SAFETY DATA SHEET Revised edition no : 1 SDS/MSDS Date : 1 / 8 / 2013

Transcription

1 Page : 1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : IUM SALT 40% AQUEOUS SOLUTION Product code : Identification of the product : Pentasodium (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate CAS No : EC No : Relevant identified uses of the substance or mixture and uses advised against Use : Industrial. For professional use only Details of the supplier of the safety data sheet Company identification : 107 Wode House Road, Jehangir Villa, Colaba Mumbai INDIA 1.4. Emergency telephone number Phone nr : (9:00am - 6:00 pm) [ Office hours ] 2. Hazards identification -DSD 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 Classification : F+; R12 R19 Xn; R22 R66 R67 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 - Warning (CLP : STOT SE 3) H336 Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302 Physical hazards : Flammable solids - Category 1 - Danger (CLP : Flam. Sol. 1) H228

2 Page : 2 2. Hazards identification -DSD (continued) 2.2. Label elements Labelling EC 67/548 or EC 1999/45 Symbol(s) Symbol(s) êf êx : F+ : Extremely flammable Xn : Harmful R Phrase(s) : R12 : Extremely flammable. R19 : May form explosive peroxides. R22 : Harmful if swallowed. R66 : Repeated exposure may cause skin dryness or cracking. R67 : Vapours may cause drowsiness and dizziness. S Phrase(s) : S16 : Keep away from sources of ignition - No smoking. S29 : Do not empty into drains. S33 : Take precautionary measures against static discharges. Contains : Pentasodium (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms Signal words Hazard statements Precautionary statements Prevention Response M MÄ : Danger : H228 : Flammable solid. H302 : Harmful if swallowed. H336 : May cause drowsiness or dizziness. : P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting,, equipment. P210: Keep away from heat, sparks, open flames or hot surfaces. No smoking. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. : P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel unwell. P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing. P370+P378: In case of fire: Use for extinction.

3 Page : 3 2. Hazards identification -DSD (continued) Storage Disposal considerations Contains : P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Pentasodium (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate 2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH. 3. Composition/information on ingredients Substance / Preparation : Pentasodium (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate CAS No : EC No : Substance. Substance name Contents CAS No EC No Annex No REACH Ref. Classification Pentasodium (carboxylatomethyl) : 100 % R10 Xn; R22 iminobis(ethylenenitrilo) Xi; R37/38-41 tetraacetate Eye Dam 1 _ H318 Flam. Sol. 2 _ H228 Acute Tox. 4 (oral) _ H302 Skin Irrit. 2 _ H315 STOT SE 3 _ H335 Contains no other components or impurities which will influence the classification of the product. 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Call a POISON CENTER or doctor if you feel unwell. Remove to fresh air and keep at rest in a position comfortable for breathing. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms relating to use : Swallowing a small quantity of this material will result in serious health hazard. May cause drowsiness or dizziness. Repeated exposure may cause skin dryness or cracking.

4 Page : 4 4. First aid measures (continued) 4.3. Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Flammable class Hazardous combustion products : Flammable solid. May form explosive peroxides. : Under fire conditions, hazardous fumes will be present. May form flammable/ explosive vapour-air mixture Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. DO NOT fight fire when fire reaches explosives. Evacuate area. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders Technical measures Special precautions For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. Avoid breathing dust, fume, gas, mist, vapours, spray. : Use special care to avoid static electric charges. : Remove ignition sources. No naked lights. No smoking. Reacts vigorously with strong oxidizers and acids. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters.

5 Page : 5 6. Accidental release measures (continued) 6.3. Methods and material for containment and cleaning up Clean up methods : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures Special precautions : Handle empty containers with care because residual vapours are flammable. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. : Provide good ventilation in process area to prevent formation of vapour. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical, ventilating, lighting,, equipment. : No naked lights. No smoking. Avoid breathing dust, fume, gas, mist, vapours, spray Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, well ventilated place. Keep in fireproof place. Ground/bond container and receiving equipment. Keep container tightly closed. : Strong bases. Strong acids. Sources of ignition. Direct sunlight. Heat sources. Oxidizing agent Specific end use(s) Specific end use(s) : None. 8. Exposure controls/personal protection 8.1. Exposure controls Personal protection Respiratory protection Hand protection : Avoid all unnecessary exposure. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. : Wear protective gloves.

6 Page : 6 8. Exposure controls/personal protection (continued) Eye protection Others : Chemical goggles or safety glasses. : When using, do not eat, drink or smoke Control parameters Occupational Exposure Limits : No data available. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Liquid. Colour : Clear colorless to pale yellow Odour : Odorless Odour threshold : No data available. ph value : Not applicable. Melting point [ C] : No data available. Decomposition point [ C] Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) Flammable solid. Flash point [ C] Boiling point [ C] Initial boiling point [ C] Final boiling point [ C] Evaporation rate Vapour pressure [20 C] Vapour pressure mm/hg Vapour density Density [g/cm3] : 1.303g /ml at 20 C Relative density, gas (air=1) Relative density, liquid (water=1) Solubility in water [% weight] : Miscible in water Solubility in water Log Pow octanol / water at 20 C : No data available. Solubility Viscosity at 40 C [mm2/s] 9.2. Other information

7 Page : 7 9. Physical and chemical properties (continued) Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties May form explosive peroxides. : No data available. 10. Stability and reactivity Reactivity Reactivity : Not established Chemical stability Chemical stability : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : Not established Conditions to avoid Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. Heat. Sparks. Open flame. Direct sunlight. Overheating Incompatible materials Materials to avoid : Strong acids. Strong bases. Oxidizing agent Hazardous decomposition products Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide. May release flammable gases. 11. Toxicological information Information on toxicological effects Acute toxicity Inhalation Dermal Ingestion : Harmful if swallowed.

8 Page : Toxicological information (continued) Corrosion Irritation Sensitization Mutagenicity Carcinogenicity Toxic for reproduction STOT-single exposure STOT-repeated exposure Aspiration hazard : Repeated exposure may cause skin dryness or cracking. : May cause drowsiness or dizziness. 12. Ecological information Toxicity Toxicity information : Not established Persistence - degradability Persistence - degradability : Biodegradable Bioaccumulative potential Bioaccumulative potential : Not established Mobility in soil Mobility in soil : Not established Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. 13. Disposal considerations Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Hazardous waste due to potential risk of explosion.

9 Page : Disposal considerations (continued) Special precautions Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Handle empty containers with care because residual vapours are flammable. 14. Transport information Land transport (ADR-RID) Proper shipping name : DIETHYL ETHER (ETHYL ETHER) UN N : 1155 H.I. nr :33 ADR - Class :3 Labelling - Transport : 3 : Flammable liquid. óp ADR - Classification code :F1 F1 F1 ADR - Group :I ADR - Packing instructions : P001 ADR - Limited Quantity :0 ADR - Tunnel code º : D/E : Bulk or tank carriage: Passage forbidden through tunnels of category D and E. Other carriage: Passage forbidden through tunnels of category E Sea transport (IMDG) [English only] Proper shipping name : DIETHYL ETHER (ETHYL ETHER) UN N : 1155 IMO-IMDG - Class or division : 3 : Flammable liquid. IMO-IMDG - Packing group :I IMO- IMDG - Packing instructions : P001 IMO-IMDG - Limited quantities : None IMO-IMDG - Marine pollution :No EMS-Nr : F-E S-D

10 Page : Transport information (continued) Air transport (ICAO-IATA) [English only] Proper shipping name : DIETHYL ETHER (ETHYL ETHER) UN N : 1155 IATA - Class or division : 3 : Flammable liquid. IATA - Packing group :I IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 351 instruction - Passenger and Cargo - Maximum :1 L Quantity/Packing IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 30 L Packing ERG-Nr : 3AH 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions. REACH Authorisation - Annex XIV : The components of this product are not subject to authorization Chemical Safety Assessment Chemical Safety Assessment : It has not been carried out. 16. Other information Revision : Revision - See : * Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vpvb: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 List of relevant R phrases (heading 3) : R10 : Flammable. R22 : Harmful if swallowed. R37/38 : Irritating to respiratory system and skin.

11 Page : Other information (continued) List of full text of H-statements in section 3 Further information R41 : Risk of serious damage to eyes. : H228 : Flammable solid. H302 : Harmful if swallowed. H315 : Causes skin irritation. H318 : Causes serious eye damage. H335 : May cause respiratory irritation. : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document