SAFETY DATA SHEET. Creation Date 04-Feb-2010 Revision Date 24-May-2017 Revision Number 6

Transcription

1 SAFETY DATA SHEET Creation Date 04-Feb-2010 Revision Number 6 Product Name 1. Identification Ferrous chloride tetrahydrate Cat No. : I Synonyms Recommended Use Uses advised against Iron(II) chloride tetrahydrate; Ferrous protochloride (Crystalline/Certified) Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number CHEMTRECÒ, Inside the USA: CHEMTRECÒ, Outside the USA: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute oral toxicity Category 4 Skin Corrosion/irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system. Label Elements Signal Word Danger Hazard Statements Harmful if swallowed Causes severe skin burns and eye damage May cause respiratory irritation Page 1 / 8

2 Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Use only outdoors or in a well-ventilated area Response Immediately call a POISON CENTER or doctor/physician Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Ingestion Rinse mouth Do NOT induce vomiting Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition / information on ingredients Component CAS-No Weight % Iron (II) chloride, tetrahydrate >95 Ferrous chloride First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately. Move to fresh air. If not breathing, give artificial respiration. Call a physician or Poison Control Center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. Do not induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation Page 2 / 8

3 Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Treat symptomatically 5. Fire-fighting measures CO 2, dry chemical, dry sand, alcohol-resistant foam. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical The product causes burns of eyes, skin and mucous membranes. Hazardous Combustion Products Hydrogen chloride gas Thermal decomposition can lead to release of irritating gases and vapors Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA Health 3 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing. Should not be released into the environment. Do not allow material to contaminate ground water system. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust Up formation. Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. 8. Exposure controls / personal protection Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Iron (II) chloride, tetrahydrate TWA: 1 mg/m 3 (Vacated) TWA: 1 mg/m 3 TWA: 1 mg/m 3 TWA: 1 mg/m 3 STEL: 2 mg/m 3 Ferrous chloride TWA: 1 mg/m 3 (Vacated) TWA: 1 mg/m 3 TWA: 1 mg/m 3 TWA: 1 mg/m 3 STEL: 2 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration Page 3 / 8

4 NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Tightly fitting safety goggles. Face-shield. Long sleeved clothing. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Solid Appearance Light green Odor Odorless Odor Threshold ph g/L aq sol (20 C) Melting Point/Range C / F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Soluble in water Alcohol Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature >150 C Viscosity Molecular Formula Cl2 Fe. 4 H2 O Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Incompatible products. Excess heat. Strong oxidizing agents Hazardous Decomposition Products Hydrogen chloride gas, Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization Hazardous polymerization does not occur. Page 4 / 8

5 Hazardous Reactions Acute Toxicity None under normal processing. 11. Toxicological information Product Information Oral LD50 Category 4. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Iron (II) chloride, tetrahydrate ATE LD50 = 705 mg/kg Not listed Not listed Ferrous chloride LD50 = 450 mg/kg ( Rat ) Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity Causes burns by all exposure routes The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Iron (II) chloride, Not listed Not listed Not listed Not listed Not listed tetrahydrate Ferrous chloride Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard... Respiratory system None known Symptoms / effects,both acute and delayed Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. The toxicological properties have not been fully investigated. 12. Ecological information Component Freshwater Algae Freshwater Fish Microtox Water Flea Ferrous chloride Not listed LC50: = 4 mg/l, 96h static Not listed Not listed (Morone saxatilis) Persistence and Degradability Bioaccumulation/ Accumulation Mobility Soluble in water Persistence is unlikely based on information available.. Will likely be mobile in the environment due to its water solubility. Page 5 / 8

6 Waste Disposal Methods 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Proper technical name Iron (II) chloride, tetrahydrate Hazard Class 8 Packing Group II TDG UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Hazard Class 8 Packing Group II IATA UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Hazard Class 8 Packing Group II IMDG/IMO UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Hazard Class 8 Packing Group II 15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Iron (II) chloride, tetrahydrate X X X X - Ferrous chloride X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories Page 6 / 8

7 Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No CWA (Clean Water Act) Component CWA - Hazardous CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants Substances Quantities Ferrous chloride X 100 lb - - Clean Air Act OSHA Occupational Safety and Health Administration CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Ferrous chloride 100 lb - California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Iron (II) chloride, X tetrahydrate Ferrous chloride X X X - X U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant Y N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 04-Feb May May-2017 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information Page 7 / 8

8 relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 8 / 8