SAFETY DATA SHEET. Creation Date 23-Feb-2010 Revision Date 18-Jan-2018 Revision Number 3

Transcription

1 SAFETY DATA SHEET Creation Date 23-Feb-2010 Revision Number 3 Product Name 1. Identification Fisherbrand Traceable Conductivity Calibration Cat No. : ; ; ; ; Synonyms Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number CHEMTRECÒ, Inside the USA: CHEMTRECÒ, Outside the USA: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Kidney. Label Elements Signal Word Warning Hazard Statements Causes serious eye irritation May cause damage to organs through prolonged or repeated exposure Precautionary Statements Page 1 / 7

2 Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Response Get medical attention/advice if you feel unwell Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % Water > 90 Potassium chloride < 8 n-propyl alcohol < 2 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. Do not induce vomiting. Obtain medical attention.. Treat symptomatically 5. Fire-fighting measures Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and Page 2 / 7

3 sources of ignition. Hazardous Combustion Products Hydrogen chloride gas Chlorine Potassium oxides Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Up Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Do not breathe vapors or spray mist. Avoid contact with skin, eyes and clothing. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) n-propyl alcohol TWA: 100 ppm (Vacated) TWA: 200 ppm (Vacated) TWA: 500 mg/m 3 (Vacated) STEL: 250 ppm (Vacated) STEL: 625 mg/m 3 TWA: 200 ppm TWA: 500 mg/m 3 IDLH: 800 ppm TWA: 200 ppm TWA: 500 mg/m 3 STEL: 250 ppm STEL: 625 mg/m 3 TWA: 200 ppm TWA: 500 mg/m 3 STEL: 250 ppm STEL: 625 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if Page 3 / 7

4 exposure limits are exceeded or if irritation or other symptoms are experienced. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor Odorless Odor Threshold ph Melting Point/Range Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Soluble in water Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity 10. Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Excess heat. None known Hazardous Decomposition Products Hydrogen chloride gas, Chlorine, Potassium oxides Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information No acute toxicity information is available for this product Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Based on ATE data, the classification criteria are not met. ATE > 20 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Water - Not listed Not listed Potassium chloride LD50 = 2600 mg/kg ( Rat ) Not listed Not listed n-propyl alcohol LD50 = 1870 mg/kg ( Rat ) LD50 = 4049 mg/kg ( Rabbit ) LC50 > ppm ( Rat ) 4 h Toxicologically Synergistic Page 4 / 7

5 Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity Severe eye irritant The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Water Not listed Not listed Not listed Not listed Not listed Potassium chloride Not listed Not listed Not listed Not listed Not listed n-propyl alcohol Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Mutagenic effects have occurred in humans. Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity.... None known Kidney The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. 12. Ecological information Component Freshwater Algae Freshwater Fish Microtox Water Flea Potassium chloride EC50: 2500 mg/l/72h Lepomis macrochirus: LC50: Not listed EC50: 825 mg/l/48h 1060 mg/l /96h Pimephales promelas: LC50: mg/l /96h n-propyl alcohol Not listed Pimephales promelas: LC50=4480 mg/l 96h EC50 = mg/l 5 min EC50 = mg/l 5 h EC50 = 8686 mg/l 15 min EC50 = 980 mg/l 12 h EC50: mg/l, 48h Static (Daphnia magna) EC50: = 3642 mg/l, 48h (Daphnia magna) Persistence and Degradability Bioaccumulation/ Accumulation. Mobility. Component log Pow n-propyl alcohol Waste Disposal Methods 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a Page 5 / 7

6 hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. DOT TDG IATA IMDG/IMO 14. Transport information 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Water X X X - X X X Potassium chloride X X X X X X X n-propyl alcohol X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Water - - X - - n-propyl alcohol X X X - X U.S. Department of Transportation Page 6 / 7

7 Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 23-Feb Jan Jan-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7