SAFETY DATA SHEET NEWV 1 PACK SILVER

Transcription

1 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER R PRINTING INK STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : ( Mon- Fri 24 hrs) Fax : sds@stehlin.co.uk 2 HAZARDS IDENTIFICATION Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1999/45) R52/53. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification (67/548) 2-benzyl-2-dimethylamino-4-morpholinobutyro phenone 2-phenoxy ethyl acrylate <5% <5% N;R50/53. Xi;R36/37/38. Aluminium < 50 F;R15. R10. Glycerol Propoxy Triacrylate <5% Xi;R36. The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Supply fresh air; consult doctor in case of complaints INGESTION If symptoms persist, seek medical advice. SKIN CONTACT Wash immediately with plenty of water and soap and rinse thoroughly. EYE CONTACT Rinse opened eye for several mintues under running water 5 FIRE-FIGHTING MEASURES 1 / 4

2 EXTINGUISHING MEDIA Co2, sand, extinguishing powder. Do not use water. Use fire extinguising methods suitable to surrounding conditions. For safety reasons unsuitable extinguishing media: Water PROTECTIVE MEASURES IN FIRE Do not inhale explosion gases or combustion gases 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. Remove people from danger area. Keep unprotected people away ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS Absorb with liquid binding material such as sand, vermiculite, sawdust etc. Ensure good ventilation Do not flush with water or aqueous cleansing agens 7 HANDLING AND STORAGE STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Aluminium Std WEL TWA - 8 hrs 10 inhalable, 4 respirable mg/m3 STEL - 15 min Notes WEL = Workplace Exposure Limit. RESPIRATORY EQUIPMENT In case of inadequate ventilation use suitable respirator. HAND PROTECTION Solvent resistant gloves recommended. Preventative skin protection by use of skin protecting agents is recommended. Prior contacts with water insoluble substance / product / preparation apply water soluble skin protecting agent (fat-free film former or O/W emulsions). The selection of suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. The exact breaktrhough time has to be found out by the manufacturer of the protective gloves and has to be observed. EYE PROTECTION Wear approved safety goggles. HYGIENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. SKIN PROTECTION Protective clothing should be worn. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR SOLUBILITY BOILING POINT ( C) Fluid According to product specification Characteristic Not miscible or difficult to mix with water 2467 DEGREES C 2 / 4

3 FLASH POINT ( C) AUTO IGNITION TEMPERATURE ( C) 101 degrees C 600 DEGREES C 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. MATERIALS TO AVOID Reacts with acids, alkalis and oxidising agents HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide (CO). Carbon dioxide (CO2). 11 TOXICOLOGICAL INFORMATION SKIN CONTACT No irritating effect Not a skin sensitiser. EYE CONTACT No irritating effect 12 ECOLOGICAL INFORMATION ECOTOXICITY Harmful to fish and aquatic organisms. WATER HAZARD CLASSIFICATION Water hazard class 1 (German Regulation) (Self Assessment): Slightly hazardous for water. Do not allow product to reach ground water, water course or sewage system. Harmful to aquatic organisms. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION The user's attention is drawn to the possible existence of regional or national regulations regarding disposal DISPOSAL METHODS Must not be disposed of together with household garbage. Do not allow product to reach sewage system. WASTE CLASS waste ink containing hazardous substances 14 TRANSPORT INFORMATION GENERAL Not dangerous according to the above specification 15 REGULATORY INFORMATION RISK PHRASES SAFETY PHRASES EU DIRECTIVES R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S7/8 Keep container tightly closed and dry. S43 In case of fire, use alcohol-resistant foam, carbon dioxide or dry powder. Never use water. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. This product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Observe the general safety regulations when handling chemicals. 3 / 4

4 16 OTHER INFORMATION REVISION COMMENTS This is first issue. ISSUED BY B.A Hayden HSQE Manager SDS NO SAFETY DATA SHEET STATUS Approved. DATE 07/10/10 RISK PHRASES IN FULL R10 R15 R36 R36/37/38 R50/53 Flammable. Contact with water liberates extremely flammable gases. Irritating to eyes. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 4 / 4

5 Technical Information E UV-curing inks and varnishes NewV UV-metal-pigmented inks Metal-pigmented, 2-component inks contain additives that help to stabilise the metallic surface and prevent it from -oxi dising and are therefore necessary to ensure the metallic lustre is maintained. These substances have negative effects on UV-resistant roller coverings and rubber blanket materials (e.g. EPDM) and cause swelling. This results in printing problems in the production run caused by apparent piling on the ink roller coverings when working with such types of ink. Roller coverings such as those used for alternating between conventional and UV processing are suitable for use with metal-pigmented UV inks. If the rollers you use are made of pure EPDM, we can also supply you with 1-component UV gold and silver ink systems. Depending on the substrate, however, the metallic effect produced by the 1-component UV gold inks may be slightly less metallic, but all other application-related aspects apply equally to both systems. When printing UV-curing bronze inks wet-on-wet, copper precipitation may occur on the printing plates of downstream printing units. This leads to the copper pigments of the bronze inks being applied together with the actual ink to be applied from these units and consequently to scumming. This can be remedied by using imitation gold inks based on ground aluminium powder or by printing bronze ink from the last printing unit. To obtain a perfect metallic effect, the ph should be no lower than 5.5. The printing characteristics of UV metallic inks can be made more stable by adding a mixture consisting of tap water and 8 10% isopropyl alcohol (without adding a fount solution additive). Mixtures of metal pastes and UV-curing varnishes tend to polymerise (cure) very quickly. For this reason, both should only be mixed immediately prior to being printed on the press. Mixing with pigmented UV inks can greatly shorten the amount of time available for applying the mixed metallic ink. Range of applications The 2-component, metal-pigmented inks are suitable for: Coated and uncoated papers and card stocks Pretreated (corona or gas flame) or preprimed, non-absorbent substrates such as PE, PVC, PS, PP, etc. Aluminium-vaporised board and paper Aluminium foils The 1-component, metal-pigmented inks are suitable solely for printing coated and uncoated papers and card stocks. * Postprint finishing The best metallic effect is obtained on coated stocks that have a uniform, smooth surface, because the metallic effect can not be enhanced by means of excessive inking. As a rule, this simply leads to printing problems such as piling, poor curing and insufficient smudge resistance. One rule that has proven useful, especially in solid image areas, is not to print silver ink from the last unit. Smoothing the print with an additional rubber blanket, without UV inter-station drying, helps to enhance coating quality. Adhesion problems arise very frequently during postprint finishing of metal-pigmented offset prints. Technical Information. hubergroup _NewV_UV_metallpigmentierte_Farben. Page 1/2

6 In this case, we recommend you carry out a pre-production test (to test adhesion and scratch resistance). Following UV curing, UV metallic inks are suitable for inline or offline UV varnishing. Application of a UV varnish or lamina - tion, however, greatly reduces the metallic effect. If the print is to be laminated, you must always carry out tests prior to beginning the print run. Prints made with UV metallic inks (and not varnished) are not suitable for products to be glued, for blister packs, hot foil stampings, etc. Product overview 2-component system How supplied Silver (2-component system) UV Silver Paste 46 U ,3 kg UV Varnish for Silver Mixture ratio: 30% paste: 70% varnish 40 U ,7 kg Bronze (2-component system) UV Rich Pale Gold Paste (per PANTONE 873) 46 U ,4 kg UV Rich Gold Paste (per PANTONE 871) 46 U ,4 kg UV Pale Gold Paste (per PANTONE 874) 46 U ,4 kg UV Varnish for Bronze Inks Mixture ratio: 40 % paste: 60 % varnish 40 U ,6 kg Copper (2-component system) UV Copper Paste 46 U ,4 kg UV Varnish for Copper Mixture ratio: 40 % paste: 60 % varnish 40 U ,6 kg 1-component system How supplied UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Gold per PANTONE R 1,0 kg UV 1-comp. Silver per PANTONE R 1,0 kg Classification Safety Data Sheet available on request. Shelf life At least 12 months for 2-component systems or 6 months for 1-component systems when stored under the correct conditions (20 C, protected against heat and light). Contact addresses for advice and further information can be found under This Technical Information sheet reflects the current state of our knowledge. It is designed to inform and advise. We assume no liability for correctness. Modifications may be made in the interest of technical improvement. Technical Information. hubergroup _NewV_UV_metallpigmentierte_Farben. Page 2/2