SPECIAL PROVISION Asphalts, Oils and Emulsions

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1 1995 Metric SPECIAL PROVISION Asphalts, Oils and Emulsions For this project, Item 300, Asphalts, Oils and Emulsions, of the Standard Specifications, is hereby amended with respect to the clauses cited below, and no other clauses or requirements of this Item are waived or changed hereby. Article Materials, is supplemented by the following: (11) Modified Performance Graded Asphalt Binder. The grades of modified performance graded asphalt binders available and the requirements are as follows: A) SBR latex rubber modified performance graded binders: PG 64-28L, PG 70-28L, PG 70-22L, PG 76-22L and PG 82-22L 1) Binders shall be smooth, homogeneous, and meet the requirements of Table 11. 2) The manufacturer shall provide certification that SBR latex rubber was used in production of the binder. 3) Ductility (AASHTO T51), 4 C, 10 mm/min, mm, 700 mm minimum. 4) Binders shall show no separation when tested according to Tex-540-C, "Measurement of Polymer Separation on Heating in Modified Asphalt Systems". (If (1) the modifier is introduced separately at the mix plant either by injection in the asphalt line or mixer; or (2) the binder is blended on site in continuously agitated tanks; or (3) binder acceptance is based on field samples taken from an inline sampling port at the hot mix plant after the addition of modifiers; separation testing is not required.) B) SBS rubber modified performance graded binders: PG 64-28S, PG 70-28S, PG 70-22S, PG 76-22S, and PG 82-22S 1) Binders shall be smooth, homogeneous, and meet the requirements of Table 11. 2) The manufacturer shall provide certification that SBS rubber was used in production of the binder. 3) Elastic recovery (Tex-539-C), 10 C - 55% minimum

2 4) Binders shall show no separation when tested according to Tex-540- C, "Measurement of Polymer Separation on Heating in Modified Asphalt Systems". (If (1) the modifier is introduced separately at the mix plant either by injection in the asphalt line or mixer; or (2) the binder is blended on site in continuously agitated tanks; or (3) binder acceptance is based on field samples taken from an inline sampling port at the hot mix plant after the addition of modifiers; separation testing is not required.) C) Tire Rubber Modified Performance Graded Binders: PG 64-28TR, PG 70-28TR, PG 70-22TR, PG 76-22TR, and PG 82-22TR 1) Binders shall be smooth, homogeneous, and meet the requirements of Table 11. 2) The manufacturer shall provide certification that tire rubber was used in production of the binder. 3) Elastic recovery (Tex-539-C), 10 C - 40% minimum. 4) Binders shall show no separation when tested according to Tex-540-C, "Measurement of Polymer Separation on Heating in Modified Asphalt Systems". (If (1) the modifier is introduced separately at the mix plant either by injection in the asphalt line or mixer; or (2) the binder is blended on site in continuously agitated tanks; or (3) binder acceptance is based on field samples taken from an inline sampling port at the hot mix plant after the addition of modifiers; separation testing is not required.) D) Multigrade Modified Performance Graded Binders: PG 64-28MG, PG 70-28MG, PG 70-22MG, PG 76-22MG, and 82-22MG 1) Binders shall be smooth, homogeneous, and meet the requirements Table 11. 2) The manufacturer shall provide certification that gelling agent was used in production of the binder. 3) Float test (AASHTO T50), 60 C, seconds minimum. E) Binders shall show no separation when tested according to Tex-540-C, "Measurement of Polymer Separation on Heating in Modified Asphalt Systems". (If (1) the modifier is introduced separately at the mix plant either by injection in the asphalt line or mixer; or (2) the binder is blended on site in continuously agitated tanks; or (3) binder acceptance is based on field samples taken from an in-line sampling port at the hot mix plant after the addition of modifiers; separation testing is not required.) Acceptance of Performance Graded Binder. Performance graded binder acceptance procedures are dependent on where the binder is manufactured. The requirements are as follows:

3 Performance Graded Binders Manufactured at the Source. PG binders are manufactured at the source are normally approved at the source according to the applicable requirements of the Construction Division, Materials Section. The Engineer may acquire field samples at any time, particularly if material quality is suspect. Performance Graded Binders Manufactured at the Jobsite. If PG binders are manufactured at the jobsite, for example where SBR latex is injected at the hot mix plant, the following quality measures are required: (Antistrip agents are not considered asphalt modifiers). Preconstruction. The Contractor shall provide the Engineer with a 1-liter sample of the proposed binder and a test report showing compliance with the required performance grade. The sample and test report will be forwarded to the Construction Division, Materials Section for verification testing. The Materials Section will complete verification testing within ten (10) working days after receipt of the sample. The sample shall be verified before mixture production is allowed to begin. Construction. Construction Sampling. A sampling port is required which meets the requirements of AASHTO Designation T40, "Practice for Sampling Bituminous Materials", Section 9, "Sampling from Pipelines during Loading or Unloading". This sampling port shall be located on the asphalt line before introduction of the asphalt into the mix plant and shall be down stream from the addition of any modifiers and any dispersing or mixing equipment associated with their introduction. Sample containers shall be provided by the Contractor and shall be clean, double friction top round 1-liter cans. All samples shall be taken by the Contractor, and witnessed by the Engineer. All samples shall be taken from the sampling port after a sufficient amount of asphalt is run out and wasted, in order to clear any residual asphalt which builds up in the sampling port. All samples shall be taken in a clean, 4-liter can, immediately stirred and used to fill three (3) 1-liter sample cans. The cans shall be delivered to the Engineer. The Engineer will choose one sample can for testing and the other cans are retained until testing is complete, in case the original sample is lost or damaged. Sampling Frequency. A sample of the PG binder shall be taken from each mixture production day, at a time determined by the Engineer. The sample from the first day's production shall be subjected to verification testing. Additionally, the Engineer will randomly select a minimum of one (1) sample from every nine (9) daily binder samples (or a minimum of one (1) sample per project if there are less than nine (9) mixture production days) for verification testing. Verification Testing. Verification testing will be performed on all construction samples by the Construction Division, Materials Section. The Materials Section will complete verification testing within ten (10) working days after receipt of the sample

4 For verification testing which fails to confirm the required performance grade, the Contractor shall review the manufacturing process to locate the source of the problem. The Engineer may stop production until the Contractor can show that the next binder produced will meet the specifications. The Engineer may require materials not meeting the specification requirements to be removed and replaced at the Contractor's expense. Article Storage, Heating and Application Temperatures is supplemented by the following: Performance graded asphalt binders containing particulate or polymer modifiers may be susceptible to separation of the modifier. Appropriate circulation or agitation in storage shall be provided if separation of the modifier is expected or suspected, and in every case when the modifier binder will be stored at elevated temperatures for more than one day before use. Table 10, describing application and storage temperatures is supplemented by the following: Application Type-Grade Recommended Range, C Maximum Allowable, C Heating and Storage Maximum, C All PG Binders Binder or modifier supplier instructions regarding recommended application and storage temperatures shall supersede the above guidelines. Table 11 Performance Graded Asphalt Binders PG 58 PG 64 Performance Grade Avg. 7-day Max Pvmt Design Temp, C(a) Min Pvmt Design Temperature, C(a) >-22 >-28 >-34 >-16 >-22 >-28 >-34 Original Binder Flash Point Temp, AASHTO T48:Min C 230 Vis, AASHTO TP48(b,c) Max, 3.0 Pa*s, Test Temp, C 135 Dynamic Shear, ASHTO TP5(d) G*/sind, Min, 1.00 kpa Test rad/s, C Rolling Thin Film Over (Tex-541-C) Max Loss, Maximum, percent 1.0 Dynamic Shear, AASHTO TP5: G*/sind, Min:2.20 kpa Test 10 rad/s, C Pressure Aging Vessel Residue (AASHTO PP1) PAV Aging Temperature, C 100 Dynamic Shear, AASHTO TP5: G*sind, Max, kpa Test 10 rad/s, C Creep Stiffness, AASHTO TP1:(e,f) S, Max, MPa, M - value, Min, Test s, C Dir. Tension, AASHTO TP3:(f) Failure Strain, Min, 1.0% Test 1.0 mm/min, C

5 PG 70 PG 76 Performance Grade Avg. 7-day Max Pvmt Design Temp, C(a) Min Pvmt Design Temperature, C(a) >-16 >-22 >-28 >-34 >-16 >-22 >-28 >-34 Original Binder Flash Point Temp, AASHTO T48:Min C 230 Vis, AASHTO TP48(b,c) Max, 3.0 Pa*s, Test Temp, C 135 Dynamic Shear, ASHTO TP5(d) G*/sind, Min, 1.00 kpa Test rad/s, C Rolling Thin Film Over (Tex-541-C) Max Loss, Maximum, percent 1.0 Dynamic Shear, AASHTO TP5: G*/sind, Min:2.20 kpa Test 10 rad/s, C Pressure Aging Vessel Residue (AASHTO PP1) PAV Aging Temperature, C 100 Dynamic Shear, AASHTO TP5: G*sind, Max, 5000 kpa Test 10 rad/s, C Creep Stiffness, AASHTO TP1:(e,f) S, Max, 300 MPa, M - value, Min, Test Temp s, C Dir. Tension, AASHTO TP3:(f) Failure Strain, Min, 1.0% Test 1.0 mm/min, C PG 82 Performance Grade Avg. 7-day Max Pvmt Design Temp, C(a) 82 Min Pvmt Design Temperature, C(a) >-16 >-22 >-28 Original Binder Flash Point Temp, AASHTO T48:Min C 230 Vis, AASHTO TP48(b,c) Max, 3.0 Pa*s, Test Temp, C 135 Dynamic Shear, ASHTO TP5(d) G*/sind, Min, 1.00 kpa Test rad/s, C 82 Rolling Thin Film Over (Tex-541-C) Max Loss, Maximum, percent 1.0 Dynamic Shear, AASHTO TP5: G*/sind, Min:2.20 kpa Test 10 rad/s, C 82 Pressure Aging Vessel Residue (AASHTO PP1) PAV Aging Temperature, C 100 Dynamic Shear, AASHTO TP5: G*sind, Max, kpa Test 10 rad/s, C Creep Stiffness, AASHTO TP1:(e,f) S, Max, MPa, M - value, Min, Test s, C Dir. Tension, AASHTO TP3:(f) Failure Strain, Min, 1.0% Test 1.0 mm/min, C a. Pavement temperatures are estimated from air temperatures using an algorithm contained in the PGEXCEL3.XLS software program, may be provided by the specifying agency, or by following the procedures as outlined in AASHTO MP2 and PP

6 b. This requirement may be waived at the discretion of the specifying agency if the supplier warrants that the asphalt binder can be adequately pumped, mixed and compacted at temperatures that meet all applicable safety, environmental and constructability requirements. At test temperatures where the binder is a Newtonian fluid, any suitable standard means of viscosity measurement may be used, including capillary (AASHTO T201 or T202) or rotational viscometry (AASHTO TP48). c. Viscosity at 135C is an indicator of mixing and compaction temperatures that can be expected in the lab and field. High values may indicate high mixing and compaction temperatures. Additionally, significant variation can occur from batch to batch. Contractors should be aware that variation could significantly impact their mixing and compaction operations. Contractors are therefore responsible for addressing any constructability issues which may arise. d. For quality control of unmodified asphalt cement production, measurement of the viscosity of the original asphalt cement may be substituted for dynamic shear measurements of G*/sind at test temperatures where the asphalt is a Newtonian fluid. Any suitable standard means of viscosity measurement may be used, including capillary (AASHTO T201 or T202) or rotational viscometry (AASHTO TP48). e. Silicone beam molds as described in AASHTO TP1-93 are acceptable for use. f. If the creep stiffness is below 300 MPa, the direct tension test is not required. If the creep stiffness is between 300 and 600 MPa, the direct tension failure strain requirement can be used in lieu of the creep stiffness requirement. The m-value requirement must be satisfied in both cases

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