GORE Sealant Technologies for Chlor-Alkali Applications Rick Freer / Marcos Gomes November 13, 2014
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1 GORE Sealant Technologies for Chlor-Alkali Applications Rick Freer / Marcos Gomes November 13, 2014 GORE and designs are trademarks of W.L. Gore & Associates. Copyright 2014 W.L. Gore & Associates, Inc.
2 Contents Introduction to W. L. Gore & Associates What is PTFE & eptfe? GORE Sealant Technologies Case Histories Value in Chlor-Alkali Applications
3 W. L. Gore & Associates Founded in 1958 Privately held $3 billion in sales 10,000+ associates Recognized as a Best Company to Work For 2010 W. L. Gore & Associates, Inc.
4 An Enterprise Organized Around Four Divisions Industrial Products Electronic Products Medical Products Fabrics
5 W. L. Gore & Associates Worldwide Locations 2010 W. L. Gore & Associates, Inc.
6 Contents Introduction to W. L. Gore & Associates What is PTFE & eptfe? GORE Sealant Technologies Case Histories Value in Chlor-Alkali Applications
7 Polymerization of Tetrafluoroethylene PTFE is produced by polymerization of a C 2 F 4 (tetrafluoroethylene) monomer to produce a very long chain macro molecule. The Carbon-Fluorine chemical bond is the strongest known producing superior protection against chemical attack.
8 Properties of PTFE Advantages Chemically inert to almost all media (ph 0-14) Wide range of thermal resistance Non-aging, weather and UV resistant Low coefficient of friction Physiologically harmless Wide application versatility Disadvantage Mechanically weak
9 3 Generations of PTFE Address Mechanical Weakness of PTFE Expanded PTFE Filled PTFE Virgin PTFE
10 Gasket Performance Benefits of eptfe Superior Reliability of GORE Gaskets: Standardization Cost Savings Safety Tight-Sealing Corrosion Protection Minimize Leaks Outstanding Creep Long-Term Reliable Seal Resistance
11 Standardize Across Flanges Common Gaskets Flange material Cl 2 NaOH H 2 SO 4 Chlorine Path Titanium Stainles Steel FRP Carbon Steel (Dry Cl2) Caustic Soda (Evaporation) Carbon Steel Stainless Steel Metal Alloys Nickel SAC (Cl2 Drying) FRP PTFE-Lined Steel GLS Cell Room, Bath, Electrolizers Titanium FRP BRINE Brine FRP Carbon Steel Metal Reinforced X X Filled PTFE X X X X Metal X EPDM X X X Envelopes X High Corrosion X X X Corrosion that leads to potential downtime X X X X Problems with Common Gaskets Danger of Emissions X X Seal may not be able to reliably meet Continuous Production Demands Creep due to Thermal Cycles & High Temperatures X X X X X Applications for GORE Gasketing Rubber Compression Set & Degradation Piping Large Diameter Applications GORE Series 500 Gasket Tape X X X GORE Universal Pipe Gasket (Style 800)
12 Tight-Sealing Leak Rate after Aging 3 rd party test Legend: ARLA, 3.2mm (1/8 ) sheet thickness Initial Gasket Stress: 43.5 MPa (5000 psi) Initial Pressure: 55 bar (800 psi) Aging Conditions: 96 hours at 315 C (600 F) Note: Third party testing validates approximately 100,000 times less emission for GORE UPG sheet gasketing.
13 Outstanding Creep Resistance Difference amongst leading PTFE options revealed by simple test 34.5MPa (5000 psi), 230 C (446 F), 15 minutes After Before % Larger 4% 34% 69% 54% 75% GORE GR Sheet Gasketing Filled (silica) Filled (glass microspheres) Filled (barium sulphate) Microcellular
14 Contents Introduction to W. L. Gore & Associates What is PTFE & eptfe? GORE Sealant Technologies Case Histories Value in Chlor-Alkali Applications
15 GORE Universal Pipe Gasket (Style 800) Standardize across process piping
16 GORE Series 500 Gasket Tape Saves You Time, Money and Trouble Fits any shape instantly & reliably
17 Contents Introduction to W. L. Gore & Associates What is PTFE & eptfe? GORE Sealant Technologies Case Histories Value in Chlor-Alkali Applications
18 Case Study 1 FRP Process Piping Plant Flanges Pressure: Temperature: Previous Gasket Application Media Chlor-alkali manufacturer FRP Standard ANSI pipe sizes 10 bar (150 PSI) Maximum 49 C (120 F) Maximum EPDM, EPDM w/ PTFE envelope, Viton Process Piping Chlorine, Caustic Soda Solution: GORE Universal Pipe Gasket (Style 800) provide chemical compatibility of 100% PTFE with low stress to seal characteristics. Ultimately, the goal is to standardize on gasket reducing the need for multiple gaskets in these applications. Customer has specified GORE Universal Pipe Gasket (Style 800) successfully for over 4 years.
19 Case Study 2 Heat Exchanger-Wet Chlorine Diameter: Pressure: Temperature: Previous Gasket: Problem: 1067 mm (42 ID) 0,7 bar (10 PSIG) 85 C (185 F) Filled PTFE Repeated Leakage Solution: GORE Series Gasket Tape, is available on a spool, the user customizes a gasket in place on the flange in minutes, with minimal manpower. The application recommendation was 6,35 mm (¼ ) thick x 25,4 mm (1 ) wide with a torque of 170 Nm (125 ft-lbs). The tape form can eliminate unnecessary downtime while waiting for custom-produced gaskets done offsite. The adhesive backing holds the gasket in place securely for a quicker and safer installation.
20 Contents Introduction to W. L. Gore & Associates What is PTFE & eptfe? GORE Sealant Technologies Case Histories Value in Chlor-Alkali Applications
21 Value in Chlor-Alkali Applications Maximizing Performance & Safety Premium Performing Products Training Application & Installation Assistance Established Track Record of Performance in Chlor-Alkali Applications SEAL-18-R1-PRS-US-FEB12
22 OBRIGADO THANK YOU GORE and designs are trademarks of W.L. Gore & Associates. Copyright 2014 W.L. Gore & Associates, Inc.
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