer based water softener; A sequestering agent to isolate cationic contaminants; Buffering agents to improve tank-mixing compatibility; Spreading and sticking agents to enhance foliar cover. Directions for Use: The hardness of the spray water determines the amount of HEADLAND GLOW to be added to the spray tank. Soft water 0.5 l/1000 l water (0.05% or 100ml/200 l) Med/hard water 1 l/1000 l water (0.1% or 200ml/200 l) Hard water 2 l/1000 l water (0.2% or 400ml/200 l) If the degree of hardness of the water is unknown, the amount of HEADLAND GLOW required may be determined by use of a water testing kit. Water testing kit: Take a 1 litre sample from the water supply. Add 1 measured dose (0.5ml = 1 pump) of HEADLAND GLOW Testing Indicator to the water to obtain an initial colour. Continue to add measured 0.5ml quantities of Testing Indicator until a yellow/amber colour is achieved. At ph 5.0 and above the water is blue. At ph 4.9 and below the water colour will change to green. At ph 4.3 and below the water will change to yellow. PAGE 7

8 GLOW Every 0.5ml of Testing Indicator added to the test sample is equivalent to 250ml of HEADLAND GLOW added to 1000 litres of spray-tank water. It is advisable to check samples of water regularly as ph of water can vary frequently. Mixing: Always add the required amount of HEADLAND GLOW to the water in the spray tank and agitate to ensure dispersion before adding the pesticide or fertiliser. Storage: Keep dry and cool in a suitable chemical store. Protect from frost - store above 5 C. Regulatory Information: The European Regulation (EC) No. 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures (CLP Regulation) the EU Globally Harmonised Systems (GHS) apply to this product. Label elements under CLP: Hazard Statements: H314 Causes severe skin burns and eye damage. Signal Words: Danger Hazard Pictograms: GHS05 Corrosion Precautionary Statements: P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P IF SWALLOWED: rinse mouth Do NOT induce vomiting. P IF IN EYES: Rinse cautiously with water for +338 several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P IF ON SKIN (or hair): Remove immediately all +353 contaminated clothing. Rinse skin with water. P405 Store locked up. Transport: This product is classified as hazardous for transport. UN number: UN proper shipping name: Transport hazard class(es): 8 Packing group: III Environmentally hazardous: No Marine pollutant: No Date of Issue: December Significant changes since last issue: Classification to CLP and Classification for transport. PAGE 8 UN1760 CORROSIVE LIQUID, N.O.S. ORTHOPHOSPHORIC ACID) 100%

9 GUARD 2000 HEADLAND GUARD 2000 An agricultural/horticultural sticker-extender. Contains 10% w/w styrene/butadiene co-polymer. A sticking and extending adjuvant specially formulated for mixing with approved pesticides, plant growth stimulants and micronutrients. Crops: Numerous - see below. Pack size: Packs per pallet: 2.5 litres 48 x 4 x 2.5 litres Introduction: HEADLAND GUARD 2000 is a sticker/extender for use in tank mix with crop protection chemicals in situations where product performance may be adversely affected by unfavourable weather or crop growing conditions. A key area of use is in Potatoes and the product is authorised for use with all approved Potato blight fungicides. HEADLAND GUARD 2000 is an organic copolymer/biodegradable surfactant blend and is designed to provide: Rainfastness Improved foliar cover Improved foliar retention of spray Protection against irrigation wash-off Protection from u-v decomposition Protection against evaporation loss. HEADLAND GUARD 2000 may also be used to reduce drift where this is a concern. Directions for Use: HEADLAND GUARD 2000 may be used with approved pesticides in accordance with the Conditions of Use (see page 2). The Conditions of Use of the partner pesticide must also be complied with. The Conditions of Use do not apply to use of HEADLAND GUARD 2000 with foliar-applied micronutrients or seaweed-based plant growth stimulants. Application Rate: Use HEADLAND GUARD 2000 at 0.1% of total spray volume (100 ml per 100 litres of water or pro rata). Mixing: Prepare the pesticide spray mixture in accordance with the manufacturer s instructions. Add the required amount of HEADLAND GUARD 2000 to the spray mix as the last operation. Maintain agitation whilst mixing, travelling and spraying. Clean all equipment thoroughly after use. PAGE 9

10 GUARD 2000 Compatibility: HEADLAND GUARD 2000 is compatible with most foliar-applied pesticides. Consult your distributor for the latest information. Alternatively, up-to-date compatibility information may be found at Do not mix HEADLAND GUARD 2000 with formulations of bifenox. HEADLAND GUARD 2000 s superior adhesive properties may interfere with the vapour phase activity of pirimicarb formulations so mixtures with these are not recommended. Storage: Keep dry and cool in a suitable pesticide store. Protect from frost. Safety Precautions: KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS. DO NOT USE WITH ANY PESTICIDE WHICH IS TO BE APPLIED IN OR NEAR WATER. Conditions of Use: IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY STICKING AND EXTENDING AGENT. Maximum Concentration: Maximum number of treatments: 0.1% of spray volume Follow the statutory conditions of use of the pesticide. Latest Timings: With all approved pesticides for use on crops not intended for human or animal consumption: On Potatoes with all approved Potato blight fungicides: Follow the statutory conditions of use of the pesticide. Follow the statutory conditions of use of the pesticide. With approved pesticides on other crops - see below: Beans First pod set Peas Flat pod Edible Podded Peas Pod set Oilseed Rape 10% potential pods Linseed 10% capsules formed PAGE 10

11 GUARD 2000 Sugar Beet Cereals Maize Brussels Sprouts Potatoes (other than with Blight fungicides - see previous page): Cauliflower Cucumber Tomato Strawberry Raspberry Blackcurrant Apples/Pears Cherry/Plum 6 fully expanded leaves 1/4 inflorescence (GS52) Tip of tassel visible Lateral buds beginning to develop. Tuber initiation Heads beginning to form (width up to 1 cm) First fruit set First fruit set on first truss First fruit development First fruit set First visible green fruitlet Fruits 5-10 mm First fruit set. Note: These latest timings do not apply to the use of HEADLAND GUARD 2000 with micronutrients or seaweed-based plant growth stimulants. Regulatory Information: The Chemicals (Hazard Labelling and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Adjuvant Authorisation Number: ADJ 0652 The (CoSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Transport: This product is not classified as hazardous for transport. Overseas Registrations: HEADLAND GUARD 2000 is also registered for use as a pesticide adjuvant in New Zealand, Greece, Holland and the Republic of Ireland. Contact Headland Agrochemicals for further information. Date of latest revision: December Significant changes since last issue: None. PAGE 11

12 HOLDTITE HOLDTITE A sticker and anti-shattering agent to reduce seed loss from pod splitting before and during harvest. Contains an aqueous solution of carboxymethylcellulose sodium salt. Crops: Oilseed Rate and other podded crops. Pack size: 5 litres Packs per pallet: 4 x 5 x 40 litres Introduction: HOLDTITE is an anti-shattering and anti-pod splitting agent for application at any time from when the pods are full size, up to when they begin to split. Application: Fill the spray tank to the three quarter level with water and commence agitation. Add the required volume of HOLDTITE. Agitate the mixture continuously whilst filling up the tank and during application. Spray immediately. Apply as a MEDIUM quality spray. If applied in mixture with a crop desiccation product, apply in accordance with the label recommendations of the partner product. Following Application: Do not allow HOLDTITE or its residues to dry out in the tank or spray lines. Immediately after operation, rinse the sprayer thoroughly with a suitable non-ionic surfactant, ensuring the entire tank, pump, boom and nozzles are flushed through. If HOLDTITE is to be applied on consecutive days, at the end of each day s operation, fill the tank with water and spray sufficient out to ensure tank, boom and nozzles are cleaned then top the tank up. Compatibility: HOLDTITE may be mixed with glyphosate, diquat or glufosinate-ammounlum as long as the resultant mixture is used in accordance with the herbicide label. Storage: Protect from frost. Store above 5ºC. Keep away from food, drink and feed. Ensure adequate ventilation in working area. PAGE 12 ISSUE 5/13

13 HOLDTITE Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or the Product Label for full details. Transport Information: This product is not hazardous for transport. Date of previous revision: New, May PAGE 13 ISSUE 5/13

14 INTAKE HEADLAND INTAKE An agricultural penetrant. Contains 40% w/w propionic acid. A wetting and penetrating adjuvant specially formulated for mixing with approved pesticides, plant growth stimulants and micronutrients. Crops: Numerous - see below. Pack size: Packs per pallet: 2.5 litres 48 x 4 x 2.5 litres Introduction: HEADLAND INTAKE is an agricultural wetting agent specially formulated for inclusion in tank mixes with a wide range of foliar-applied herbicides, fungicides, insecticides and plant growth regulators. It may also be used as an acidifier to optimise ph when water used for spraying is alkaline. HEADLAND INTAKE contains a blend of organic acids and surface active agents and has been designed to achieve: Rapid foliar penetration Improved wetting Improved coverage Optimisation of spray water ph. HEADLAND INTAKE should be used when rapid penetration of a pesticide is required and when slow growth, cold weather, or waxy leaf surfaces may reduce the efficacy of chemical Applications. Post-emergence herbicides, wild-oat herbicides, systemic fungicides and insecticides, systemic total herbicides and plant growth regulators can all benefit from the use of HEADLAND INTAKE when such conditions prevail. Directions for Use (1): Use With Approved Pesticides HEADLAND INTAKE may be used with approved pesticides in accordance with the Conditions of Use (see page 2/4). The Conditions of Use of the partner pesticide must also be complied with. Use HEADLAND INTAKE at 0.5% of total spray volume (500 ml per 100 litres of water or pro rata). PAGE 14

15 INTAKE Directions for Use (2): Use as a Water Acidifier HEADLAND INTAKE may be used to optimise water ph when hard or alkaline water is being used for spraying. Use at 0.1% of spray volume (100 ml per 100 litres of water or pro rata). This application of the product is not subject to the Conditions of Use. Mixing (1): Prepare the pesticide spray mixture in accordance with the manufacturer s instructions. Add the required amount of HEADLAND INTAKE to the spray mix as the last operation when the pesticide has been fully dispersed in the bulk of the water. Maintain agitation whilst mixing, travelling and spraying. Clean all equipment thoroughly after use. Mixing (2): When using HEADLAND INTAKE as a water acidifier, always add the required amount of HEADLAND INTAKE to the water in the spraytank and agitate to ensure dispersion before adding the pesticide. Compatibility: HEADLAND INTAKE is compatible with most foliar-applied pesticides. Consult your distributor for the latest information. Alternatively, up-to-date information on compatibilities may be found at Do not mix HEADLAND INTAKE with formulations of quizalofop-ethyl or bifenox. Do not use HEADLAND INTAKE with chlormequat/trinexapac-ethyl mixtures in Cereals as excessive straw shortening and yield loss may result. Storage: Keep dry and cool in a suitable pesticide store. Protect from frost - store above 5 C. Disposal: Wash out container thoroughly, empty washings into spray tank and dispose of safely. Do not re-use container for any purpose. Conditions Of Use: FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY WETTING AGENT. Maximum concentration: 0.5% of spray volume. Maximum number of treatments: Follow the statutory conditions of use of the pesticide. PAGE 15

16 INTAKE Latest Timings: With all approved pesticides which Follow the statutory conditions of recommend the use of a use of the pesticide. wetting agent: With plant growth regulators GS52 ( 1 /4 inflorescence) or the latest in Cereal crops: time given on the partner pesticide label, whichever is earlier. On crops not intended for human or Follow the statutory conditions of animal consumption: use of the pesticide. With approved pesticides on other crops - see below: Beans First pod set Peas Flat pod Edible Podded Peas Pod set Oilseed Rape 10% potential pods Linseed 10% capsules formed Sugar Beet 6 fully expanded leaves Cereals 1/4 inflorescence (GS52) Maize Tip of tassel visible Brussel Sprouts Lateral buds beginning to develop Potatoes Tuber initiation Cauliflower Heads beginning to form (width up to 1 cm). Note: These latest timings do not apply when HEADLAND INTAKE is used only as a water acidifier. Operator Protection: Operators must follow all operator protection instructions for the partner pesticide. Where the personal protective equipment specified on this label is different to that specified on the pesticide label, the highest level of personal protective equipment must be worn. Regulatory Information: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Corrosive C Risk Phrase: R34 Corrosive. Causes burns. Safety Phrases: S1 Keep under lock and key. S2 Keep out of reach of children. S23 Do not breathe vapours or spray mist. S24/25 Avoid contact with skin and eyes. PAGE 16

17 INTAKE S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 In case of contact with skin, rinse immediately with plenty of water. S36/37/39 Wear suitable protective clothing, suitable gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately. The (CoSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Product Authorisation Number: ADJ 0074 Transport: This product is classified as hazardous for transport. Road Transport: Corrosive UN Number: 1760 Proper Shipping Name: Corrosive liquid N.O.S. (PROPIONIC ACID solution) UN Class: 8 CPL Packing Group: III ADR/RID Description: Corrosive liquid IMDG Class: 8 Corrosive Overseas Registrations: HEADLAND INTAKE is also registered for use as a pesticide adjuvant in Australia, New Zealand, Holland and the Irish Republic. Contact Headland Agrochemicals Ltd for further details. Date of latest revision: December Significant changes since last issue: None. PAGE 17

18 ZIGZAG ZIGZAG An adjuvant with sticking, wetting and extending properties, for use with pesticides and micronutrients. Contains 36.5% w/w styrene/butadiene co-polymer and 6.375% w/w polyether-modified trisiloxane. A formulated spray adjuvant for enhancing the wetting, spreading and penetration of pesticides, micronutrients and seaweed-based foliar feeds. The product is particularly suitable for application with glyphosate formulations. Crops: Numerous - see below. Pack size: 2.5 litres Packs per pallet: 48 x 4 x 2.5 litres Directions for Use: ZIGZAG may be used with approved pesticides in accordance with the Conditions of Use (see page 2). The Conditions of Use of the partner pesticide must also be complied with. Use ZIGZAG at 0.125% of water volume of total spray volume (250 mls per 200 litres of water or pro rata). Do not use ZIGZAG with any pesticide which is to be applied in or near water. Mixing: Shake the container well before opening and use. Half-fill the spray tank with clean water. Add the required amount of pesticide in accordance with the manufacturer s instructions and agitate well to ensure thorough dispersion. Add the required amount of ZIGZAG whilst maintaining agitation, complete the filling with water and apply without delay. Thoroughly clean the sprayer after use. Compatibility: ZIGZAG is compatible with most foliar-applied pesticides. Please consult your Headland distributor for the latest information. Alternatively, up-to-date information on compatibilities may be found at Storage: Keep dry and cool in a suitable pesticide store. Protect from frost - store above 5 C. PAGE 18

19 ZIGZAG Conditions of Use: IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL /HORTICULTURAL/FORESTRY STICKER/EXTENDER AND WETTER. Maximum Dose: All crops 0.125% of water volume Maximum number of treatments: Refer to the partner pesticide label Latest Timings: With approved formulations of glyphosate on all Cereal crops at any growth stage: Refer to the partner pesticide label With approved pesticides applied at half or less than half of the approved rate: Refer to the partner pesticide label With approved pesticides on crops not intended for human or animal consumption: Refer to the partner pesticide label With approved pesticides on edible crops - see below: Beans Peas Edible Podded Peas Oilseed Rape Linseed Cereals Maize Brussels Sprouts Potatoes Cauliflower Apple/Pear: Cherry/Plum: Apricot/Almond/Peach: First pod set Flat pod Pod set 10% potential pods 10% capsules formed 1/4 inflorescence (GS52) (post GS52 with glyphosate formulations - see above). Tip of tassel visible Lateral buds beginning to develop Tuber initiation Heads beginning to form (width up to 1 cm) Fruits 5-10 mm First fruit set First fruit set Other Specific Restriction: Do not use with any pesticide which is to be applied in or near water. PAGE 19

20 ZIGZAG Note: The latest timings given above do not apply when ZIGZAG is used in conjunction with micronutrient products or with seaweed-based growth stimulators and fertilisers. Operator Protection: Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment: WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND FACE PROTECTION (FACESHIELD) when handling the concentrate. However, engineering controls may replace personal protective equipment if a CoSHH assessment shows they provide an equal or higher standard of protection. Operators must follow all operator protection instructions for the partner pesticide. Where the personal protective equipment specified in this leaflet is different to that specified on the pesticide label, the highest level of protective equipment must be worn. Regulatory Information: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Irritant Xi Risk Phrases: R41 Risk of serious damage to eyes. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: S2 Keep out of reach of children. S24 Avoid contact with eyes. S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice. S39 Wear eye/face protection. S57 Use appropriate containment to avoid environmental contamination. Adjuvant Authorisation Number: ADJ 0692 The (CoSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Transport: This product is not classified as hazardous for transport. Date of issue: December Significant changes since last issue: None. PAGE 20

21 TRADEMARK ACKNOWLEDGEMENTS Headland Fortune, Headland Guard 2000, Holdtite and ZigZag are Headland registered trademarks. Foam-free, Headland Glow and Headland Intake are Headland trademarks. PAGE 21 ISSUE 3/14