Safety data sheet. SAFEWING MP I ECO Plus (80) Pre-diluted, Type I ENG. Revision: Replaces: Version: 01.

Transcription

1 Safety data sheet Revision: Replaces: Version: 0100/GBR SECTION 1: Identification of the substance/mixture and of the company/undertaking 11 Product identifier Trade name: SAFEWING MP I ECO Plus (80) Pre-diluted, Type I ENG 12 Relevant identified uses of the substance or mixture and uses advised against Recommended uses: Aircraft de-icing 13 Details of the supplier of the safety data sheet Supplier: Aerochem AB Stubbsundsvägen 17 S Nacka Sweden Tel: Fax: info@aerochemse 14 Emergency telephone number (UK only) Only available to health professionals SECTION 2: Hazards identification 21 Classification of the substance or mixture DPD-classification: - Most serious harmful effects: The product shall not be classified as hazardous according to the national classification and labelling rules May cause slight irritation to the skin and eyes 22 Label elements Hazard designation: R-phrases: - S-phrases: - Other labelling: The product shall not be classified as hazardous according to the national classification and labelling rules 23 Other hazards Assessment to determine PBT and vpvb has not been made 1 / 6

2 SECTION 3: Composition/information on ingredients 32 Mixtures Registration number CAS/ EC Number Substance: Aqueous solution of corrosion inhibitors and surface active agents in propylene glycol DPD-classification/ CLP-classification w/w% Note Please see section 16 for the full text of R-phrases and H-phrases SECTION 4: First aid measures 41 Description of first aid measures Inhalation: Seek fresh air Seek medical advice in case of persistent discomfort Ingestion: Skin: Eyes: Wash out mouth thoroughly and drink 1-2 glasses of water in small sips Seek medical advice in case of persistent discomfort Remove contaminated clothing Wash the skin thoroughly with water and continue washing for a long time Flush with water (preferably using eye wash equipment) until irritation subsides Seek medical advice if symptoms persist Other information: When obtaining medical advice, show the safety data sheet or label 42 Most important symptoms and effects, both acute and delayed May cause slight irritation to the skin and eyes 43 Indication of any immediate medical attention and special treatment needed No special immediate treatment required SECTION 5: Firefighting measures 51 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Extinguish with powder, foam, carbon dioxide or water mist Use water or water mist to cool non-ignited stock Do not use water stream, as it may spread the fire 52 Special hazards arising from the substance or mixture Can generate harmful flue gases containing carbon monoxide in the event of fire 53 Advice for firefighters If there is a risk of exposure to vapour and flue gases, a self-contained breathing apparatus must be worn Move containers from danger area if it can be done without risk Avoid inhalation of vapour and flue gases seek fresh air SECTION 6: Accidental release measures 61 Personal precautions, protective equipment and emergency procedures For non-emergency personnel: Wear safety goggles if there is a risk of eye splash Wear gloves For emergency responders: Normal protective clothing equivalent to EN 469 is recommended 62 Environmental precautions Prevent spillage from entering drains and/or surface water 63 Methods and material for containment and cleaning up Contain and absorb spill with sand or other absorbent material and transfer to suitable waste containers Wipe up minor spills with a cloth 64 Reference to other sections See section 8 for type of protective equipment See section 13 for instructions on disposal SECTION 7: Handling and storage 71 Precautions for safe handling Running water and eye wash equipment should be available Wash hands before breaks, before using restroom facilities, and at the end of work 72 Conditions for safe storage, including any incompatibilities The product should be stored safely, out of reach of children and away from food, animal 2 / 6

3 feeding stuffs, medicines, etc Store at temperatures below 90 C 73 Specific end use(s) SECTION 8: Exposure controls/personal protection 81 Control parameters Legal basis: EH40/2005 Workplace exposure limits incl supplement from October 2007 Contains no substances subject to reporting requirements 82 Exposure controls Appropriate engineering controls: Wear the personal protective equipment specified below See also section 71 Personal protective equipment, eye/face protection: Personal protective equipment, skin protection: Personal protective equipment, respiratory protection: Environmental exposure controls: Wear safety goggles if there is a risk of eye splash Eye protection must conform to EN 166 In case of direct skin contact, wear protective gloves of eg nitrile rubber, butyl rubber Gloves must conform to EN 374 Not required Ensure compliance with local regulations for emissions SECTION 9: Physical and chemical properties 91 Information on basic physical and chemical properties State: Liquid Colour: Orange Odour: Odourless Odour threshold: ph (solution for use): ph (concentrate): 8-9,5 (20 C ) (DIN 19268) Melting point/freezing point: Initial boiling point and boiling 125 C (DIN 51371) range: Flash point: >100 C (DIN 51376, open cup) Evaporation rate: Flammability (solid, gas): Flammability: >400 C (DIN 51794) Upper/lower flammability limits: Upper/lower explosive limits: Vapour pressure: < 0,0133 kpa Vapour density: Relative density: 1,04 (20 C ) (DIN 51757) Solubility: Solubility in water: Completely miscible Partition coefficient n-octanol/water: Auto-ignition temperature: Not spontaneously flammable Decomposition temperature: Viscosity: mm2/s (20 C ) (DIN 51562) Explosive properties: Oxidising properties: 92 Other information SECTION 10: Stability and reactivity 101 Reactivity Not reactive 102 Chemical stability The product is stable when used in accordance with the supplier s directions 103 Possibility of hazardous reactions None known 104 Conditions to avoid Avoid temperatures >90 C 105 Incompatible materials None known 3 / 6

4 106 Hazardous decomposition products None known SECTION 11: Toxicological information 111 Information on toxicological effects Acute toxicity - oral: Ingestion may cause discomfort The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rat: LD50 >5000 mg/kg (OECD 401) Acute toxicity - dermal: Acute toxicity - inhalation: Skin corrosion/irritation: Serious eye damage/eye irritation: Sensitisation: Mutagenicity: Carcinogenic properties: Reproductive toxicity: Toxicity in case of single exposure: Toxicity in case of repeated or prolonged exposure: Aspiration hazard: Other toxicological effects: The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available May cause slight irritation The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rabbit: Non-irritating (OECD 404) Temporary irritation The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rabbit: Non-irritating (OECD 405) The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available The product does not have to be classified Test data are not available None known SECTION 12: Ecological information 121 Toxicity The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Acute toxicity: Fish: Brachydanio rerio: 96hLC50 = 7071 mg/l (OECD 203) Crustacea: Daphnia magna: 48hEC50 >10 g/l (OECD 202) Algae: Scenedesmus subspicatus: 72hEC50 >10 g/l (OECD 201) 122 Persistence and degradability Biologically degradable, when diluted may be degraded in biological purification plants 123 Bioaccumulative potential 124 Mobility in soil Readily biodegradable (OECD 301 E) Test data are not available Test data are not available 125 Results of PBT and vpvb assessment No assessment has been made 126 Other adverse effects None known SECTION 13: Disposal considerations 131 Waste treatment methods Avoid discharge to drain or surface water Contact the local authorities EWC code: Depends on line of business and use, for instance Antifreeze fluids other than those mentioned in Absorbent/cloth contaminated with the product: EWC code: Absorbents, filter materials, wiping cloths and protective clothing other than those mentioned in / 6

5 SECTION 14: Transport information ADR/RID 141 UN number UN proper shipping name Transport hazard class(es) Packing group - Tunnel restriction code: Environmental hazards - ADN 141 UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards - Environmental hazard in tank vessels: - IMDG 141 UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards - IMDG Code segregation group: - ICAO/IATA 141 UN number UN proper shipping name Transport hazard class(es) Packing group Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code - SECTION 15: Regulatory information 151 Safety, health and environmental regulations/legislation specific for the substance or mixture Special provisions: 152 Chemical safety assessment Chemical safety assessment has not been performed SECTION 16: Other information Changes have been made in the following sections: / 6

6 Abbreviation explanations: R-phrases: H-phrases: Training: PBT: Persistent, Bioaccumulative and Toxic vpvb: Very Persistent and Very Bioaccumulative No R-phrases No H-phrases No special training is required, but a thorough knowledge of this safety data sheet should be a prerequisite condition JST/ Bureau Veritas HSE Denmark A/S Birkemosevej 7, DK-6000 Kolding T: , F: , infohse@dkbureauveritascom, Web: wwwhsebureauveritasdk (Made in Toxido ) UK 6 / 6