Safety Data Sheet PolyTHF 2000 Polyether Revision date : 2016/12/02 Page: 1/9

Transcription

1 Revision date : 2016/12/02 Page: 1/9 1. Identification Product identifier used on the label PolyTHF* 2000 Polyether Recommended use of the chemical and restriction on use Recommended use*: initial product for chemical syntheses * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Chemical family: polyether Synonyms: PTMG 2000 Use: Chemical used in synthesis and/or formulation of industrial products. 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product No need for classification according to GHS criteria for this product. Label elements The product does not require a hazard warning label in accordance with GHS criteria.

2 Revision date : 2016/12/02 Page: 2/9 Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) This product does not contain any components classified as hazardous under the referenced regulation. 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. If breathing difficulties develop, aid in breathing and seek immediate medical attention. Keep patient calm, remove to fresh air. If on skin: Wash thoroughly with soap and water. If irritation develops, seek medical attention. Wash thoroughly with soap and water. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention. Wash affected eyes for at least 15 minutes under running water with eyelids held open. If swallowed: Rinse mouth and then drink plenty of water. Induce vomiting. Seek medical attention if necessary. Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed Symptoms: Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Symptomatic treatment (decontamination, vital functions).

3 Revision date : 2016/12/02 Page: 3/9 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, foam, dry powder, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: nitrogen oxides, carbon oxides The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Environmental precautions Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Allow to solidify and sweep/shovel up. For large amounts: Allow to solidify and sweep/shovel up. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Prevent contact with air/oxygen (formation of peroxide). Handle under dry inert gas. Protection against fire and explosion: Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Conditions for safe storage, including any incompatibilities Suitable materials for containers: Stainless steel (V2), Aluminium, High density polyethylene (HDPE), Carbon steel (Iron), tinned carbon steel (Tinplate), glass, Low density polyethylene (LDPE), Galvanized carbon steel (Zinc), Stainless steel Further information on storage conditions: Containers should be stored tightly sealed in a dry place. Keep under nitrogen. Prevent entry of air/oxygen. Formation of peroxides.

4 Revision date : 2016/12/02 Page: 4/9 Storage stability: Storage temperature: 20 - < 95 C Storage duration: 24 Months The product is stabilized, the shelf life should be noted. Protect from temperatures above: 90 C If transport time lasts more than 2 days the packed product must be protected against exceeding the indicated temperature. additives: BHT (CAS Number: ) 8. Exposure Controls/Personal Protection No occupational exposure limits known. Personal protective equipment Respiratory protection: Respiratory protection required in case of exceptional circumstances (e.g.: accidental release, exceeding the occupational exposure limit) Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN Type A-P2) Hand protection: Chemical resistant protective gloves, Suitable materials, rubber, plastic Eye protection: Tightly fitting safety goggles (chemical goggles). Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Avoid inhalation of dust. Wash soiled clothing immediately. 9. Physical and Chemical Properties Form: liquid to waxy Odour: odourless Odour threshold: not applicable, odour not perceivable Colour: colourless ph value: No data available. Melting point: 36 C Boiling point: > 250 C Flash point: 246 C (DIN ISO 2592) Flammability: not highly flammable Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Autoignition: > 245 C (DIN 51794)

5 Revision date : 2016/12/02 Page: 5/9 Vapour pressure: < 0.1 mbar ( 20 C) Density: g/cm3 ( 40 C) Vapour density: not determined Partitioning coefficient n (calculated) octanol/water (log Pow): Thermal decomposition: C (DSC (DIN 51007)) No exothermic decomposition within the mentioned temperature range. It is not a self-decompositionable substance. Viscosity, dynamic: 1,270 mpa.s ( 40 C) Solubility in water: ( 20 C) sparingly soluble Solubility (qualitative): soluble solvent(s): organic solvents, Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Oxidizing properties: not fire-propagating Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Risk of self-ignition when a large surface area is produced due to fine dispersion. Self-ignition at high temperatures. Conditions to avoid Temperature: > 100 degrees Celsius See MSDS section 7 - Handling and storage. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: Possible decomposition products: tetrahydrofuran, No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: C, 2.0 K/min (DSC (DIN 51007)) No exothermic decomposition within the mentioned temperature range. It is not a selfdecompositionable substance. 11. Toxicological information Primary routes of exposure

6 Revision date : 2016/12/02 Page: 6/9 Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Oral Type of value: LD50 Species: rat Value: > 5,000 mg/kg (BASF-Test) Assessment other acute effects Assessment of STOT single: No data available. Irritation / corrosion Assessment of irritating effects: Not irritating to the eyes. Skin contact causes slight irritation. Skin Species: rabbit Result: non-irritant Method: Draize test Eye Species: rabbit Result: non-irritant Method: Draize test Sensitization Assessment of sensitization: The chemical structure does not suggest a sensitizing effect. Aspiration Hazard not applicable Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No data available. Genetic toxicity Assessment of mutagenicity: The substance was not mutagenic in bacteria. Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: No data available. Teratogenicity Assessment of teratogenicity: No data available. Symptoms of Exposure

7 Revision date : 2016/12/02 Page: 7/9 Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. There is a high probability that the product is not acutely harmful to aquatic organisms. Assessment of terrestrial toxicity No data available. Microorganisms/Effect on activated sludge Toxicity to microorganisms DIN EN ISO 8192-OECD /302/EEC,P. C aerobic activated sludge, domestic/ec20 (30 min): approx. 450 mg/l The details of the toxic effect relate to the nominal concentration. Persistence and degradability Assessment biodegradation and elimination (H2O) Not readily biodegradable (by OECD criteria). Poorly biodegradable. Elimination information % BOD of the ThOD (32 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, adapted) Bioaccumulative potential Bioaccumulation potential Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is possible. Mobility in soil Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected. Additional information Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Other ecotoxicological advice: Do not allow to enter soil, waterways or waste water channels. 13. Disposal considerations Waste disposal of substance:

8 Revision date : 2016/12/02 Page: 8/9 Incinerate in suitable incineration plant, observing local authority regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage. The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed According to Controlled Products Regulations (CPR) (SOR/88-66) Not WHMIS controlled. Assessment of the hazard classes according to UN GHS criteria (most recent version): Skin Corr./Irrit. 3 Skin corrosion/irritation 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2016/12/02 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring

9 Revision date : 2016/12/02 Page: 9/9 the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. PolyTHF is a registered trademark of BASF Canada or BASF SE END OF DATA SHEET