: LPF100A Iodine Vaporizer Crystals

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance name Product code : Substance : : LPF100A 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet : Latent fingerprint developer SIRCHIE Finger Print Laboratories 100 Hunter Place Youngsville, NC USA T ; F ; Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Dermal) H312 Acute Tox. 4 (Inhalation:dust,mist) H332 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H312+H332 - Harmful in contact with skin or if inhaled : P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, protective gloves P302+P352 - If on skin: Wash with plenty of water/ P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P312 - Call a poison center/doctor/ if you feel unwell P321 - Specific treatment (see a physician on this label) P362+P364 - Take off contaminated clothing and wash it before reuse P501 - Dispose of contents/container to local, regional,national, international regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance Name : 08/30/2015 EN (English US) Page 1

2 Name Product identifier % Classification (GHS-US) iodine (CAS No) Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Full text of H-phrases: see section Mixture SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity 5.3. Advice for firefighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures : On burning: release of harmful/irritant gases/vapours (iodine) Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures 6.2. Environmental precautions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 08/30/2015 EN (English US) 2/1

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. ACGIH ACGIH TWA (mg/m³) 1 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ ACGIH ACGIH TWA (ppm) 0.01 ppm ACGIH ACGIH STEL (ppm) 0.01 ppm OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Gas mask. Gloves. Safety glasses. Hand protection Eye protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C : Solid : Crystalline powder. : Metallic violet-black : Irritating/pungent odour Solubility : Water: Solubility in water of component(s) of the mixture : : 0.03 g/100ml Log Pow 08/30/2015 EN (English US) 3/1

4 Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. SECTION 10: Stability and reactivity Reactivity On burning: release of harmful/irritant gases/vapours (iodine) Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ATE US (dermal) ATE US (dust, mist) ATE US (dermal) ATE US (gases) ATE US (vapors) ATE US (dust, mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : Dermal: Harmful in contact with skin. Inhalation:dust,mist: Harmful if inhaled mg/kg body weight mg/l/4h mg/kg body weight ppmv/4h mg/l/4h mg/l/4h Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. 08/30/2015 EN (English US) 4/1

5 SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Threshold limit algae Persistence and degradability Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) mg/l (96 h; Carassius auratus) 71 mg/l (48 h; Daphnia magna; QSAR) 0.44 mg/l (24 h; Ictalurus punctatus) 48 mg/l (72 h; Algae) Biodegradability: not applicable Bioaccumulative potential Bioaccumulative potential BCF other aquatic organisms (Ophiuroidea; Dry weight) Log Pow 2.49 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Proper Shipping Name (DOT) Department of Transportation (DOT) Hazard Classes Hazard labels (DOT) : Corrosive solid, n.o.s. (Iodine) CORROSIVE : 8 - Class 8 - Corrosive material 49 CFR : 8 - Corrosive Packing group (DOT) : III - Minor Danger 08/30/2015 EN (English US) 5/1

6 Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Dermal) H312 Acute Tox. 4 (Inhalation:dust,mist) H332 Aquatic Acute 1 H400 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xn; R20/21 N; R50 Full text of R-phrases: see section 16 National regulations US State regulations SECTION 16: Indication of changes : Revision - See : *. Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H-phrases: Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category H312 Harmful in contact with skin H332 Harmful if inhaled SDS US (GHS HazCom 2012) The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their particular purposes. 08/30/2015 EN (English US) 6/1