SAFETY DATA SHEET. Common name and synonym. 2-pyrrolidone <10. Carbon black This ink supply contains an aqueous ink formulation.

Transcription

1 SAFETY DATA SHEET 1. Identification of the substance or mixture and of the supplier 1.1 GHS product identifier 1.2 Other means of identification C1Q49Series 1.3 Recommendations and restrictions on the use of substances or mixtures Inkjet printing Recommended use Recommended restrictions 1.4 Supplier s details HP Inc (Thailand) Ltd. Telephone Main Fax U Chu Liang Building, 3rd Floor, Rama IV Rd., Silom, Bangrak, BKK Bangkok, Bangkok, Thailand HP Inc. health effects line (Toll-free within the US) (Direct) HP Inc. Customer Care Line (Toll-free within the US) (Direct) Hazards identification hpcustomer.inquiries@hp.com 2.1 GHS classification of substance or mixture, and national or regional information Not classified. Physical hazards Health hazards Environmental hazards 2.2 GHS label elements Hazard symbol(s) Signal word Hazard statement(s) Precautionary statement(s) 2.3 Other hazards which do not result in GHS classification Supplemental information Not classified. Not classified. None. None. Potential routes of exposure to this product are skin and eye contact, ingestion, and inhalation. Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. Complete toxicity data are not available for this specific formulation. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA. None. 3. Composition/information on ingredients 3.2 Mixture Chemical identity Common name and synonym CAS number and other unique identifiers Concentration or concentration range Water pyrrolidone <10 Carbon black <5 Composition comments This ink supply contains an aqueous ink formulation. Carbon black is present only in a bound form in this preparation. 1 / 6

2 4. First-aid measures 4.1 Description of first-aid measures Remove to fresh air. If symptoms persist, get medical attention. Inhalation Skin contact Eye contact Ingestion 4.2 Most important symptoms/effects, acute and delayed 4.3 Indication of immediate medical considerations and important specific treatment that should be performed 5. Fire-fighting measures Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention. 5.1 Prohibited extinguishing media and suitable extinguishing media Suitable extinguishing For small (incipient) fires, use media such as foam, sand, dry chemical, or carbon dioxide. media For large fires use very large (flooding) quantities of water and/or foam, applied as a mist or spray. Unsuitable extinguishing media 5.2 Specific hazards arising from chemicals 5.3 Special protective equipment and precautions for fire-fighters Specific methods 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions 6.3 Methods and materials for containment and cleaning up Other issues relating to spills and releases 7. Handling and storage 7.1 Precautions for safe handling, use and storage 7.2 Conditions for safe storage, including any incompatibilities None known. Not applicable. None established. 8. Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits US. ACGIH Threshold Limit Values Components Carbon black (CAS ) Biological limit values Exposure guidelines 8.2 Appropriate engineering controls 8.3 Personal protective measures Eye/face protection Skin protection Hand protection Wear appropriate personal protective equipment. Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Soak up with inert absorbent material. Slowly vacuum or sweep the material into a bag or other sealed container. Dispose of in compliance with federal, state, and local regulations. See also section 13 Disposal considerations. Avoid contact with skin, eyes and clothing. Keep out of the reach of children. Keep away from excessive heat or cold. Type Value Form TWA 3 mg/m3 Inhalable fraction. No biological exposure limits noted for the ingredient(s). Exposure limits have not been established for this product. Use in a well ventilated area. 2 / 6

3 Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Physical state Form Color 9.2 Odor Handle in accordance with good industrial hygiene and safety practice. Liquid. Black. 9.3 Odor threshold limit 9.4 ph Melting point/freezing point 9.6 Initial boiling point and boiling range 9.7 Flash point > F (> C) 9.8 Evaporation rate 9.9 Flammability (solid, gas) 9.10 Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) 9.11 Vapor pressure 9.12 Vapor density 9.14 Solubility(ies) Solubility (water) 9.15 Partition coefficient: n-octanol/water 9.16 Auto-ignition temperature 9.17 Decomposition temperature 9.18 Viscosity Other information Oxidizing properties VOC 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products 11. Toxicological information Not determined 209 g/l Stable under recommended storage conditions. Will not occur. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons Information on likely routes of exposure Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Skin contact Eye contact Ingestion Contact with skin may result in mild irritation. Contact with eyes may result in mild irritation. Health injuries are not known or expected under normal use. 3 / 6

4 11.2 Symptoms related to physical, chemical and toxicological characteristics 11.3 Delayed and immediate effects, including chronic effects from short- and long-term exposure 11.4 Numerical values of toxicity Acute toxicity Components 2-pyrrolidone (CAS ) Acute Species Test Results Oral LD50 Rat > 5000 mg/kg Carbon black (CAS ) Acute Oral LD50 Rat > mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity ACGIH Carcinogens Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. Carbon black (CAS ) A3 Confirmed animal carcinogen with unknown relevance to humans. IARC. Monographs on the evaluation of carcinogenic risks to humans Carbon black (CAS ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information 12. Ecological information 12.1 Ecological toxicity Components 2-pyrrolidone (CAS ) Aquatic Crustacea Aquatic toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 2B Possibly carcinogenic to humans. Complete toxicity data are not available for this specific formulation This product has not been tested for ecological effects. EC50 Species Water flea (Daphnia pulex) This product has not been tested for ecological effects. Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone Mobility in soil Test Results mg/l, 48 hours 4 / 6

5 12.5 Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Waste from residues / unused products Contaminated packaging 14. Transport information DOT IATA IMDG ADR Further information 15. Regulatory information Federal regulations Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. Thailand. Explosive Substances & Precursors (Ministry of Defense Notification Re: Arms Subject to Imports License) Thailand. Notification of the Ministry of Interior, Re: Work Safety Relating to Dangerous Chemicals Thailand. Notification of the Ministry of Interior, Re: Work Safety Relating to More Dangerous Chemicals Thailand. Reportable Hazardous Substances (Notification of Ministry of Industry Re: Bases respecting report of quantity of hazardous materials under Department of Industrial Works, B.E. 2547) Other information International regulations Ordinance of the Minister of Labour and Social Policy of 06 June 2014 concerning maximum permissible concentrations and intensities of agents harmful to health in a work environment (Journal of Laws 2014 item 817). All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. 16. Other information, including date of preparation or last revision Issue date Version # Disclaimer 17-May This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-hp Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs. 5 / 6

6 Revision information Explanation of abbreviations 1. Product and Company Identification: Alternate Trade Names 3. Composition / Information on Ingredients: Disclosure Overrides Regulatory information: International regulations Other information, including date of preparation or last revision: Disclaimer ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds 6 / 6