GPS Product Safety Summary
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1 Document Number: GPSSR-38 (PENTAPROPENYL SUCCINIMIDO) -HEXANOATE, SODIUM AND TRIETHANOLAMINE SALTS (Penta- PSCA Na-TEA) GENERAL STATEMENT GPS summary is intended to provide a general overview of the chemical substances in context of ICCA Global Product Strategy. The information in the summary is general information about the chemical properties & hazards involved to human & environment. Additional information is available through the relevant Safety Data Sheet, which should be consulted before use of the chemical. The substance Penta- PSCA Na-TEA is a UVCB substance of organic origin. CHEMICAL IDENTITY Public Name : (Pentapropenyl succinimido) -hexanoate, sodium and triethanolamine salts (Penta- PSCA Na-TEA) Chemical Name (IUPAC) : sodium/triethanolamine- 6-(2,5-dioxo-3-pentapropenylpyrrolidin-1-yl)hexanoate CAS Name : 1-Pyrrolidinehexanoic acid, 2,5-dioxo-3-(pentapropenyl)-, sodium salt, compd. with 2,2',2''-nitrilotris[ethanol] CAS Number : EC Number : Molecular formula : C 25 H 44 NO 4.1/2Na.1/2C 6 H 15 NO 3 Molecular weight range : ca Structural formula : USES AND APPLICATIONS Used in Hydraulic fluids, Lubricants and lubricant additives, greases, release products, Metal working fluids, in Corrosion inhibitors and anti-scaling agents, Page 1 of 5
2 PHYSICAL/CHEMICAL PROPERTIES Property Physical state Liquid Form Viscous Colour Brown Melting point 4 C at kpa Boiling point 112 C at kpa Relative Density 1.07 at 20 C Vapour pressure 0.2 Pa at 20 C Flash-point ( C) 135 C at 1013 hpa Octanol-water partition 3.64 at 20 C coefficient (Log Kow) Water solubility g/l at 20 C Surface tension 31.6 mn/m at 20 C and 1000 mg/l Self-ignition temperature 395 C at 1013 hpa Viscosity (dynamic in mpa s mpa.s, 20 C) Value HEALTH EFFECTS Human Health Safety Assessment The registration substance Penta- PSCA Na-TEA is classified as dangerous. It causes skin irritation & may damage fertility or the unborn child. Consumer: For the substance Penta- PSCA Na-TEA, no consumer use and no use associated with general population exposure is supported. Workers: The substance Penta- PSCA Na-TEA is manufactured in closed process, in high integrity contained systems where only little potential exists for exposure of workers. It is used under well controlled conditions by workers in industrial settings & professional settings. All exposure scenarios are assessed as safe regarding worker exposure. The risk management measures listed for protection of workers and the environment are implemented as described during the manufacture and loading processes at their production site. The risk management measures for this product are communicated to downstream users by means of a safety data sheet. Effect Assessment Acute Toxicity Oral/dermal/inhalation Irritant effect on skin & eyes No significant toxic effect was found on Oral/dermal/inhalation, however may damage fertility or the unborn child Irritant on skin but no eye irritation Page 2 of 5
3 Sensitisation Toxicity after repeated exposure Genotoxicity / Mutagenicity Carcinogenicity Toxicity for reproduction Not sensitizing to skin Not classified as toxic after repeated exposure Based on available data not mutagenic / genotoxic not considered as carcinogenic based on available data To be classified as a reprotoxicant ENVIRONMENTAL EFFECTS As per CLP/GHS, the substance Penta- PSCA Na-TEA is not classified as toxic to aquatic organisms. But the substance is classified as dangerous for the environment & toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment according to DSD / DPD. Furthermore the substance is evaluated to be not PBT (persistent, bioaccumulative, toxic) or vpvb (very persistent, very bioaccumulative). Effect Assessment Aquatic toxicity (fish, algae, daphnia and microorganisms) Fate and Behaviour Biodegradation Bioaccumulation potential PBT / vpvb conclusion No environmental classification is proposed since no (adverse) effects are expected for aquatic organisms as per CLP/GHS but classified as dangerous for the environment & toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment according to DSD / DPD Not readily or inherently biodegradable No bioaccumulation potential The substance is not a PBT/vPvB substance EXPOSURE Human Health : The registration substance Penta- PSCA Na-TEA is classified as dangerous & it causes skin irritation & may damage fertility or the unborn child. Exposure to the substance Penta- PSCA Na-TEA of personnel in manufacturing facilities is considered very low because the process, storage and handling operations are under industrial hygiene considerations and occupational safety measures. Workers who might accidentally come in contact with the substance should follow the safety measures recommended in the Safety Data Sheet. Environment : No environmental classification is proposed since no (adverse) effects are expected for aquatic organisms as per CLP/GHS. Furthermore the substance is evaluated to be not PBT (persistent, bioaccumulative, toxic) or vpvb (very persistent, very bioaccumulative).. Page 3 of 5
4 RISK MANAGEMENT RECOMMENDATIONS The substance Penta- PSCA Na-TEA is classified as dangerous according to the criteria of the Dangerous Substances Directive (67/548/EEC) or the Classification, Labelling and Packaging of Substances and Mixtures (CLP Regulation; 1272/2008/EC). Specific Risk Management Measures are therefore required. Do not ingest. If swallowed then seek immediate medical assistance. Avoid manual contact with wet work pieces. Avoid direct eye contact with product, also via contamination on hands. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).control any potential exposure using measures such as contained or enclosed systems, properly designed and maintained facilities and a good standard of general ventilation. Drain down systems and transfer lines prior to breaking containment. Drain down and flush equipment where possible prior to maintenance. Where there is potential for exposure: Ensure relevant staff are informed of the nature of exposure and aware of basic actions to minimise exposures; ensure suitable personal protective equipment is available; clear up spills and dispose of waste in accordance with regulatory requirements; monitor effectiveness of control measures; consider the need for health surveillance; identify and implement corrective actions. Whenever exposure is possible, wear chemically resistant gloves in combination with specific activity training. Use suitable eye protection. STATE AGENCY REVIEW This substance is registered under REACH REGULATORY INFORMATION / CLASSIFICATION AND LABELLING Labeling according CLP regulation (Regulation (EC) No. 1272/2008, as amended): Hazard pictogram: GHS07: exclamation mark GHS08: health hazard Hazard statements: H315: Causes skin irritation. H360: May damage fertility or the unborn child Signal Word: Danger Page 4 of 5
5 CONCLUSION CONTACT INFORMATION WITHIN COMPANY Clariant Produkte (Deutschland) GmbH Frankfurt am Main Telephone no. : GLOSSARY Acute toxicity: harmful effects after a single exposure Biodegradable: breakdown of materials by a physiological environment Bioaccumulation : accumulation of substances in the environment Carcinogenicity: effects causing cancer Chronic toxicity: harmful effects after repeated exposures Clastogen: a substance that causes breaks in chromosomes Embryotoxicity: harmful effects on foetal health GHS: Global Harmonized System Hazard: situation bearing a threat to health and environment Mutagenicity: effects that change genes Reprotoxicity: combining teratogenicity, embryotoxicity and harmful effects on fertility Sensitising: allergenic Teratogenic: effects on foetal morphology DATE OF ISSUE March 2014 REVISION : ADDITIONAL INFORMATION DISCLAIMER The information contained in this paper is intended as advice only and whilst the information is provided in utmost good faith and has been based on the best information currently available, is to be relied upon at the user s own risk. No representations or warranties are made with regards to its completeness or accuracy and no liability will be accepted by Clariant for damages of any nature whatsoever resulting from the use of or reliance on the information. Page 5 of 5
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