09/08/2014 EN (English) 1

Transcription

1 Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product Identifier Product Form Product Name Product Code Type of Product : Mixture : Leak Sealer XP-LS : XP-LS : Liquid dispersed in liquid (emulsion) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional Use Spec : Industrial For professional use only Use of the substance/mixture : Central heating system cleaner Uses advised against No additional information available 1.3 Details of the supplier of the safety data sheet Expert Range Old Bank, The Triangle, Poulton, BS32 7LE Bristol United Kingdom T: F: support@expertrange.co.uk Emergency telephone number Emergency number : Section 2: Hazards Identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not Classified. Classification according to Directive 67/548/EEC or 1999/45/EC Not Classified. Adverse physicochemical, human health and environmental effects 2.2 Label Elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Precautionary statements (CLP) : P102 - Keep out of reach of children. P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste. 09/08/2014 EN (English) 1

2 2.3 Other Hazards No additional information available Section 3: Composition/Information on Ingredients 3.1 Substances Not applicable 3.2 Mixture Name Product identifier % Classification according to Directive 67/548/EEC Classification According to Regulation (EC) No. 1272/2008 [CLP] Polydimethyl-siloxane < 10 Not classified Not classified dazomet (ISO), tetrahydro-3,5- dimethyl-1,3,5-thiadiazine-2- thione (CAS No) (EC no) (EC index no) X < 1 Xn; R22 Xi; R36 N; R50/53 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of R- and H-phrases: see section 16 Section 4: First Aid Measures 4.1 Description of first aid measures First aid measures general First aid measures after inhalation First aid measures after skin contact First aid measures after eye contact First aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice. (Show the label where possible.) : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. If even minor quantity swallowed, give lukewarm water (1/2 litre). 4.2 Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not expected to present a significant hazard under anticipated conditions of normal use. : Slight irritation. Avoid prolonged or repeated contact with skin. : May cause slight irritation. 4.3 Indication of any immediate medical attention and special treatment needed Section 5: Firefighting Measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : Do not use a heavy water stream. 09/08/2014 EN (English) 2

3 5.2 Special hazards arising from the substance or mixture Hazardous decomposition products (In case of fire) : Nitrogen oxides (NOx) and sulphur oxides. Carbon monoxide. Carbon dioxide. 5.3 Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Section 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2 Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3 Methods and material for containment and cleaning up For containment : Stop leak without risks if possible. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4 Reference to other sections See Heading 8. Exposure controls and personal protection. Section 7: Handling and Storage 7.1 Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Provide good ventilation in process area to prevent formation of vapour. Avoid contact with skin and eyes. Wear personal protective equipment Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from Direct sunlight. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Heat sources. Storage temperature : 5 C 09/08/2014 EN (English) 3

4 Storage area : Protect from freezing Specific end use(s) SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Gloves. Protective goggles. Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold : Liquid. : Water-white liquid below 26 C. : White. : Slight. ph : 7 8. Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature 09/08/2014 EN (English) 4

5 Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C : Non-flammable. Relative density : 1. Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : In water, the material disperses Other information SECTION 10: Stability and Reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity 09/08/2014 EN (English) 5

6 Skin corrosion/irritation ph: 7 8 Serious eye damage/irritation ph: 7 8 Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity: (Single exposure) Specific target organ toxicity (Repeated exposure) : Not classified Aspiration hazard Potential Adverse human health effects and symptoms : SECTION 12: Ecological Information Toxicity Persistence and degradability System Leak Sealer XP-LS Persistence and degradability Contains non readily biodegradable component(s) Bioaccumulative potential System Leak Sealer XP-LS Bioaccumulative potential Not established Mobility in soil Results of PBT and vpvb assessment System Leak Sealer XP-LS PBT: not relevant no registration required 09/08/2014 EN (English) 6

7 12.6. Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal Considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials : In a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 14: Transport Information In accordance with ADR / RID / IMDG / IATA UN number No dangerous goods in sense of transport regulations UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) Transport hazard class(es) (ADR) Transport hazard class(es) (IMDG) Transport hazard class(es) (IATA) Transport hazard class(es) (ADN) Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) 09/08/2014 EN (English) 7

8 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user Overland transport No data available Transport by sea No data available Air transport No data available Inland waterway transport Not subjected to AND : No Rail transport Carriage prohibited (RID) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions. System Leak Sealer is not on the REACH Candidate List. Contains no REACH candidate substance. Contains no REACH Annex XIV substances National regulations Germany Water hazard class (WGK) : 3 - Strongly hazardous to water Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other Information 09/08/2014 EN (English) 8

9 Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of R-, H- and EUH-phrases Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H302 Harmful if swallowed H319 Causes serious eye irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects R22 Harmful if swallowed R36 Irritating to eyes R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xi Irritant Xn Harmful SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 09/08/2014 EN (English) 9