Identified Uses of Petroleum Substances

Transcription

1 Identified Uses of Petroleum Substances Version 1.0, 26 October Important notes 1.1. CONCAWE definitions for purposes of this communication: Use means a use as defined in Art. 3(24) of the REACH Regulation Identified Use means a use as defined in Art. 3(26) of the REACH Regulation Supported Use means a use for which the risk assessment demonstrates that any risk to human health or the environment is controlled with the implementation of appropriate risk management measures. Petroleum Substances are the substances listed on the CONCAWE Internet website: Categories of Petroleum Substances are listed below. Grouping the substances into categories allows read across of intrinsic (hazard) properties between the substances within a category. Notes allow for differentiation of hazard properties within a category. 1. low boiling point naphthas / gasolines 2. kerosines 3. straight run gas oils 4. vacuum gas oils, hydrocracked gas oils and distillate fuels 5. cracked gas oils 6. other gas oils 7. heavy fuel oil components 8. white mineral oils 9. unrefined / acid treated oils 10. other lubricant base oils 11. foots oils 12. paraffinic and hydrocarbon waxes 13. slack waxes 14. petrolatums 15. untreated distillate aromatic extracts 16. treated distillate aromatic extracts 17. residual aromatic extracts 18. bitumen 19. petroleum coke In addition identified uses for sulphur and MK-1 have also been listed. Because of the extensive overlap of gases from refinery operation and gases from steamcrackers and/or aromatics production units CONCAWE has agreed to collaborate with by the Lower Olefins/Aromatics consortium (LOA). The common parts of the registration dossiers for categories of petroleum gases will be prepared by LOA. CONCAWE REACH Use Mapping Note Version /10/2009 Page 1 of 6

2 1.2. Identified Uses Under REACH, Downstream Users have the right to make their Use(s) (the Identified Uses) known to their direct suppliers. For substances requiring REACH registration in 2010 there is no obligation for registrants to consider Use communication received from Downstream Users after 30 November Therefore this date becomes in effect the cut-off date for Downstream Users to make their Uses known to their suppliers. Uses made known prior to 30 November 2009 will be reviewed to assess the risks associated with those Uses. If the outcome of this review results in a determination that an Identified Use is associated with an unacceptable risk, it will be flagged as a Use Advised Against as part of the Registration Dossiers prepared by CONCAWE. Any of the Supported Uses may be included by registrants in their relevant substance Registration Dossier. CONCAWE has prepared an initial map of Identified Uses based on input provided from its member companies. The mapping has been done by grouping applications into generic exposure scenario (GES) titles and noting associated Uses according to the Use Descriptor System supported by ECHA. These Use are designed to describe how products are used in the supply chain. More information on Use can be found on the ECHA website 1. The list below shows the Identified Uses for Categories of Petroleum Substances, MK-1 and sulphur. Registrants are obliged to include a brief general description of all Identified Uses in their Technical Dossier and in the Chemical Safety Reports (CSR). Additionally, for substances which require an exposure assessment, CONCAWE is developing, assessing and will communicate exposure scenarios Notes on the list 1. The assignment of Use to Identified Uses may change. 2. The number and the definition of GESs are not final and may be subject to changes during their development. 3. The list of Identified Uses may not be final. The list below will be updated if and when additional Uses have been identified to us. 4. Identified Uses must in no circumstances be confused with Supported Uses. An Identified Use will only be supported if there is no risk or if any identified risk to human health and the environment is controlled with the implementation of appropriate risk management measures Missing Uses If you suspect that a Use which has been identified and be made known to you is missing in the list please take into account that the description of the Uses in the list are in layman s terms. A different description of a Use does not make it necessarily a different Identified Use. 1 Please note that the Use Descriptor System guidance is currently being revised. The version under consultation is available to the public on the ECHA website ( =20_08_0). CONCAWE REACH Use Mapping Note Version /10/2009 Page 2 of 6

3 1.5. Recommended action a) Before you start collecting information please familiarise yourself on the ECHA website with the Use Descriptor System the Use information described below 2 3. b) You are a registrant: Inform CONCAWE of the Use which you believe is missing in the list by sending an e- mail to use@super-sief.eu and add the Use information described below. CONCAWE will not consider Uses without accompanied Use information. c) You are a Downstream User: Directly inform your supplier of the Use which you believe is missing in the list and provide the Use information described below. Please note that CONCAWE will not consider notified Uses without accompanied Use information Collection of Use information Before you start collecting information please familiarise yourself on the ECHA website with the Use Descriptor System 4, which consists of the following 5 elements: sector of use (SU), chemical product category (PC), process category (PROC), environmental release category and article category (AC). If you are a registrant we recommend that only thereafter you contact the immediate Downstream User who has made the Use known to you to obtain in accordance with REACH Art. 37(2) the information specified below. Only those Identified Uses for which it can be indicated that they present no risk or if there is any identified risk to human health and the environment, the risk is controlled with the implementation of appropriate operating conditions and risk management measures. Such Supported Uses can be registered under REACH. We anticipated that we have identified all major Uses of Petroleum Substances, MK-1 and sulphur and that few, if any, additional Uses will be identified between now and 30 November Therefore, if via discussions with Downstream Users, registrants become aware of new Uses, to enable CONCAWE to address such Use(s) and in particular to check whether that Use(s) fits into an existing exposure scenario, at least the information listed below is to be provided. According to Article 37 of REACH, the Downstream Users have the obligation to provide sufficient information to allow the manufacturer to prepare the exposure scenario. Without this information the Use cannot and will not be addressed in the risk assessment and the exposure scenarios submitted in SUBSTANCE IDENTITY identity of substance (CAS Registry Number or EC number) 2. ENVIRONMENT process description emissions to air, water, soil annual average consumption per site per substance in tonnes/year 2 See footnote 1. 3 See also the following ECHA News Alert: communication_final_ pdf 4 See footnote 1. CONCAWE REACH Use Mapping Note Version /10/2009 Page 3 of 6

4 annual maximum consumption per site per substance in tonnes/year sector of use industrial guidance on risk management measures use of waste water treatment plants, skimmers, etc. description of waste disposal emission factors per life cycle stage (if available) 3. HUMAN HEALTH physical form currently implemented risk management measures nature of process (open/closed) if not obvious from the PROC, i.e. operating temperature (and data or information to determine volatility at operating temperature), duration of activity, frequency of activity, presence of exhaust ventilation, use of respiratory protection, use of gloves etc. used indoor vs. used outdoor, if substance is classified, provide available exposure information if substance is used in a preparation (mixture), provide percentage of substance present in the preparation (mixture) use at the industrial, professional and/or consumer stage o o o in industrial use, workers might be expected to have a high standard of competence, qualifications and skills and there is a high standard of supervision and control as well as a high standard of technical (risk management) measures available. Resulting exposures and emissions can be expected to be predictable and well-managed. in professional use, workers have various/different competences, qualifications and skills and there are lower or varying standard of supervision and control as well as lower standard of technical (risk management) measures. Resulting exposures and emissions will often be higher than those encountered in Industrial settings. in consumer use, there is little expertise and/or fewer skills for implementing measures and no technical measures and no individual protection (except for gloves or protective glasses in certain cases). The control of exposures and emissions cannot therefore be expected to rely on strategies which demand trained users or access to specific equipment. CONCAWE will not consider any uses made known to us as Identified Uses that are illegal under current law. Uses historically advised against remain advised against Petroleum substances and specific cuts thereof CONCAWE and the Hydrocarbon Solvents Consortium (HCSC) had informed participants of SIEFs for the following Categories of Petroleum Substances low boiling point naphthas / gasolines kerosines straight run gas oils vacuum gas oils, hydrocracked gas oils and distillate fuels CONCAWE REACH Use Mapping Note Version /10/2009 Page 4 of 6

5 cracked gas oils other gas oils that refinery streams and specific cuts of refinery streams are not the same substances in spite of currently being in the market with the same CAS or EC number. The issue can be illustrated as follows: In the past, fractions 1 to 4 of a refinery stream have shared the same descriptor (EC number, substance name, substance descriptions) although in reality the fractions are specific cuts. These specific cuts are mainly used in solvent applications. However, it is not the application as a solvent why fractions 1 to 4 are not the same as the feedstock stream that is manufactured in a typical refinery process; it is rather the fact that the feedstock has undergone a transformation. Also the feedstock could and in practice sometimes is be applied as a solvent. The Hydrocarbon Solvents Producers Association (HSPA) has therefore developed a naming convention for some fractions of certain refinery streams. Please see for a comprehensive paper on the naming convention. The Hydrocarbon Solvents Consortium (HCSC) has decided to register under REACH the 77 substances that were originally listed in the naming convention document. The European Chemical Agency (ECHA) has meanwhile assigned new EC numbers to the 77 substances that had been pre-registered under their name in accordance with naming convention. The refinery streams used as feedstocks are not the same substances as the 77 HCSC substances. Pre-registrants of those 77 substances under the EC number of their feedstocks should be aware that the registration dossiers currently being prepared by CONCAWE for the feedstocks of these 77 substances will only in very exceptional cases address the application of these feedstocks as a solvent. Therefore, if you cannot find on the list below the Use where your substance is applied as a solvent it is likely, in most cases even certain, that your substance is not a refinery stream but a specific cut. In this case you should inform us (info@super-sief.eu ) so that we can remove you from the SIEF and contact HCSC (ian.carruthers@reachcentrum.eu) for joining the appropriate SIEF. CONCAWE REACH Use Mapping Note Version /10/2009 Page 5 of 6

6 2. List of Identified Uses and Mapping against Generic Exposure Scenario Titles and the Use Descriptor System 2.1. Acronyms used in the list of Identified Uses CMR ERC GES IBC PC PROC SU UD Substance is classified as a carcinogen, a mutagen or toxic to reproduction Environmental release category generic exposure scenario intermediate bulk container chemical product category process category sectors of use use descriptor 2.2. List of Identified Uses CONCAWE REACH Use Mapping Note Version /10/2009 Page 6 of 6

7 Low Boiling Point Naphthas / Gasolines Gas Oils (Straightrun) Gas Oils (Cracked) Gas Oils (vacuum, hydrocracked & distillate fuels) Gas Oils (other) kerosines MK-1 White Mineral Oils Other Lubricant Base Oils Unrefined / Acid treated oils Foots Oils Paraffinic & Hydrocarbon Waxes Petrolatums Slack Waxes Distillate Aromatic Extracts Treated Distillate Aromatic Extracts Residual Aromatic Extracts Heavy Fuel Oil Components Petroleum Coke Bitumen sulphur Manufacture of substance Industrial (SU8, SU9, SU3) Classification Note --> Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container). Full use (see "Classification Note per category") PROC3, PROC4, PROC8a,, Limited Use (see "Classification Note per category"), ERC 1 not CMR CMR original feedstock is not carcinogenic original feedstock is carcinogenic has a DMSO extract of < 3% m/m using the IP 346 has a DMSO extract of 3% m/m using the IP 346 has a DMSO extract of < 3% m/m using IP346 has a DMSO extract of 3% m/m using IP346 original base oil has DMSO extract < 3% m/m using IP346 original base oil has DMSO extract 3% m/m using IP346 original base oil has DMSO extract < 3% m/m using IP346 original base oil has DMSO extract 3% m/m using IP346 has a DMSO extract of < 3% m/m using the IP 346 has a DMSO extract of 3% m/m using the IP 346 Final Carcinogenicty Classification Currently Under Discussion Distribution of substance Formulation & (re)packing of substances and mixtures Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, and associated laboratory activities. Excludes emissions during transport. Industrial (SU10) Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tablettting, compression, pelletization, extrusion, large and small scale packing, maintenance, sampling and associated laboratory activities including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities. PROC3, PROC4, PROC8a, PROC3, PROC4, PROC5, PROC9, PROC14, PROC3, PROC4, PROC10,,,,, ERC1, ERC2 ERC2 Uses in Coatings including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities. PROC3, PROC4, PROC5,,, PROC19, Use in Cleaning Agents including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning. PC1, PC4, PC5, PC9, PC10, PC18, PC23, PC24, PC31 including PROC3, transfer from storage, pouring/unloading from drums or PROC4, PROC7, containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, PROC10, dipping, wiping, automated and by hand), related equipment cleaning and including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand). Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, lubricants and air care products. PROC3, PROC4, PROC8a, PROC11, PC3, PC4, PC9, PC24, PC35 ERC4 ; ; Use in Oil field drilling and production operations Use in Metal working fluids / rolling oils Use as a propellant Use as a blowing agent Oil field well drilling and production operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils. Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils. PROC3, PROC4,, PROC9, PROC10 PROC9, PROC10 PROC3,, PROC3, PROC11,, ERC 8F Use as a propellant in industrial aerosol products, including tbd tbd tbd product disposal Use as a propellant in professional aerosol products, including tbd tbd tbd product disposal Use as a propellant in household consumer aerosol products tbd tbd tbd Use as a blowing agent for rigid and flexible foams, including PROC3, material transfers, mixing and injection, curing, cutting, storage and packing PROC12 Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of PROC3, PROC4, PROC6, PROC7, PROC14 ERC 5 Use as release agents or binders Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of PROC3, PROC4, PROC6, PROC 8a, PROC11, PROC14 ERC 8C Use in agrochemicals Use in road and construction applications Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal. Covers the consumer use in agrochemicals in liquid and solid forms. Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and water-proofing membranes PROC1, PROC4, PROC11, PC12, PC22, PC27 PROC11, PROC1, ERC8A, ERC8F CONCAWE REACH Use Mapping - Overview Version /10/ Page 1 of 44

8 Low Boiling Point Naphthas / Gasolines Gas Oils (Straightrun) Gas Oils (Cracked) Gas Oils (vacuum, hydrocracked & distillate fuels) Gas Oils (other) kerosines MK-1 White Mineral Oils Other Lubricant Base Oils Unrefined / Acid treated oils Foots Oils Paraffinic & Hydrocarbon Waxes Petrolatums Slack Waxes Distillate Aromatic Extracts Treated Distillate Aromatic Extracts Residual Aromatic Extracts Heavy Fuel Oil Components Petroleum Coke Bitumen sulphur Rubber production and Use in polymer production Use in polymer Industrial (SU3, SU10, SU11) Classification Note --> Manufacture of tyres and general rubber articles, including of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as Industrial (SU10) Manufacture of polymers from monomers in continuous and batch processes, include sparging, discharging, and reactor maintenance and immediate polymer product formation (i.e. compounding, pelletisation, product off-gassing). Full use (see "Classification Note per category") PROC3, PROC4, PROC14,, PROC21 PROC3, PROC4, Industrial (SU10) Processing of formulated polymers including material PROC3, transfers, additives handling (e.g. pigments, stabilisers, fillers, PROC4, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated PROC9,, Processing of formulated polymers including material transfers, moulding and forming activities, material re-works and associated Covers the use as a fuel (or fuel additives and additive PROC3, PROC4, PROC8a,, Limited Use (see "Classification Note per category"),, ERC 3 not CMR CMR original feedstock is not carcinogenic original feedstock is carcinogenic has a DMSO extract of < 3% m/m using the IP 346 has a DMSO extract of 3% m/m using the IP 346 has a DMSO extract of < 3% m/m using IP346 has a DMSO extract of 3% m/m using IP346 ERC 8C, ERC 8F ERC8B original base oil has DMSO extract < 3% m/m using IP346 original base oil has DMSO extract 3% m/m using IP346 original base oil has DMSO extract < 3% m/m using IP346 original base oil has DMSO extract 3% m/m using IP346 has a DMSO extract of < 3% m/m using the IP 346 has a DMSO extract of 3% m/m using the IP 346 Final Carcinogenicty Classification Currently Under Discussion Use as a fuel Covers the use as a fuel (or fuel additives and additive PROC3, PROC4, PROC8a,,, Lubricants De-icing and anti-icing applications Use in laboratories Use in mining operations Covers consumer uses in fuels PC13 PC13 open PROC3, ERC 7, systems including transfer operations, operation of PROC4, PROC7, machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes., open systems including transfer operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil. Covers the consumer use of formulated lubricants in closed and open systems including transfer operations, application, operation of engines and similar articles, equipment maintenance and disposal of waste oil. Ice prevention and de-icing of vehicles, aircraft and other equipment by spraying PROC3, PROC4, PROC8a,,, PROC20 PC1, PC6, PC24, PC31 PROC2,, PROC2, PROC11 De-icing of vehicles and similar equipment by spraying PC4 Use of the substance within laboratory settings, including PROC10, material transfers and equipment cleaning Use of small quantities within laboratory settings, including PROC10, ERC 8A material transfers and equipment cleaning Industrial (SU10) Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal. Industrial (SU10) water at industrial facilities in open and closed systems PROC3, PROC4, PROC5, PROC10,, PROC23 PROC3, PROC4, PROC8a,, Use in water treatment chemicals water in open and closed systems PROC3, PROC4, PROC8a,, Explosives manufacture & use water in open and closed systems Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning PC36, PC37 PROC1, PROC8a, Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in industrial equipment including maintenance and related material transfers PROC3, PROC4, PROC 8a, PROC 8b, PROC9 PROC3, PROC 8b ERC 7 Use as a functional fluids Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in professional equipment including maintenance and related material transfers. PROC3, PROC 8a, PROC9, PROC20 PROC3 Other Uses Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants uses not covered in consumer examples listed above e.g. use as a carrier in cosmetics/personal care products, perfumes and fragrances. PC16, PC17 PC28, PC39 CONCAWE REACH Use Mapping - Overview Version /10/ Page 2 of 44

9 PC) (PROC or Uses / Applications of Low Boiling Point Naphthas / Gasolines Manufacture of substance Distribution of substance Industrial (SU8, SU9, SU3) Classification Note --> Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container). Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, and associated laboratory activities. Excludes emissions during transport. not CMR PROC9, CMR,, ERC 1 ERC1, ERC2 not CMR CMR Formulation & (re)packing of substances and mixtures Uses in Coatings Industrial (SU10) Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tablettting, compression, pelletization, extrusion, large and small scale packing, maintenance, sampling and associated laboratory activities including exposures during use (including materials semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities. including exposures during use (including materials semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities. including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning. PROC14, PROC10,, PROC11,,, PROC19 PC1, PC4, PC5, PC9, PC10, PC18, PC23, PC24, PC31,,, ERC2 Cutback for bitumen in rapid curing paints (Cutback for bitumen) Cutback for bitumen in rapid curing paints (Cutback for bitumen) Cutback for bitumen in rapid curing paints (Cutback for bitumen) Use in Cleaning Agents including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand). ERC4 ; - Solvent (diluent) - Solvent (diluent) Use in Oil field drilling and production operations Use in Metal working fluids / rolling oils Covers general exposures to consumers arising from PC3, PC4, PC9, PC24, the use of household products sold as washing and PC35 cleaning products, aerosols, coatings, lubricants and air care products. Oil field well drilling and production operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils. Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils. PROC10 PROC9, PROC10 PROC10,,, ; ERC 8F - Solvent (diluent) Use as a propellant Use as a blowing agent Use as release agents or binders Use in agrochemicals Use as a propellant in industrial aerosol products, including product disposal Use as a propellant in professional aerosol products, including product disposal Use as a propellant in household consumer aerosol products Use as a blowing agent for rigid and flexible foams, including material transfers, mixing and injection, curing, cutting, storage and packing Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal. Covers the consumer use in agrochemicals in liquid and solid forms., PROC9, PROC12 PROC6, PROC7, PROC14 PROC6, PROC 8a, PROC11, PROC14 PROC1, PROC4, PROC11, PC12, PC22, PC27 PROC1, ERC 5 ERC 8C ERC8A, CONCAWE REACH Use Mapping - Low Boiling Point Naphthas / Gasolines Version /10/ Page 3 of 44

10 PC) (PROC or Uses / Applications of Low Boiling Point Naphthas / Gasolines Classification Note --> not CMR CMR not CMR CMR Use in road and construction applications Rubber production and Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and waterproofing membranes Industrial (SU3, Manufacture of tyres and general rubber articles, SU10, SU11) including of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as Industrial (SU10) Manufacture of polymers from monomers in continuous and batch processes, include sparging, discharging, and reactor maintenance and immediate polymer product formation (i.e. compounding, pelletisation, Use in polymer production product off-gassing). Industrial (SU10) Processing of formulated polymers including material transfers, additives handling (e.g. pigments, stabilisers, fillers, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated Use in polymer Processing of formulated polymers including material transfers, moulding and forming activities, material reworks and associated PROC11, PROC14,, PROC21 PROC9,,, ERC8F ERC 3 ERC 8C, ERC 8F - Solvent - Solvent Use as a fuel Lubricants Covers the use as a fuel (or fuel additives and additive Covers the use as a fuel (or fuel additives and additive,, ERC8B - Avgas - Diluent for fuel additives - Spark ignition engine fuel - Avgas - Spark ignition engine fuel Covers consumer uses in fuels PC13 PC13 - Avgas - Spark ignition engine fuel - Heating ERC 7, open systems including transfer operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes. open systems including transfer operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil. Covers the consumer use of formulated lubricants in closed and open systems including transfer operations, application, operation of engines and similar articles, PROC10,, PROC9,,, PROC20 PC1, PC6, PC24, PC31 - Avgas - Diluent for fuel additives - Spark ignition engine fuel - Avgas - Spark ignition engine fuel - Avgas - Spark ignition engine fuel - Heating De-icing and anti-icing applications Use in laboratories Use in mining operations Use in water treatment chemicals Explosives manufacture & use Ice prevention and de-icing of vehicles, aircraft and PROC2,, PROC2, other equipment by spraying PROC11 De-icing of vehicles and similar equipment by spraying PC4 Use of the substance within laboratory settings, PROC10, including material transfers and equipment cleaning Use of small quantities within laboratory settings, PROC10, ERC 8A including material transfers and equipment cleaning Industrial (SU10) Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal. PROC5,,, PROC23 Industrial (SU10) water at industrial facilities in open and closed systems Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in industrial transfers Use as functional fluids e.g. cable oils, transfer oils, Use as a functional fluids insulators, refrigerants, hydraulic fluids in professional transfers. Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants Other Uses uses not covered in consumer examples listed above e.g. use as a carrier in cosmetics/personal care products, perfumes and fragrances. PC36, PC37 PROC 8a, PROC 8b, PROC9 PROC3, PROC 8a, PROC9, PROC20 PC16, PC17 PC28, PC39 PROC3, PROC 8b PROC3 ERC 7 CONCAWE REACH Use Mapping - Low Boiling Point Naphthas / Gasolines Version /10/ Page 4 of 44

11 Uses / Applications of Gas Oils (Straight-run) Manufacture of substance Industrial (SU8, SU9, SU3) Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container). Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, and associated laboratory activities. Excludes emissions during transport. Distribution of substance Industrial (SU10) Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tablettting, compression, pelletization, extrusion, large Formulation & (re)packing and small scale packing, maintenance, sampling and of substances and associated laboratory activities mixtures Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities. Uses in Coatings Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities. Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning. PROC9, PROC14, PROC10,, PROC11,,, PROC19 PC1, PC4, PC5, PC9, PC10, PC18, PC23, PC24, PC31 ERC 1 ERC1, ERC2 ERC2 - Printing inks - Lubricant additive (Anti-rust coating) - Solvent for pigment paste - Printing inks - Lubricant additive (Anti-rust coating) - Solvent for pigment paste - Cosmetics (production of unguents, body lotions, thickenting agent, base material for ointments, skin creams, suntan lotions and emollients, clean lotions) Use in Cleaning Agents Use in Oil field drilling and production operations Use in Metal working fluids / rolling oils Use as a propellant Use as a blowing agent Use as release agents or binders Use in agrochemicals Use in road and construction applications Rubber production and including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand). Covers general exposures to consumers arising from PC3, PC4, PC9, PC24, the use of household products sold as washing and PC35 cleaning products, aerosols, coatings, lubricants and air care products. Oil field well drilling and production operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils. Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils. Use as a propellant in industrial aerosol products, including product disposal Use as a propellant in professional aerosol products, including product disposal Use as a propellant in household consumer aerosol products Use as a blowing agent for rigid and flexible foams, including material transfers, mixing and injection, curing, cutting, storage and packing Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal. Covers the consumer use in agrochemicals in liquid and solid forms. Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and waterproofing membranes Industrial (SU3, Manufacture of tyres and general rubber articles, SU10, SU11) including of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as PROC10 PROC9, PROC10 PROC10,,,, PROC9, PROC12 PROC6, PROC7, PROC14 PROC6, PROC 8a, PROC11, PROC14 PROC1, PROC4, PROC11, PC12, PC22, PC27 PROC11, PROC14,, PROC21 ERC4 ; ; ERC 8F ERC 5 ERC 8C ERC8A, ERC8F - Lubricant additive (Cleaning/degreasing) - Lubricant additive (Cleaning/degreasing) - Blending stock for Lubes (Blending stock for Lubes) - Lubricant additive (Aluminum rolling, Flute grinding oils, Metal cutting / metalworking, Metal rolling) - Lubricant additive (Aluminum rolling, Flute grinding oils, Metal cutting / metalworking, Metal rolling) - Mould binding agent (e.g. Foundry moulds) - Mould release agent (e.g. concrete) - Blending component for bitumen (Component of bitumen blending; Fluxant) - Lubricant additive (Road sealing oils) - Lubricant additive (Extender oils/process oils) CONCAWE REACH Use Mapping - Gas Oils (Straight-run) Version /10/ Page 5 of 44

12 Uses / Applications of Gas Oils (Straight-run) Use in polymer production Use in polymer Industrial (SU10) Manufacture of polymers from monomers in continuous and batch processes, include sparging, discharging, and reactor maintenance and immediate polymer product formation (i.e. compounding, pelletisation, product off-gassing). Industrial (SU10) Processing of formulated polymers including material transfers, additives handling (e.g. pigments, stabilisers, fillers, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated Processing of formulated polymers including material transfers, moulding and forming activities, material reworks and associated PROC9,, ERC 3 ERC 8C, ERC 8F Use as a fuel Lubricants De-icing and anti-icing applications Use in laboratories Use in mining operations Use in water treatment chemicals Explosives manufacture & use Use as a functional fluids Other Uses Covers the use as a fuel (or fuel additives and additive Covers the use as a fuel (or fuel additives and additive ERC8B - Heating (Heating, Drying e.g. coal) - Compression ignition engine fuel (Vehicles, machinery, ships, trains) - Diluent for fuel additives - Blending stock for HFO (Blending stock for HFO) - Blending stock for gas oils - Ship/barge fuel - Lubricant additive (2-stroke oil, Spark erosion fluid) - Heating - Compression ignition engine fuel (Vehicles, machinery, ships, trains) - Diluent for fuel additives - Lubricant additive (2-stroke oil, Spark erosion fluid) Covers consumer uses in fuels PC13 - Heating - Compression ignition engine fuel (Vehicles, machinery, ships, trains) open systems including transfer operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes. open systems including transfer operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil. Covers the consumer use of formulated lubricants in closed and open systems including transfer operations, application, operation of engines and similar articles, PROC10,, PROC9,,, PROC20 PC1, PC6, PC24, PC31 ERC 7, Ice prevention and de-icing of vehicles, aircraft and PROC2,, other equipment by spraying PROC11 De-icing of vehicles and similar equipment by spraying PC4 Use of the substance within laboratory settings, PROC10, including material transfers and equipment cleaning Use of small quantities within laboratory settings, PROC10, ERC 8A including material transfers and equipment cleaning Industrial (SU10) Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal. PROC5,,, PROC23 Industrial (SU10) water at industrial facilities in open and closed systems Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in industrial transfers Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in professional transfers. Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants uses not covered in consumer examples listed above e.g. use as a carrier in cosmetics/personal care products, perfumes and fragrances. PC36, PC37 PROC 8a, PROC 8b, PROC9 PROC3, PROC 8a, PROC9, PROC20 PC16, PC17 PC28, PC39 ERC 7 - Lubricant additive (Calibration fluid, Gear oils, High speed industrial macinery, Textile machine oil, Paper machinery oil) - Lubricant additive (Calibration fluid, Gear oils, High speed industrial macinery, Textile machine oil, Paper machinery oil) - Manufacture of explosives (e.g. slurry explosives) - Lubricant additive (Electrical insulating oil, Heat transfer fluids, Hydraulic fluid) - Lubricant additive (Electrical insulating oil, Heat transfer fluids, Hydraulic fluid) - cosmetics (end-use of unguents, body lotions, thickenting agent, base material for ointments, skin creams, suntan lotions and emollients, clean lotions) CONCAWE REACH Use Mapping - Gas Oils (Straight-run) Version /10/ Page 6 of 44

13 Uses / Applications of Gas Oils (Cracked) Manufacture of substance Distribution of substance Industrial (SU8, SU9, SU3) Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container). Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, and associated laboratory activities. Excludes emissions during transport.,, ERC 1 ERC1, ERC2 Formulation & (re)packing of substances and mixtures Uses in Coatings Industrial (SU10) Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tablettting, compression, pelletization, extrusion, large and small scale packing, maintenance, sampling and associated laboratory activities Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities. Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities. Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.,,, ERC2 Use in Cleaning Agents including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand). ERC4 ; Use in Oil field drilling and production operations Use in Metal working fluids / rolling oils Use as a propellant Use as a blowing agent Use as release agents or binders Use in agrochemicals Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, lubricants and air care products. Oil field well drilling and production operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils. Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils. Use as a propellant in industrial aerosol products, including product disposal Use as a propellant in professional aerosol products, including product disposal Use as a propellant in household consumer aerosol products Use as a blowing agent for rigid and flexible foams, including material transfers, mixing and injection, curing, cutting, storage and packing Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal. Covers the consumer use in agrochemicals in liquid and solid forms. PROC1, ; ERC 8F ERC 5 Mould binding agent (e.g. Foundry moulds) ERC 8C ERC8A, CONCAWE REACH Use Mapping - Gas Oils (Cracked) Version /10/ Page 7 of 44

14 Uses / Applications of Gas Oils (Cracked) Use in road and construction applications Rubber production and Use in polymer production Use in polymer Industrial (SU3, SU10, SU11) Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and waterproofing membranes Manufacture of tyres and general rubber articles, including of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as Industrial (SU10) Manufacture of polymers from monomers in continuous and batch processes, include sparging, discharging, and reactor maintenance and immediate polymer product formation (i.e. compounding, pelletisation, product off-gassing). Industrial (SU10) Processing of formulated polymers including material transfers, additives handling (e.g. pigments, stabilisers, fillers, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated Processing of formulated polymers including material transfers, moulding and forming activities, material reworks and associated, ERC8F ERC 3 ERC 8C, ERC 8F Use as a fuel Lubricants Covers the use as a fuel (or fuel additives and additive Covers the use as a fuel (or fuel additives and additive,, ERC8B - Heating (Heating, Drying e.g. coal) - Compression ignition engine fuel (Vehicles, machinery, ships, trains) - Diluent for fuel additives - Blending stock for HFO - Blending stock for gas oils - Lubricant additive (2-stroke oil, Spark erosion fluid) - Heating - Compression ignition engine fuel (Vehicles, machinery, ships, trains) - Ship/barge fuel - Lubricant additive (2-stroke oil, Spark erosion fluid) Covers consumer uses in fuels PC13 - Heating - Compression ignition engine fuel (Vehicles, machinery, ships, trains) open systems including transfer operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes. ERC 7, - Lubricant additive (Gear oils) open systems including transfer operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil. Covers the consumer use of formulated lubricants in closed and open systems including transfer operations, application, operation of engines and similar articles, Ice prevention and de-icing of vehicles, aircraft and De-icing and anti-icing other equipment by spraying applications De-icing of vehicles and similar equipment by spraying Use of the substance within laboratory settings, including material transfers and equipment cleaning Use of small quantities within laboratory settings, Use in laboratories including material transfers and equipment cleaning Industrial (SU10) Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal. Use in mining operations Industrial (SU10) water at industrial facilities in open and closed systems Use in water treatment chemicals Explosives manufacture & use Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in industrial transfers Use as functional fluids e.g. cable oils, transfer oils, Use as a functional fluids insulators, refrigerants, hydraulic fluids in professional transfers. Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants uses not covered in consumer examples Other Uses listed above e.g. use as a carrier in cosmetics/personal care products, perfumes and fragrances. PROC2, PROC3, PROC 8b PROC3 ERC 8A ERC 7 CONCAWE REACH Use Mapping - Gas Oils (Cracked) Version /10/ Page 8 of 44