Super Concentrated Screen-Wash 21+ Safety Data Sheet according to Regulation (EC) No. 453/2010

Transcription

1 MSDS Version: E05.00 Date of issue: 30/08/2013 Blend Version: 4 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Product code : W Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Use of the substance/mixture : Prevents freezing of screen-wash system Uses advised against 1.3. Details of the supplier of the safety data sheet Wynn's Belgium Industriepark-West Sint-Niklaas - Belgium T F msds@wynns.eu Emergency telephone number Emergency number : BIG: +32(0)14/ SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 Full text of H-phrases: see section 16 H226 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] R10 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS02 : Warning : H226 - Flammable liquid and vapour : P102 - Keep out of reach of children P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool Allergenic fragrances > 0,01%: D-LIMONENE Detergent Regulation : Labelling of contents:(regulation (EC) No. 648/2004 of 31 March 2004 on detergents): Component % anionic surfactants <5% Perfume 30/04/2015 EN (English) 1/7

2 D-LIMONENE 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % w Classification according to Directive 67/548/EEC Ethanol (CAS No) (EC no) (EC index no) (REACH-no) F; R11 Name Product identifier % w Classification according to Regulation (EC) No. 1272/2008 [CLP] Ethanol (CAS No) (EC no) (EC index no) (REACH-no) Flam. Liq. 2, H225 Eye Irrit. 2, H319 Name Product identifier Specific concentration limits Ethanol (CAS No) (EC no) (EC index no) (REACH-no) Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion (C >= 50) Eye Irrit. 2, H319 : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Vomiting: prevent asphyxia/aspiration pneumonia. Victim in shock: on his back with legs slightly raised. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. : Remove victim to fresh air. : After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water and soap. Take victim to a doctor if irritation persists. : Rinse immediately with plenty of water. Take victim to an ophtalmologist if irritation persists. : Rinse mouth thoroughly with water. Do not induce vomiting. Ingestion of large quantities: immediately to hospital Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : All extinguishing media can be used Special hazards arising from the substance or mixture Fire hazard : None to our knowledge. If there is a fire close by, use suitable extinguishing agents. : Flammable liquid and vapour. 30/04/2015 EN (English) 2/7

3 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Safety glasses. Gloves. : Mark the danger area. Wash contaminated clothes. : Equip cleanup crew with proper protection Environmental precautions Prevent spreading in sewers. Prevent soil and water pollution Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Contain leaking substance, pump over in suitable containers Conditions for safe storage, including any incompatibilities Storage conditions Heat and ignition sources Storage area Special rules on packaging 7.3. Specific end use(s) : Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Clean contaminated surfaces with an excess of water. : meet the legal requirements. No particular risk when handled in accordance with good occupational hygiene practice. Avoid exposure - obtain special instructions before use. Store in a closed container. : Observe normal hygiene standards. Wash contaminated clothing before reuse. : Keep container tightly closed. Meet the legal requirements. : Keep away from heat. : Meet the legal requirements. : Keep only in original container. correctly labelled. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethanol ( ) Belgium Limit value (mg/m³) 1907 mg/m³ Belgium Limit value (ppm) 1000 ppm 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Does not require any specific or particular technical measures. : Gloves. Safety glasses. Hand protection : neoprene. nitrile. PVC (Polyvinyl chloride). Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. 30/04/2015 EN (English) 3/7

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold : Liquid : Clear. : Blue. : Lemon. ph : 7-8,5 Relative evaporation rate (butylacetate=1) refraction index : Melting point Freezing point : -70 C Boiling point : > 75 C Flash point : 24 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density C Solubility Log Pow Log Kow Viscosity, C Viscosity, C Viscosity : Viscosity Index : Explosive properties Oxidising properties Explosive limits : 860 kg/m³ : Soluble in water Other information Additional information : The physical and chemical data in this section are typical values for this product and are not intended as product specifications. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity 30/04/2015 EN (English) 4/7

5 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard ph: 7-8,5 ph: 7-8,5 SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Ethanol ( ) Persistence and degradability Bioaccumulative potential Ethanol ( ) The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the substance available. Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1993 : Remove to an authorized waste treatment plant UN proper shipping name Proper Shipping Name (ADR) Transport document description (ADR) : FLAMMABLE LIQUID, N.O.S. : UN 1993 FLAMMABLE LIQUID, N.O.S. (Ethanol), 3, III, (D/E) Transport hazard class(es) Class (ADR) : 3 30/04/2015 EN (English) 5/7

6 Danger labels (ADR) : Packing group Packing group (ADR) Environmental hazards Other information : III : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 30 Classification code (ADR) : F1 Orange plates : Special provisions (ADR) : 274, 601, 640E Transport category (ADR) : 3 Tunnel restriction code (ADR) : D/E Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 EAC code : 3Y Transport by sea EmS-No. (1) : F-E, S-D Air transport Instruction "cargo" (ICAO) : 366 Instruction "passenger" (ICAO) : 355 Instruction "passenger" - Limited quantities (ICAO) : Y Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Allergenic fragrances > 0,01%: D-LIMONENE 0,03% National regulations Water hazard class (WGK) : 1 - low hazard to waters Chemical safety assessment SECTION 16: Other information 30/04/2015 EN (English) 6/7

7 Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H319 Causes serious eye irritation R10 Flammable R11 Highly flammable F Highly flammable This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 30/04/2015 EN (English) 7/7