Typical Characteristics Appearance transparent, viscous liquid Specific gravity at 25 C 0.89 g/cm 3. Solvents 1-Propanol 21% n-propyl acetate 44%

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1 Printing & Packaging Technical Data Sheet Versamid PUR Product Description Versamid PUR is a thermoplastic polyurethane resin for flexographic printing ink applications. Key Features & Benefits Chemical Composition - Excellent cohesion, flexibility and adhesion to a variety of films - Excellent solvent release - Good pigment dispersion capability Thermoplastic polyurethane resin in an alcohol/acetate solution blend Properties Product Specifications Solids Viscosity at 25 C 500 1,150 cps Gardner color 1 2 max Typical Characteristics Appearance transparent, viscous liquid Specific gravity at 25 C 0.89 g/cm 3 Solvents 1-Propanol 21 n-propyl acetate 44 1 Gardner Holdt Color at 35 total non-volatiles (TNV) as supplied. These typical values should not be interpreted as specifications. Applications Versamid PUR is a 35 solids solution in a solvent blend of n-propanol and n-propyl acetate. Versamid PUR is a film former that is soluble in a variety of alcohols and co-solvent (alcohol and hydrocarbon) systems for use in flexographic or gravure lamination inks. Since it is completely dilutable in alcohol, a finished ink can be formulated that will not swell flexographic printing plates. Versamid PUR can be formulated into inks that provide excellent cohesion, flexibility and adhesion to various polyolefin, polyester, polymer coated and metalized films. s formulated with Versamid PUR exhibit excellent adhesive and cohesive strength in both adhesive and extrusion laminates. In addition, it has sufficient block resistance to be used as a surface printing ink vehicle. Versamid PUR is recommended for applications such as: Printing inks for flexographic or gravure applications July 2014 Rev 3 Page 1 of 5

2 Formulations White Formula Materials n-propanol Iso-propanol Versamid PUR 23.9g 23.9g TiO g 41.5g n-propanol 20.8g 0g Iso-propanol 0g 20.8g Add 30g of 4mm glass beads and grind for 30 minutes on paint shaker, measure grind viscosity then add: 27 Seconds (Zahn #3) 24 seconds (Zahn #3) n-propanol 13.8g 0g Iso-propanol 0g 13.8g Total 100.0g 100.0g Formulation attributes Pigment: Binder ratio 5.0:1 5.0:1 Solids as printed Viscosity (Zahn #2) 22 seconds 23 seconds Blue Formula Materials n-propanol Iso-propanol Versamid PUR 39.8g 39.8g Sunfast 2 Blue g 12.4g n-propanol 12.4g 0g Iso-propanol g Add 30g of 4mm glass beads and grind for 60 minutes on paint shaker, measure grind viscosity then add: 42 Seconds (Zahn #X) 43 seconds (Zahn #X) n-propanol 35.4g 0g Iso-propanol 0g 37.8g Total 100.0g 102.4g Formulation attributes Pigment:Binder ratio 1.0: :1.1 Solids as printed Viscosity (Zahn #2) 23 seconds 22 seconds Versamid PUR and Co-resin Compatibility Solids Ratio (Urethane:Co-Resin) Co-Resin 4:1 1:1 Poly(vinylbutyral) C C Cellulose acetate butyrate C C Cellulose acetate propionate I I Polyketone C C Fumaric modified rosin ester (20 in n-propanol) C C Versamid 757 (35 in n-propanol) I PC (slightly hazy) Versamid 759 (35 in n-propanol) C C Versamid 963 (20 in n-propanol) I I Versamid 973 (20 in n-propanol) I I Nitrocellulose PC^ PC^ Key: C = compatible, I = incompatible, PC = partially compatible ^Solution was compatible and completely clear but discolored and showed limited viscosity increase. Versamid PUR and Additive Compatibility Additive Solids Ratio (Urethane:Additive) Result Polyethylenimine 98:2 I Titanate 98:2 C Resinous gum 95:5 I Silanes 98:2 C Polyaziridine 95:5 C ed isocyanate 92:8 C Melamine 95:5 C Key: C = compatible, I = incompatible, PC = partially compatible Testing Parameters s were printed with a 165 Q anilox handproofer on polyester and polypropylene, PVDC coated polyester and nylon films. The adhesive was applied with a K-coater 3 using a #2 bar to achieve a coating weight of lb/ream. The adhesives were Adcote and Adcote A/B. July 2014 Rev 3 Page 2 of 5

3 The films were laminated to PE film (back sheet) using a card laminator at 175 F (79 C) for adhesive lamination and at 325 F (163 C) for extrusion lamination where films were laminated to PE film (back sheet) without any adhesive application. strengths were measured on a Thwing Albert 5 Model #225-1 Friction/Peel Tester operating in the 90 T-peel mode. Measurements were made after aging laminates for 3 days; FT = film tear. resistance was measured face-to-face and face-to-back at 50 C with 10 psi for 16 hours. Samples were given a numerical rating: 10 = best, no blocking 0 = worst, complete blocking The percent decal was rated as a : 100 = ink completely separated from substrate 50 = ink split, ink layer cohesive failure 0 = ink did not separate from substrate Polyester results Blue Versamid PUR PUR coverage Polypropylene results Blue Versamid PUR PUR coverage PVDC coated polyester results Blue Versamid PUR PUR coverage Adcote FT, > Adcote A/B FT, > Extrusion Adcote FT, > Adcote A/B Extrusion Adcote Adcote A/B Extrusion FT, > Adcote FT, > Adcote A/B FT, > Extrusion Adcote Adcote A/B Extrusion Adcote Adcote A/B Extrusion Adcote Adcote A/B FT, > Extrusion Adcote FT, > Adcote A/B FT, > Extrusion Adcote FT, > Adcote A/B Extrusion ² Registered trademark of Sun Chemical Company. 3 Registered trademark of RK PrintCoat Instruments Ltd. 4 Trademark of Dow Chemical Company. 5 Registered trademark of Thwing Albert Instrument Company. July 2014 Rev 3 Page 3 of 5

4 Nylon results Blue Versamid PUR PUR coverage Adcote Adcote A/B Extrusion Adcote Adcote A/B Extrusion Adcote Adcote A/B Extrusion Safety General The usual safety precautions when handling chemicals must be observed. These include the measures described in Federal, State, and Local health and safety regulations, thorough ventilation of the workplace, good skin care, and wearing of protective goggles. Material Safety Data Sheet All safety information is provided in the Material Safety Data Sheet for Versamid PUR. Storage Versamid PUR is supplied in solution form for ease of handling. Properly stored and protected, an unopened container of Versamid PUR should have a shelf life of at least one year. Use proper loading and grounding procedures when handling near flammable materials. Important While the descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, they are provided for guidance only. Because many factors may affect processing or application/use, BASF recommends that the reader make tests to determine the suitability of a product for a particular purpose prior to use. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESCRIPTIONS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. In no case shall the descriptions, information, data or designs provided be considered a part of BASF's terms and conditions of sale. Further, the descriptions, designs, data, and information furnished by BASF hereunder are given gratis and BASF assumes no obligation or liability for the descriptions, designs, data or information given or results obtained all such being given and accepted at the reader's risk. Versamid is a registered trademark of BASF Group. BASF Corporation, 2014 July 2014 Rev 3 Page 4 of 5

5 BASF Corporation is fully committed to the Responsible Care initiative in the USA, Canada, and Mexico. For more information on Responsible Care goto: U.S.: Canada: México: U.S & Canada Mexico BASF Corporation BASF Mexicana, S.A. de C.V W Eleven Mile Road Av. Insurgentes Sur # 975 Southfield, MI Col. Ciudad de los Deportes ph: 1(800) C.P fax:1(800) Mexico, D.F. Custserv_charlotte@basf.com Phone: (52-55) edtech_info@basf.com Fax: (52-55) July 2014 Rev 3 Page 5 of 5

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