Safety Data Sheet Irgafos 126 Revision date : 2014/03/07 Page: 1/8

Transcription

1 Revision date : 2014/03/07 Page: 1/8 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Synonyms: Not available Use : Antioxidant / Stabilizer 2. Hazards Identification Emergency overview CAUTION: This product may cause neurotoxicity. Symptoms of neurotoxicity can include weakness, staggered walk, tremors, or even paralysis. Animal studies have indicated in one test that the material is a neurotoxin at the high dose in dogs. Three other types of animals, including a two year study in rats, did not produce neurotoxicity. This material is considered to be a neurotoxin at high levels of exposure. Persons with certain types of neurological diseases, such as multiple sclerosis,should contact a physician prior to exposure. May cause mechanical irritation to eyes, skin and respiratory system. AVOID CREATING DUST. Use NIOSH approved respirator as needed to mitigate exposure. Take precautionary measures against static discharges. State of matter: solid Colour: white to cream Odour: odourless Potential health effects Primary routes of entry: Skin Eyes Inhalation. Acute toxicity: Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion. Irritation / corrosion: Not irritating to eyes and skin. Assessment other acute effects: Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

2 Revision date : 2014/03/07 Page: 2/8 Sensitization: Skin sensitizing effects were not observed in animal studies. Chronic toxicity: Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. Based on the ingredients there is no suspicion of a carcinogenic effect in humans. Repeated dose toxicity: Repeated oral uptake of the substance did not cause substance-related effects. Reproductive toxicity: The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity: No teratogenic effects reported. Genotoxicity: The substance was not mutagenic in studies with mammals. Signs and symptoms of overexposure: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Further important symptoms and effects are so far not known. 3. Composition / Information on Ingredients CAS Number Content (W/W) Hazardous ingredients % 2,4,8,10-Tetraoxa-3,9-diphosphaspiro[5.5]undecane, 3,9-bis[2,4- bis(1,1-dimethylethyl)phenoxy]- 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. If on skin: Wash thoroughly with soap and water. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention. If swallowed: If swallowed, drink plenty of water. Do not induce vomiting. Consult a physician. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

3 Revision date : 2014/03/07 Page: 3/8 5. Fire-Fighting Measures Flash point: 125 C (DIN 51758) Autoignition: approx. 350 C Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Flammability: not flammable Self-ignition temperature: 20 C Based on its structural properties the product is not classified as self-igniting. > 400 C (Directive 84/449/EEC, A.16) Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire. Impact Sensitivity: Remarks: Based on the chemical structure there is no shock-sensitivity. 6. Accidental release measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Cleanup: Avoid raising dust. For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. 7. Handling and Storage Handling General advice: Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges.

4 Revision date : 2014/03/07 Page: 4/8 Dust can form an explosive mixture with air. Storage General advice: Keep container tightly closed and dry; store in a cool place. 8. Exposure Controls and Personal Protection Personal protective equipment Respiratory protection: Breathing protection if breathable aerosols/dust are formed. Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Wear chemical resistant protective gloves. Eye protection: Safety glasses with side-shields. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Wear protective clothing as necessary to minimize contact. Handle in accordance with good industrial hygiene and safety practice. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: solid Odour: odourless Odour threshold: No data available. Colour: white to cream ph value: not soluble Melting point: C Boiling point: > 311 C Vapour pressure: 5 mmhg ( 210 C) Density: g/cm3 ( 20 C) Bulk density: kg/m3 Vapour density: 20.9 Partitioning coefficient n- 11 (calculated) Unspecified octanol/water (log Pow): Viscosity, dynamic: not applicable, the product is a solid Solubility in water: negligible Molar mass: g/mol Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static charge.

5 Revision date : 2014/03/07 Page: 5/8 Substances to avoid: Water, strong acids, strong bases, strong oxidizing agents Hazardous reactions: The product may contain explosive fine dust or such dust may be produced by abrasion during transport or product transfer. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: No decomposition if correctly stored and handled. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating 11. Toxicological information Acute toxicity Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Inhalation: Type of value: LC50 Species: rat No data available concerning acute toxicity. Dermal: Type of value: LD50 Species: rabbit Value: > 2,000 mg/kg Irritation / corrosion Skin: Species: rabbit Result: non-irritant Eye: Species: rabbit Result: non-irritant Sensitization: Species: guinea pig Result: Non-sensitizing. Method: OECD Guideline 406 Aspiration Hazard: No aspiration hazard expected.

6 Revision date : 2014/03/07 Page: 6/8 12. Ecological Information Fish Acute: OECD Guideline 203 static Brachydanio rerio/lc50 (96 h): 70.7 mg/l The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. Chronic: No data available regarding toxicity to fish. Aquatic invertebrates Acute: No data available. Chronic: OECD Guideline 211 semistatic Daphnia magna (NOEC) 21 d 0.1 mg/l The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. Aquatic plants Toxicity to aquatic plants: OECD Guideline 201 static green algae/ec50 (72 h): 97 mg/l The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. OECD Guideline 201 static green algae/ec10 (72 h): 15.4 mg/l The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. A saturated solution has been tested. Microorganisms Toxicity to microorganisms: OECD Guideline 209 static activated sludge, domestic/ec20 (3 h): > 1,000 mg/l Non-Mammals Other terrestrial non-mammals: No data available. Plant Toxicity to terrestrial plants: No data available. Soil living organisms Toxicity to soil dwelling organisms: OECD Guideline 207 artificial soil Eisenia foetida/lc50 (14 d): > 1,000 mg/kg The details of the toxic effect relate to the nominal concentration.

7 Revision date : 2014/03/07 Page: 7/8 Degradability / Persistence Biological / Abiological Degradation Evaluation: The product is virtually insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plants. Bioaccumulation Because of the product's consistency and low water solubility, bioavailability is improbable. The product has not been tested. The statement has been derived from the structure of the product. Environmental mobility: Transport between environmental compartments: calculated Adsorption/water - soil log KOC: Other adverse effects: Do not discharge product into the environment without control. 13. Disposal considerations Waste disposal of substance: Do not discharge into drains/surface waters/groundwater. Dispose of in accordance with national, state and local regulations. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: Proper shipping name: YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains 2,4-DI-TERT-BUTYLPHENOL) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: Proper shipping name: 9, EHSM ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains 2,4-DI-TERT-BUTYLPHENOL)

8 Revision date : 2014/03/07 Page: 8/8 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed This product is WHMIS controlled. WHMIS classification: D2B: Materials Causing Other Toxic Effects - Toxic material THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 16. Other Information Recommended use: Antioxidant / Stabilizer We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2014/03/07 is a registered trademark of BASF Canada or BASF SE END OF DATA SHEET