SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking CHEMTREC

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1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms UNIFLOR 8961 Product Code UNIFLOR 8961 Issue date Version number 02 Revision date Supersedes date June February June Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against None known Details of the supplier of the safety data sheet Supplier Company name Address Division Nye Lubricants, Inc. 12 Howland Road Fairhaven, MA US Telephone Contact person 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture CHEMTREC The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended. Hazard summary Physical hazards Health hazards Environmental hazards Specific hazards Main symptoms 2.2. Label elements Not classified for physical hazards. Not classified for health hazards. Not classified for hazards to the environment. None known. Label according to Regulation (EC) No. 1272/2008 as amended Contains: Hazard pictograms Signal word Hazard statements Precautionary statements Prevention Response Storage POLYTETRAF LUORO ETHYL ENE The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

2 Disposal Dispose of waste and residues in accordance with local authority requirements. Supplemental label information Not applicable Other hazards None known. SECTION 3: Composition/information on ingredients 3,2. Mixtures Chemical name % CASNo. / EC No. REACH Registration No. Index No. Notes POLYTETRAFLUOROETHYL ENE 20 < 30 Classification: DSD: CLP: Other components below reportable levels 70 < 80 CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. M: Mfactor vpvb: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. #: This substance has been assigned Community workplace exposure limit(s). SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If symptoms develop, remove affected person from source of exposure into fresh air. Get immediate medical attention. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if symptoms occur. Wash clothing separately before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Get immediate medical attention. If ingestion of a large amount does occur, seek medical attention. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Direct contact with eyes may cause temporary irritation. Treat symptomatically. SECTION 6: Accidental release measures No unusual fire or explosion hazards noted. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Use methods for the surrounding fire. Product does not burn. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Selfcontained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do it without risk. Wear full protective clothing, including helmet, selfcontained positive pressure or pressure demand breathing apparatus, protective clothing and face mask Personal precautions, protective equipment and emergency procedures For nonemergency personnel Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the MSDS. Observe precautions from other sections. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

3 For emergency responders Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the MSDS Environmental precautions Prevent entry into waterways, sewers, basements or confined areas Methods and material for containment and cleaning up Soak up with inert absorbent material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Clean contaminated surface thoroughly. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination Reference to other sections Never return spills in original containers for reuse. Clean up spills immediately, observing precautions in Protective Equipment section. Sweep up and shovel into suitable containers for disposal. For personal protection, see section 8 of the MSDS. For waste disposal, see section 13 of the MSDS. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures Derived noeffect level (DNEL) Do NOT pressurize, cut, heat, or weld containers. Empty product containers may contain product residue. Avoid prolonged or repeated skin contact with this material. Do not handle or store near an open flame, heat or other sources of ignition. Avoid breathing gas/vapors/mist/fumes. Do not take internally. Do not taste or swallow. Avoid contact with eyes. Wash thoroughly after handling. Keep away from heat and sources of ignition. Store in a closed container away from incompatible materials. Store in cool place. Store away from incompatible materials (see Section 10 of the MSDS). No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Predicted no effect concentrations (PNECs) Exposure guidelines 8.2. Exposure controls Appropriate engineering controls This material does not have established exposure limits. Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Wear safety glasses; chemical goggles (if splashing is possible). Hand protection For prolonged or repeated skin contact use suitable protective gloves. Other Wear suitable protective clothing. Wear nitrile, neoprene, PVC or viton gloves. Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance An air purifying respirator with an organic vapor cartridge may be used under certain circumstances where airborne concentrations are expected to exceed exposure limits, or if irritation or symptoms are experienced. Respiratory protection must be provided in accordance with 29 CFR No personal respiratory protective equipment normally required. Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Launder contaminated clothing before reuse. Wash hands thoroughly after handling. Environmental manager must be informed of all major releases. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

4 Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid. Liquid. Semisolid White Slight Upper/lower flammability or explosive limits Flammability limit lower (%) Flammability limit upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient (noctanol/water) Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information Kinematic viscosity Shelf life 33 cst 4 years SECTION 10: Stability and reactivity Reactivity The product is stable and nonreactive under normal conditions of use, storage and transport Chemical stability Stable Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Heat, flames and sparks. Contact with incompatible materials Incompatible materials Strong acids, alkalies and oxidizing agents. Alkaline metals. Alkaline earth metals. Powdered metals. Halogenated compounds Hazardous decomposition products SECTION 11: Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms Information on toxicological effects Acute toxicity Skin corrosion/irritation Hydrogen fluoride. Carbonyl fluoride. Occupational exposure to the substance or mixture may cause adverse effects. Knowledge about health hazard is incomplete. No adverse effects due to inhalation are expected. Knowledge about health hazard is incomplete. Knowledge about health hazard is incomplete. Direct contact with eyes may cause temporary irritation. No data available. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

5 Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity IARC Monographs. Overall Evaluation of Carcinogenicity POLYTETRAFLUOROETHYLENE (CAS ) Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Mixture versus substance information Other information SECTION 12: Ecological information This product does not contain any carcinogens or potential carcinogens as listed by ACGIH and IARC. This product does not contain any carcinogens or potential carcinogens as listed by IARC. This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC and NTP. 3 Not classifiable as to carcinogenicity to humans. No information available. This product has no known adverse effect on human health Toxicity This material is not expected to be harmful to aquatic life Persistence and degradability Bioaccumulative potential No data available. Partition coefficient noctanol/water (log Kow) Bioconcentration factor (BCF) No data is available on the degradability of this product Mobility in soil No data available Results of PBT and vpvb assessment Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information Special precautions SECTION 14: Transport information ADR RID ADN IATA Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Contract with a disposal operator licensed by the Law on Disposal and Cleaning. Dispose in accordance with all applicable regulations. Dispose in accordance with all applicable regulations. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

6 IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information This substance/mixture is not intended to be transported in bulk Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, Article 59(1). Candidate List Authorizations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Restrictions on use Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Other EU regulations Directive 96/82/EC (Seveso II) on the control of majoraccident hazards involving dangerous substances Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Directive 94/33/EC on the protection of young people at work Other regulations National regulations Chemical Safety Assessment SECTION 16: Other information List of abbreviations References The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. The product does not need to be labelled in accordance with EC directives or respective national laws. This safety datasheet complies with the requirements of Directive 2001/58/EC. Follow national regulation for work with chemical agents. No Chemical Safety Assessment has been carried out. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

7 Information on evaluation method leading to the classification of mixture Full text of any statements or Rphrases and Hstatements under Sections 2 to 15 Revision information Training information Issued by Disclaimer The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. This document has undergone significant changes and should be reviewed in its entirety. Follow training instructions when handling this material. Jason Galary Manager: Technical Support, Applications, and Engineering The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release. Nye Lubricants, Inc. makes no warranty with respect thereto and disclaims all liability with respect thereon. The information in the sheet was written based on the best knowledge and experience currently available. UNIFLOR 8961 Version #: 02 Revision date: February Issue date: June / 7

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