Trade name: GELSEAL ULTRA SPRAY-ON Date of issue Page 1 of Total 5

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1 Trade name: GELSEAL ULTRA SPRAY-ON Date of issue Page 1 of Total 5 1. Product and Company identification. 1.1 Product name: Gelseal Ultra Spray-On 1.2 Company name: Agritrade 411 Blenheim Road Sockburn Christchurch 8041 FREEPHONE: PHONE: FAX: Emergency Telephone Numbers: 24 hour Emergency only 0800 CHEMCALL ( ) National Poisons and Hazardous Chemicals Information Centre Dunedin: Phone 0800 POISON ( ). Transport Emergency Only Dial: Hazards identification Classified by EPA as a hazardous substance according to the criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulations HSNO Hazard Classification: 6.1E: Harmful - May be harmful if swallowed, inhaled or absorbed through the skin 6.3A: Harmful - May cause skin irritation 6.4A: Harmful - May cause eye irritation. 6.5B: Harmful - May cause sensitisation from prolonged skin contact 6.8B: Harmful - May cause reproductive /development damage from repeated oral exposure. 6.9B: Harmful - May cause organ damage from repeated oral exposure at high doses. 9.1A: Very Toxic - Very toxic to fish with long lasting effects. 9.3C: Harmful - Harmful to terrestrial vertebrates Precautions: KEEP OUT OF THE REACH OF CHILDREN Avoid skin and eye contact Avoid contamination of any water supply with product or empty containers. 3 Composition/information on ingredients Contents CAS Number Concentration % Tebuconazole < 41.0 Boric acid < 2.0 Octhilinone < 5.0 Glycerine < 3.0 Propylene glycol < 1.5 Non hazardous excipients < 10.0 Water To 100

2 Page 2 of Total 5 4. First aid measures 4.1 Eye contact: Immediately rinse eyes with running water for at least 15 minutes. Remove contact lenses if present after the first 5 minutes. Get medical attention if irritation develops and persists. 4.2 Skin contact: Remove contaminated clothing. Wash affected area thoroughly with soap and Water. If symptoms persist call a doctor. 4.3 If inhaled: If spray mist is inhaled, remove from exposure to fresh air. 4.4 Ingestion: DO NOT INDUCE VOMITING. Seek medical attention. If conscious, give 3-4 glasses of water to dilute stomach contents. 5. Fire fighting measures 5.1 Extinguishing media: Water, water fog, CO2, foam or dry extinguisher. 5.2 Special Fire Fighting Procedures: This product is not flammable (Water based). 5.3 Combustion products: CO2 and water. In case of incomplete combustion, carbon monoxide, hydrocarbons, aldehydes, ketones and acetic acid may be developed. 6. Accidental release measures 6.1 Spills: Wear appropriate protective equipment and respirator where mists or vapours of unknown concentrations may be generated. Large amounts: Do not allow the product to enter drains, sewers or waterways. Remove leaking containers to a detached area. Bund spill area and absorb spilled product with inert material (e.g. sand, earth etc.) Small amounts: Wash away with plenty of water or allow to dry and scrape off dried film. 6.2 Disposal: Dispose of waste in accordance with local authority bylaws. 6.3 Cleaning of Equipment: Clean with water.

3 Page 3 of Total 5 7. Handling and storage 7.1 Handling: No special measures required to prevent fire and explosion. Avoid eye contact. As a precaution, wear chemical type goggles or safety glasses. Wear PVC gloves and protective clothing. 7.2 Storage: Store in original container, tightly closed in a locked dry, cool, well ventilated area away from foodstuffs, feeds, seeds, fertilisers, insecticides, or fungicides used for the protection of crops. Avoid the contamination of drinking water. 8. Exposure controls/personal protection 8.1 Exposure Standards: Glycerine mist: Workplace exposure standard (WES) - 10 mg/m Ventilation: In a situation where vapours may be generated, proper ventilation must be provided in accordance with good ventilation practices. 8.3 Personal protective equipment: Eye protection: Safety glasses/ goggles Hand protection: PVC gloves Skin and body protection: Protective clothing, PVC apron and boots. 9. Physical and chemical properties Appearance (Form): Liquid Colour: White Formulation Type: Suspension Concentrate (SC) Flash point (ºC): Not flammable Specific Gravity: 1.1 Solubility in water: Dispersible ph: Stability and reactivity 10.1 Stability: Stable under normal operating conditions Materials to avoid: Strong oxidising/reducing agents Hazardous decomposition products: Carbon monoxide, hydrocarbons, aldehydes, ketones and acetic acid Dangerous reactions: None.

4 Page 4 of Total Toxicological information 11.1 Health Effects: Toxic if swallowed. Eye: Severe irritant Octhilinone active ingredient is an eye irritant of rabbit (Strong caustic effect) Skin: Irritant. Sensitising may occur from prolonged contact (Octhilinone active ingredient has a caustic effect on skin and mucous membranes Acute oral toxicity: Tebuconazole technical - Acute oral LD50 (rat male): 4000 mg/kg Octhilinone Acticide formulation - Acute oral LD50 (rat): 279 mg/kg 11.3 Acute dermal toxicity: Tebuconazole technical - Acute percutaneous LD50 (rat): > 5000 mg/kg Octhilinone Acticide formulation - Acute dermal LD50 (rat): > 2000 mg/kg 12. Ecological Information 12.1 Ecotoxicity: Toxic to aquatic life with long lasting effects. Do not release into the environment Persistence/degradability: Tebuconazole Technical DT50 (anaerobic): 866days. DT50 (aerobic): 1386 days 12.3 Aquatic toxicity: Based on Octhilinone Acticide formulation:l Rainbow trout: LC50 (96 hour) 0.03 mg/l Daphnia: LC50 (48 hour) 0.42 mg/l Algae (Scenedesmus subspicatus): EC50 (72 hour) mg/litre Based on Tebuconazole Technical material Rainbow trout: LC50 (96 hour) 4,4 mg /litre (a.i.) Bluegill sunfish: LC50 (96 hour) 5.7 mg/litre (a.i.) Daphnia: LC50 (48 hour) 4.2 mg/litre (a.i.) Algae (Scenedesmus subspicatus): EC50 (96 hour) 4.01 mg/litre (a.i.) 12.3 Avian toxicity: Gelseal Ultra Spray-On is a vertebrate ecotoxicant (9.3C) Tebuconazole Technical: Acute oral LD50 Bobwhite Quail: 1988 mg/kg 13. Disposal considerations Dispose of waste in accordance with local authority bylaws. Disposal of empty container: Crush container and land fill or Triple rinse then send to a recycling facility.

5 Page 5 of Total Transport regulations Dangerous Goods Class: UN No: Correct Shipping Name: HAZCHEM: Packing Group: 9 (9.1A) UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S (Tebuconazole 430g/l, Octhilinone 20.0g/l) MARINE POLLUTANT 2X III 15. Regulatory information HSNO Approval No: HSR Hazardous Property Classification: 6.1E, 6.3A, 6.4A, 6.5B, 6.8B, 6.9B, 9.1A, 9.3C. HSNO Controls: See Registered pursuant to the ACVM Act 1997 No. P9046 See: for registration conditions 16. Other information 16.1 Abbreviations: HSNO: EPA: CAS Number: LD50: LC50: EC50: Hazardous substances and New Organisms Act 1996 (HSNO Act) Environmental Protection Authority of Chemical Abstracts Service Number Lethal Dose 50% (Population) Lethal Concentration 50% (Population) Effective Concentration 50% (Population) 16.2 General: Gelseal Ultra Spray-On is a horticultural fungicide for the control of Eutypa dieback in grape vines. Use only as directed on the label This SDS supersedes all previous issues. It summarises our best knowledge of the health and safety hazard information of the product. All users should read this SDS and consider the information in the context of how the product will be handled and used in the workplace, including in conjunction with other products. Since the actual use of this product is beyond the control of Omnia, we make no warranty, expressed or implied, concerning the use of this product. It is the responsibility of users to ascertain that the product is suitable for intended applications. Last page