Task II Solar Chemistry Research OA Report

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SolarPACES ExCo Meeting Marrakech, Morocco, September 9, 2012 Task II Solar Chemistry Research OA Report Anton Meier

Task Activities Purpose The primary purpose of Task II (Solar Chemistry Research) is to develop and optimize solar-driven thermo-chemical processes for the production of fuels and materials and demonstrate at an industrial scale their technical and economic feasibility Task II Activities reflect the future challenges and foster active participation of SolarPACES member countries 2

Task Activities Activity 1: Solar Fuels (SF) Near-term: Demonstrate at pilot scale most advanced processes for solar production of synthetic fuels (e.g., cracking or steam reforming of NG, gasification of carbonaceous materials, carbo-thermal reduction of metal oxides) Long-tem: Scale up solar reactor technology of promising two-step H 2 O/CO 2 -splitting processes for H 2 and syngas production (e.g., Zn/ZnO & ferrite cycles) CO 2 H 2 O Solar Thermochemical Cycle long-term Concentrated Solar Energy Solar Thermochemical Gasification Solar Fuels (e.g. H 2, syngas, liquid fuels) Carbonaceous feedstock short/mid-term 3

Task Activities Near-term: Solar production of syngas (H 2 and CO) Pilot plants have been built in the power range of 200-500 kw th Steam reforming of Steam gasification of natural gas / methane carbonaceous feedstock SOLGAS (200 kw th ) SOLREF (400 kw th ) SYNPET (500 kw th ) SOLSYN (250 KW th ) 4

Task Activities Long-term: Solar production of H 2 and syngas Metal oxide based thermo-chemical processes for H 2 and syngas production have been scaled up to the 100 kw th power level, e.g.: H 2 production using Ferrite H 2 O-splitting cycle H 2 /CO (syngas) production using Zn/ZnO H 2 O/CO 2 -splitting cycle HYDROSOL (100 kw th ) at PSA, Spain Solar2Zinc (100 kw th ) at Odeillo, France 5

Task Activities Activity 2: Solar Materials (SM) Process chemical commodities using concentrated sunlight (e.g., aluminum production; EU project ENEXAL) Activity 3: Thermo-chemical Storage (TS) Develop novel thermo-chemical storage systems (e.g., EU project TCSPower) Activity 4: Technology Innovation (TI) Engineer improved reactor materials and components Design advanced heat recovery systems Implement concentrating optics for high solar flux intensities and high temperatures 6

Activity 5: Research Infrastructure (RI) Optimize dedicated research infrastructure (e.g., EU project SFERA) Activity 6: Market Penetration (MP) Task Activities Develop Roadmap to Solar Fuels Strategy for Industry Involvement and Market Penetration (ExCo funding approved 2012) Involve industry in developing commercial applications of the most mature solar fuels technologies 7

Roadmap to Solar Fuels Task II Activity 6 with ExCo Funding Phase 1: Project Initiation and Concept Preparation (2012-2013) Identify potentially interested industries primarily from oil, gas, and coal sectors and responsible governmental representatives in two selected host countries (Australia and South Africa) Prepare documents and presentations illustrating CO 2 mitigation and market potential of specific solar fuels (e.g., H 2 ; syngas; liquid fuels) Organize workshops with interested high-level industrial and governmental representatives in the selected host countries Present Solar Fuels Science and Technology with well-developed showcase, e.g., solar reforming and gasification (SolarPACES experts) Initiate Roadmap to Solar Fuels (local and external SolarPACES experts together with identified industries and other interested bodies) Collect requisitions and pre-conditions for implementing the roadmap that will serve as a feedback for further development works to supply the country-specific needs. 8

Roadmap to Solar Fuels Task II Activity 6 with ExCo Funding Phase 2 (anticipated for 2013-2014): Perform screening analysis to identify the most promising options for solar fuels Develop a detailed and complete Roadmap to Solar Fuels (local and external SolarPACES experts, interested industries, and responsible governmental representatives). 9

Task II Activity 6 with ExCo Funding Workshop in South Africa: Location NWU, Potchefstroom (~150 km west of Johannesburg) Date Week 13 th -15 th February 2013 Proposed Agenda: 1. Welcome/Introduction 2. Overview of Solar Fuels (SolarPACES Experts) 3. Solar Fuels Opportunities in RSA [TBD] a. Petrochemical Industry (H 2, syngas & liquid fuels) b. Chemicals and Materials Production/Refinement c. Thermo Chemical Storage & Thermal Storage d. Coal Conversion 4. Panel Discussion 5. Closure Participants in Workshop: 1. Industry: a. Eskom b. Sasol c. Refineries (PetroSA, Natref, Sapref) d. Aluminium industry e. Coal mining companies (Anglo American, Exxaro) 2. Government: a. Department of Energy / SANEDI b. Department of S&T / TIA c. Provincial government reps 3. Academic/Research Institution: a. CSIR b. Mintek c. Universities (U. Stellenbosch, U. Pretoria) d. Technical Universities 10

Task II Activity 6 with ExCo Funding Workshop in Australia (1): Location and Date CSIRO Newcastle, 18 th April 2013 Proposed Agenda: 1. Welcome/Introduction (Stein / McNaughton) 2. Solar Fuels Science & Technology (SolarPACES Experts) 3. Solar Thermal Fuels opportunities in Australia (Stein / Lovegrove / McNaughton / Hinkley) a. Remote Power b. Coal Steam Gas Conversion c. Natural Gas Processing d. Coal Conversion e. Remote Energy Storage 4. Panel discussion a. Michael Epstein, WIS b. Christian Sattler, DLR c. Anton Meier, PSI d. Stein, CSIRO / Lovegrove, ITP 5. Wrap (Stein / McNaughton) Audience: 1. ARENA (Australian Govt) 2. State Governments 3. Australian Universities 4. Range of Industry but targeting a. Coal Steam Producers b. Mining Companies 11

Task II Activity 6 with ExCo Funding Workshop in Australia (2): Location and Date Canberra, 19 th April 2013 (morning) Tentative plan: 1. High level meeting with key government persons 2. SolarPACES experts discuss solar fuels 12

Task II Activity 6 with ExCo Funding Time Schedule and Deliverables (Revised August 2012) Date Activity Deliverable Responsible Jul / Aug 2012 Identification of industry; Preparation of workshop concept List of interested industries, governments, academia, etc.; date and location of workshop NC RSA & AUS; Task II OA Sep 10, 2012 Meeting Marrakech Approval of workshop concept Task II OA Oct / Nov 2012 Invitation of participants; workshop preparation Flyer Solar Fuels ; ppt-presentation Solar Fuels NC RSA & AUS; Task II OA Feb 13-15, 2013 Workshop South Africa; Initial roadmap concept Participants list; Meeting minutes; Roadmap to Solar Fuels concept NC RSA Apr 18-19, 2013 Workshop Australia; Initial roadmap concept Participants list; Meeting minutes; Roadmap to Solar Fuels concept NC AUS Jun 2013 Preparation of initial roadmap document Initial Roadmap to Solar Fuels document; Final report to ExCo Task II OA 13

Task II Activity 6 with ExCo Funding Budget Overview Responsible (Institution) Activity Expenses Initial Budget * ( ) Task II OA (PSI) Coordination; Workshop participation; Initial roadmap concept Documents (layout and printing); Reporting (technical, financial); Travels to workshops (max. 2) 5.000 SP expert (DLR) SP expert (WIS) Workshop participation; Initial roadmap concept Workshop participation; Initial roadmap concept Travels to workshops (max. 2) 5.000 Travels to workshops (max. 2) 5.000 NC AUS (CSIRO) Preparatory work for workshop in AUS; Initial roadmap concept Organization of 1-2 workshops with interested industries, governmental representatives, and SP experts 5.000 NC RSA (CSIR) Preparatory work for workshop in RSA; Initial roadmap concept Organization of 1-2 workshops with interested industries, governmental representatives, and SP experts 5.000 * Remark: The initial budget is equally distributed among all participating institutions, assuming that travel costs approximately match expenses for workshop organization, and the amount of working hours will be similar for all participants. Note that own resources will be needed to fully cover salary costs. 14

Main focus of Task II Task Activity / Country Matrix Enable research and development (R&D) and increasingly pilot and demonstration (P&D) projects. Information sharing (IS): Reporting results from national and transnational projects (Task II Annual Meeting; SolarPACES Annual Report) Active participation (AP): Partnership within EU projects facilitated by SolarPACES contacts. Recently, an EU-FP7 Call (FP7-ENERGY-2013-IRP) for Integrated Research Programs (IPR) has been launched, explicitly addressing the European Energy Research Alliance (EERA), among them the EERA Joint Program CSP. The Task II OA is leading the Subprogram Solar Thermochemical Production of Fuels (STPF) and has been asked to coordinate the pertinent Work Package. Activity 6 (active participation of five countries) 15

Task Activity / Country Matrix Country Activity 1 Solar Fuels (SF) 2 Solar Materials (SM) 3 Thermochem. Storage (TS) 4 Technology Innovation (TI) 5 Research Infrastructure (RI) 6 Market Penetration (MP) Australia IS IS IS IS AP (China) (EU) (AP) (AP) (AP) (AP) (AP) France AP, IS AP AP AP AP, IS Germany AP, IS AP AP AP AP, IS AP Israel AP, IS AP AP IS AP, IS AP Italy AP, IS AP AP AP AP, IS Mexico IS (Mitsubishi) R. Korea IS IS IS South Africa AP AP Spain AP, IS AP AP AP AP, IS Switzerland AP, IS AP AP AP AP, IS AP USA IS IS IS IS AP through (IS resulting from national projects) EU projects HYDROSOL SOLARJET EERA JP CSP EU project ENEXAL EU project TCSPower EERA JP CSP EERA JP CSP EU project SFERA SOLLAB EERA JP CSP Roadmap to Solar Fuels (ExCo funding approved in 2012) 16

Task Direction Future prospects Further promote the development and deployment of promising solar thermo-chemical technologies and related solar infrastructure: Solar production of liquid fuels from water and CO 2 Solar processing of materials Thermo-chemical storage of solar energy Concentrating solar research and demonstration facilities (1-10 MW th ) for pre-commercial testing of high-temperature thermo-chemical processes to produce solar fuels and materials 17

Contacts with hydrogen community Task Outreach IEA s Hydrogen Implementing Agreement (IEA-HIA) Task 25 High Temperature Processes for Hydrogen Production (2007-2011): Complementary activities have been pursued in developing a research roadmap for massive hydrogen production International Partnership for Hydrogen and Fuel Cells in the Economy (IPHE): Two collaborative projects have been initiated towards the development of the most promising technologies for massive solar hydrogen production (reforming of methane; thermo-chemical cycles). However, loss of political support and shift away from research has stopped these promising projects. Continuation of this initiative is warranted by pooling the expertise in solar hydrogen production from the US, Europe, Australia, and Japan (and maybe from more countries in the future) potentially under the umbrella of SolarPACES. 18

Task Outreach Contacts with fuels community So far, contacts with the fuels community are limited to collaborations with targeted industries in individual projects: Examples: - Shell (EU project SOLARJET); - PDVSA, Petróleos de Venezuela (industrial project SYNPET) In Activity 6, potential industrial players shall be identified: - SASOL - Refineries (PetroSA, Natref, Sapref) 19

Structure Maintain network of national coordinators Task Organization Coordination of international solar chemical research, development and demonstration efforts Exchange of technical and scientific information Keep annual meeting schedule Forum for presenting and discussing major technological achievements in member countries Task II Meeting, Granada, Spain, September 19, 2011 17 attendees from 9 countries Organize targeted workshops with industrial and governmental representatives (see Activity 6) 20

Contact Task II Operating Agent Dr. Anton Meier PAUL SCHERRER INSTITUT (PSI) Deputy Head, Solar Technology Laboratory WKPA/008 5232 Villigen PSI Switzerland Phone: +41 56 310 27 88 Fax: +41 56 310 31 60 E-mail: anton.meier@psi.ch Internet: http://solar.web.psi.ch/ http://www.pre.ethz.ch/ 21