Safety Data Sheet Lupragen N Dimethylaminoethoxyethanol Revision date : 2016/12/02 Page: 1/11

Transcription

1 Revision date : 2016/12/02 Page: 1/11 1. Identification Product identifier used on the label Lupragen N Dimethylaminoethoxyethanol Recommended use of the chemical and restriction on use Recommended use*: Chemical * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Molecular formula: C(6)H(15)NO(2) Chemical family: aliphatic alcohol, amine, ether Synonyms: 2-(2-(N,N'-Dimethylamino)ethoxy)ethanol 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Flam. Liq. 4 Flammable liquids Acute Tox. 4 (dermal) Acute toxicity Skin Corr./Irrit. 1C Skin corrosion/irritation Eye Dam./Irrit. 1 Serious eye damage/eye irritation Label elements

2 Revision date : 2016/12/02 Page: 2/11 Pictogram: Signal Word: Danger Hazard Statement: H227 H312 H314 Combustible liquid. Harmful in contact with skin. Causes severe skin burns and eye damage. Precautionary Statements (Prevention): P280 Wear protective gloves/protective clothing/eye protection/face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust or mist. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P310 Immediately call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. Precautionary Statements (Storage): P405 Store locked up. P403 + P235 Store in a well-ventilated place. Keep cool. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name >= <= 100.0% 2-(2-(dimethylamino)ethoxy)ethanol >= <= 0.1% 4-methylmorpholine

3 Revision date : 2016/12/02 Page: 3/11 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler. If on skin: Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Immediately rinse mouth and then drink ml of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: nitrogen oxides, carbon oxides The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

4 Revision date : 2016/12/02 Page: 4/11 Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Impact Sensitivity: Remarks: Based on the chemical structure there is no shock-sensitivity. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid inhalation. Avoid contact with the skin, eyes and clothing. Environmental precautions Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). For large amounts: Pump off product. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Protection against fire and explosion: The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Conditions for safe storage, including any incompatibilities Segregate from acids and acid forming substances. Further information on storage conditions: Keep away from sources of ignition - No smoking. Keep container tightly closed and in a well-ventilated place. Storage stability: Storage duration: 24 Months From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced. 8. Exposure Controls/Personal Protection No occupational exposure limits known. Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.

5 Revision date : 2016/12/02 Page: 5/11 Hand protection: Chemical resistant protective gloves Eye protection: Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately. 9. Physical and Chemical Properties Form: liquid Odour: amine-like Odour threshold: Not determined due to potential health hazard by inhalation. Colour: colourless to yellow ph value: 11.1 ( 100 g/l, 20 C) Melting point: < -70 C Boiling point: C (other) ( 1,013 hpa) Flash point: 90 C (DIN 51758) Flammability: Combustible liquid. Lower explosion limit: 0.9 %(V) ( 80 C, 9 hpa) Upper explosion limit: For liquids not relevant for classification and labelling. Autoignition: 205 C (DIN 51794) Vapour pressure: < 1 mbar ( 25 C) Density: 0.95 g/cm3 ( 20 C) (Regulation 440/2008/EC, A.3) Relative density: (other) ( 20 C) Literature data. Partitioning coefficient n- octanol/water (log Pow): ( 20 C) (Regulation 440/2008/EC, A.8) Self-ignition not self-igniting (other) temperature: Viscosity, dynamic: 10 mpa.s ( 25 C) Viscosity, kinematic: 11.7 mm2/s (OECD 114) ( 20 C) 4.6 mm2/s (OECD 114) ( 40 C) Particle size: The substance / product is marketed or used in a non solid or granular form.

6 Revision date : 2016/12/02 Page: 6/11 Solubility in water: Molar mass: Evaporation rate: 10. Stability and Reactivity Reactivity Corrosion to metals: No corrosive effect on metal. ( 20 C) miscible g/mol Value can be approximated from Henry's Law Constant or vapor pressure. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. (other) Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Reacts with acid chlorides. Reacts with acids. Incompatible with acid chlorides and acid anhydrides. Reacts with oxidizing agents. Reacts with halogenated compounds. The progress of reaction is exothermic. Conditions to avoid Avoid extreme heat. Incompatible materials acids, isocyanates, oxidizing agents, acid chlorides Hazardous decomposition products Decomposition products: Thermal decomposition products: carbon oxides, nitrogen oxides 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Of low toxicity after single ingestion. The inhalation of a highly enriched/saturated vapor-air-mixture represents an unlikely acute hazard. Of moderate toxicity after short-term skin contact. Oral Type of value: LD50

7 Revision date : 2016/12/02 Page: 7/11 Species: rat Value: > 2,150 - < 3,830 mg/kg (similar to OECD guideline 401) Inhalation Type of value: LC50 Species: rat Value: > 0.39 mg/l (IRT) Exposure time: 4 h Highest concentration available for testing. No Mortality within the stated exposition time as shown in animal studies, however, deaths occurred after longer exposure. Dermal Type of value: LD50 Species: rabbit (male) Value: 1,663 mg/kg (OECD Guideline 402) Assessment other acute effects Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Irritation / corrosion Assessment of irritating effects: Corrosive! Damages skin and eyes. Skin Species: rabbit Result: Corrosive. Method: OECD Guideline 404 Eye Species: rabbit Result: Risk of serious damage to eyes. Method: OECD Guideline 405 Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Species: guinea pig Result: Non-sensitizing. Method: OECD Guideline 406 The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aspiration Hazard No aspiration hazard expected. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No substance-specific organtoxicity was observed after repeated administration to animals. After repeated exposure the prominent effect is local irritation. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Genetic toxicity

8 Revision date : 2016/12/02 Page: 8/11 Assessment of mutagenicity: The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in a test with mammals. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: No data available concerning carcinogenic effects. Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in animal studies. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The results were determined in a Screening test (OECD 421/422). Teratogenicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The results were determined in a Screening test (OECD 421/422). Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish LC50 (96 h) approx. 320 mg/l, Leuciscus idus (DIN Part 15) The product will cause changes in the ph value of the test system. The result refers to an unneutralized sample. After neutralization, it is no longer toxic. Nominal concentration. Aquatic invertebrates EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1) Nominal values (confirmed by concentration control analytics) Aquatic plants EC50 (72 h) 160 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) Nominal values (confirmed by concentration control analytics) EC10 (72 h) 65 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) Nominal values (confirmed by concentration control analytics) Chronic toxicity to fish Study scientifically not justified.

9 Revision date : 2016/12/02 Page: 9/11 Chronic toxicity to aquatic invertebrates Study scientifically not justified. Assessment of terrestrial toxicity Study not necessary due to exposure considerations. Microorganisms/Effect on activated sludge Toxicity to microorganisms OECD Guideline 209 activated sludge, industrial/ec20 (30 min): > 720 mg/l OECD Guideline 209 static activated sludge, domestic/no observed effect concentration (3 h): >= 1,000 mg/l Persistence and degradability Assessment biodegradation and elimination (H2O) Not readily biodegradable (by OECD criteria). Poorly eliminated from water. Elimination information % (28 d) (OECD Guideline 302 B) (aerobic, activated sludge, industrial) 2 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Assessment of stability in water According to structural properties, hydrolysis is not expected/probable. Information on Stability in Water (Hydrolysis) According to structural properties, hydrolysis is not expected/probable. Assessment photodegration After evaporation or exposure to the air, the product will be rapidly degraded by photochemical processes. Photodegradation t 1/2 (Indirect photolysis) 0.14 d; OH radical (calculated) After evaporation or exposure to the air, the product will be rapidly degraded by photochemical processes. Bioaccumulative potential Assessment bioaccumulation potential Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Bioaccumulation potential Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Additional information Sum parameter Chemical oxygen demand (COD): 1,120 mg/g

10 Revision date : 2016/12/02 Page: 10/11 Biochemical oxygen demand (BOD): 5 mg/g Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Other ecotoxicological advice: Due to the ph-value of the product, neutralization is generally required before discharging sewage into treatment plants. 13. Disposal considerations Waste disposal of substance: Incinerate in suitable incineration plant, observing local authority regulations. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport TDG Hazard class: 8 Packing group: II ID number: UN 2735 Hazard label: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains 2-(2- DIMETHYLAMINOETHOXY)ETHANOL) Sea transport IMDG Hazard class: 8 Packing group: II ID number: UN 2735 Hazard label: 8 Marine pollutant: NO Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains 2-(2- DIMETHYLAMINOETHOXY)ETHANOL) Air transport IATA/ICAO Hazard class: 8 Packing group: II ID number: UN 2735 Hazard label: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains 2-(2- DIMETHYLAMINOETHOXY)ETHANOL)

11 Revision date : 2016/12/02 Page: 11/ Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed According to Controlled Products Regulations (CPR) (SOR/88-66) WHMIS classification: B3: Combustible Liquid E: Corrosive material Assessment of the hazard classes according to UN GHS criteria (most recent version): Flam. Liq. 4 Flammable liquids Acute Tox. 5 (oral) Acute toxicity Acute Tox. 4 (dermal) Acute toxicity Skin Corr./Irrit. 1C Skin corrosion/irritation Eye Dam./Irrit. 1 Serious eye damage/eye irritation 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2016/12/02 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. Lupragen N Dimethylaminoethoxyethanol is a registered trademark of BASF Canada or BASF SE END OF DATA SHEET