Safety Data Sheet DABCO 120 CATALYST Revision date : 2013/10/24 Page: 1/7

Transcription

1 Revision date : 2013/10/24 Page: 1/7 1. Product and Company Identification Company BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA 24 Hour Emergency Response Information CHEMTREC: BASF HOTLINE: HELP (4357) 2. Hazards Identification Emergency overview CAUTION: Harmful in contact with skin. TOXIC IF SWALLOWED. Causes severe respiratory irritation. Severely irritating to the skin. MAY CAUSE EYE IRRITATION. State of matter: liquid Colour: light yellow Odour: rotten Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute toxicity: Of moderate toxicity after short-term skin contact. Virtually nontoxic by inhalation. Virtually nontoxic after a single ingestion. Irritation / corrosion: Skin contact causes irritation. Not irritating to the eyes. Assessment other acute effects: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Sensitization: Sensitization after skin contact possible. Chronic toxicity:

2 Revision date : 2013/10/24 Page: 2/7 Carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Repeated dose toxicity: Repeated oral exposure may affect certain organs. Repeated exposure to the substance by dermal administration leads to effects similar to those found after single exposure. Repeated exposure to the substance by inhalative administration leads to effects similar to those found after single exposure. Reproductive toxicity: May cause reproductive effects. Teratogenicity: May cause teratogenic effects. Genotoxicity: Mutagenic properties can not be excluded on the basis of experimental data. Signs and symptoms of overexposure: Eye irritation, skin irritation Skin resorption hazard. Potential environmental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Degradation / environmental fate: Not readily biodegradable (by OECD criteria). 3. Composition / Information on Ingredients CAS Number Content (W/W) Chemical name % Stannane, dibutylbis(dodecylthio)- 4. First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: Wash off thoroughly with ample water. If irritation develops, seek medical attention. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

3 Revision date : 2013/10/24 Page: 3/7 5. Fire-Fighting Measures Flash point: 121 C (DIN 51758) Autoignition: > 360 C Lower explosion limit: For liquids not relevant for classification and labelling. The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Flammability: not flammable Self-ignition temperature: > 300 C Suitable extinguishing media: water spray, dry powder, alcohol-resistant foam, carbon dioxide Hazards during fire-fighting: carbon monoxide, carbon dioxide, Tin oxide, sulfur oxides, toxic gases/vapours The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental release measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not empty into drains. Do not discharge into the subsoil/soil. Cleanup: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling General advice: Ensure thorough ventilation of stores and work areas. Avoid all direct contact with the substance/product. Protection against fire and explosion: Sources of ignition should be kept well clear. Storage General advice: Containers should be stored tightly sealed in a dry place. Keep in a cool, well-ventilated place. Protect from the effects of light. Protect from air. Storage incompatibility: General advice: Segregate from foods and animal feeds. Segregate from strong oxidizing agents.

4 Revision date : 2013/10/24 Page: 4/7 8. Exposure Controls and Personal Protection Components with occupational exposure limits Stannane, dibutylbis(dodecylthio)- OSHA PEL PEL 0.1 mg/m3 (tin (Sn)); ACGIH TLV TWA value 0.1 mg/m3 (tin (Sn)); STEL value 0.2 mg/m3 (tin (Sn)); Skin Designation (tin (Sn)); The substance can be absorbed through the skin. Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Standard work clothes and shoes. General safety and hygiene measures: Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. 9. Physical and Chemical Properties Form: oily to liquid Odour: rotten Colour: light yellow ph value: 2.8 solidification temperature: < 0 C Boiling point: 185 C Vapour pressure: approx. 13 mbar ( 21 C) Density: approx g/cm3 ( 25 C) (DIN 51757) Relative density: approx Vapour density: not applicable Partitioning coefficient n- > 3 ( 25 C) octanol/water (log Pow): Viscosity, dynamic: approx. 19 mpa.s ( 25 C) Solubility in water: insoluble Miscibility with water: partly miscible Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: Avoid light. Avoid contact with air. Avoid direct sunlight. Substances to avoid: strong oxidizing agents, hypochlorites, peroxides

5 Revision date : 2013/10/24 Page: 5/7 Hazardous reactions: Reacts with peroxides. Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: > 275 C Corrosion to metals: No corrosive effect on metal. 11. Toxicological information Acute toxicity Dermal: Type of value: LD50 Species: rabbit Value: > 1,000 mg/kg Irritation / corrosion Skin: Species: rabbit Result: Severely irritating. Eye: Result: Slightly irritating. Aspiration Hazard: No aspiration hazard expected. 12. Ecological Information Fish Acute: LC50 (48 h): 2.1 mg/l Aquatic invertebrates Acute: Daphnia magna/ec50: 2.3 mg/l Other adverse effects: Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. 13. Disposal considerations Waste disposal of substance: Must be disposed of or incinerated in accordance with local regulations.

6 Revision date : 2013/10/24 Page: 6/7 Container disposal: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Land transport USDOT Hazard class: 6.1 Packing group: III ID number: UN 2788 Hazard label: 6.1, EHSM Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (contains DIBUTYL-TINN- DILAURYLMERCAPTIDE) Sea transport IMDG Hazard class: 6.1 Packing group: III ID number: UN 2788 Hazard label: 6.1, EHSM Marine pollutant: YES Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (contains DIBUTYL-TINN- DILAURYLMERCAPTIDE) Air transport IATA/ICAO Hazard class: 6.1 Packing group: III ID number: UN 2788 Hazard label: 6.1 Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (contains DIBUTYL-TINN- DILAURYLMERCAPTIDE) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed OSHA hazard category: Skin and/or eye irritant; Acute target organ effects reported; Chronic target organ effects reported; ACGIH TLV established EPCRA 311/312 (Hazard categories): Acute; Chronic 16. Other Information Recommended use: catalyst polyurethane component Suitable for use in industrial sector: Polymers industry; chemical industry

7 Revision date : 2013/10/24 Page: 7/7 HMIS III rating Health: 2 Flammability: 1 Physical hazard: 0 NFPA and HMIS use a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance possesses essentially no hazard; a rating of four indicates extreme danger. Although similar, the two rating systems are intended for different purposes, and use different criteria. The NFPA system was developed to provide an onthe-spot alert to the hazards of a material, and their severity, to emergency responders. The HMIS system was designed to communicate workplace hazard information to employees who handle hazardous chemicals. We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2013/10/24 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET