Material Safety Data Sheet

Transcription

1 Print date: 26-Sep-2008 Material Safety Data Sheet According to EC Regulation 1907/2006 Revision Number: 0 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Identification of the substance or preparation MSDS Ref. No.: Product name: A-SCSDS517 Use of the Substance/Preparation Recommended use: Company/Undertaking Identification Emergency telephone number: For use only as a home garden weedkiller. The Scotts Company (UK) Ltd, Salisbury House, Weyside Park, Catteshall Lane, Godalming, Surrey, GU7 1XE, United Kingdom ++44 (0) (24h) INFO-MSDS@Scotts.com 2. HAZARDS IDENTIFICATION Classification N - Dangerous for the environment Most important hazards Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature of the preparation Components CAS-No Weight % EC-No. Classification Methylene napthalene sulfonate % USA11 Xi,R36 Alkyl naphthalene sodium sulfonate % USA12 Xn;R22-36/37 Clay > 25% NE Glyphosate % N;R51/53 Xi;R41 Page 1 of 7

2 Components CAS-No Weight % EC-No. Classification Oxadiazon % N;R50/53 Diflufenican % R52/53 NE = Non-Established For the full text of the R phrases mentioned in this Section, see Section FIRST AID MEASURES General advice: Ingestion: Inhalation: Skin contact: Eye contact: In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If swallowed, seek medical advice immediately and show this container or label. Move to fresh air. If symptoms persist, call a physician. Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Suitable extinguishing media: Carbon dioxide (CO2). Powder. Water spray mist or foam. Unsuitable extinguishing media: High volume water jet 5. FIRE-FIGHTING MEASURES Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases: Thermal decomposition can lead to release of irritating gases and vapours. Special protective equipment for firefighters: Use personal protective equipment. Self-contained breathing apparatus and suitable protective clothing. Specific methods: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Personal precautions: Use personal protective equipment. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Do not contaminate surface water. Do not flush into surface water or sanitary sewer system. Local authorities should be advised if significant spillages cannot be contained. Methods for cleaning up: Prevent product from entering drains. Take up mechanically and collect in suitable container for disposal. Page 2 of 7

3 7. HANDLING AND STORAGE Handling: Technical measures/precautions: Safe handling advice: Storage: Technical measures/storage conditions: Incompatible products: Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Wash off splashes (immediately). Wash hands and exposed skin after use / handling. Store in original container. Keep tightly closed in a dry and cool place. Do not store half used sachets.. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. No information available 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Personal protective equipment is not normally required - gloves can be worn for personal hygiene. In case of accidental spillage of bulk product, wear personal protective equipment appropriate to the task (see below). Occupational exposure controls Personal protective equipment Respiratory protection: Hand protection: Eye/face protection Skin and body protection: Hygiene measures Effective dust mask. Protective gloves. Safety glasses with side-shields. Wear suitable protective clothing. When using, do not eat, drink or smoke. Wash hands before stopping and immediately after handling. Exposure limit values Clay Belgium - 8 Hr VLE 2 mg/m 3 TWA France INRS (VME) 10 mg/m 3 VME Portugal - TWAs 2 mg/m 3 TWA Spain - Valores Limite Ambientales - VLE 2 mg/m 3 VLA-ED UK EH40 WEL: 10 mg/m 3 9. PHYSICAL AND CHEMICAL PROPERTIES General Information Appearance: Color: Granular Light brown Page 3 of 7

4 Odor: No detectable odor Important Health Safety and Environmental Information Flash point: Solubility: Not applicable Dispersible Other information ph: 2.35 Bulk density: 0.73g/l 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Stable under recommended storage conditions. None known. None known. No decomposition if stored normally. Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Component information Clay LC50/inhalation/4h/rat = >5.6mg/l air Glyphosate Oxadiazon Diflufenican LC50/inhalation/4h/rat = > 5000 mg/kg > 2000 mg/kg > 2000 mg/kg > 2000 mg/kg > 2,34 mg/l Product information Local effects Skin effects: Eye effects: No skin irritation. No eye irritation. Page 4 of 7

5 Inhalation: Ingestion: Sensitization: No information available. No information available. No sensitization. 12. ECOLOGICAL INFORMATION Product information Aquatic toxicity: EC50/72h/algae = mg/l. Component information Clay Glyphosate Oxadiazon Diflufenican No information available EC50/algae/128h = 0.64mg/l EC50/fish = 38mg/l EC50/48h/daphnia = > 2.4mg/l LC50/96h/rainbow trout = 1.2mg/l EC50/72h/algae growth rate = mg/l EC50/48h/daphnia = >0.24mg/l LC50/96h/Fish (C.carpio) = >0.0985mg/l EC50/72h/algae = mg/l 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not empty into drains. For the UK only:. Dispose of empty container in the dustbin. Dispose of unused product in its container at a household waste site (civic amenity site). Contact your local council (local authority) for details.. For Ireland only:. Do not re-use container for any other purpose and dispose of safely. Contaminated packaging: Do not re-use container for any other purpose and dispose of safely TRANSPORT INFORMATION Product information Physical State: Solid ADR/RID Page 5 of 7

6 UN-No: 3077 Proper shipping name: Hazard Class: 9 Packing group: III IATA UN-No: 3077 Proper shipping name: Hazard Class: 9 Packing group: III IMO / IMDG Environmentally Hazardous Substance Solid N.O.S. (Glyphosate 20%w/w, Oxadiazon 20%w/w, Diflufenican 1.2%w/w) Environmentally Hazardous Substance Solid N.O.S. (Glyphosate 20%w/w, Oxadiazon 20%w/w, Diflufenican 1.2%w/w) UN-No: 3077 Proper shipping name: Environmentally Hazardous Substance Solid N.O.S. (Glyphosate 20%w/w, Oxadiazon 20%w/w, Diflufenican 1.2%w/w). Hazard Class: 9 Packing group: III EmS: F-A / S-F 15. REGULATORY INFORMATION Indication of danger: N - Dangerous for the environment. To avoid risks to man and the environment, comply with the instructions for use. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S -phrase(s) S 2 - Keep out of the reach of children. S13 - Keep away from food, drink and animal feedingstuffs. S29 - Do not empty into drains. Keep off skin. Wash off splashes (immediately). Keep in original container, tightly closed in a safe place. Do not store half used sachets Do not contaminate ponds, waterways or ditches with chemical or used container. Page 6 of 7

7 15. REGULATORY INFORMATION Registration number UK/Eire MAPP: PCS No: OTHER INFORMATION Text of R Phrases mentioned in Section 3 R22 - Harmful if swallowed. R36 - Irritating to eyes. R41 - Risk of serious damage to eyes. R36/37 - Irritating to eyes and respiratory system. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Reason for revision: *** Indicates changes since the last revision. This version replaces all previous versions Prepared by: Regulatory Affairs Department. This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product End of Safety Data Sheet Page 7 of 7