Non-electrical Application of nuclear Power

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Non-electrical Application of nuclear Power Desalination and Water Reuse- A technology for the future Ghassan Ejjeh-Director IDA and Six Construct Leon Awerbuch-President LET, Director IDA 17 April 2007, Oarai

World Water Salt Water 97.5% Total Fresh Water 2.5% 68.9% Glaciers and permanent snow cover 0.3% renewable Freshwater 29.9% Fresh Groundwater 0.9% Other (swamps, moisture, etc.)

Increased Water Demands: Greater extraction of groundwater resulting in depletion of the aquifers, The only available choice, to meet the demand is SEA WATER DESALINATION

Desalination will create sustainable development of extra water resources Help minimize regional and international conflicts, over sharing of water. Will offer commercial opportunity of 80 billion dollars plus, in the next 10-20 years.

The Challenge The need for ever increasing quantities of low cost desalinated water To ensure environmentally sustainable expansion in supply To create a product which is reliable and can attract finance

MARKET DRIVERS for DESALINATION and POWER Increasing water demand Decreasing unit cost of desalination through technology improvement Lack of alternatives to desalination Environmental constraints increasing the cost of traditional water resources Imbalance between rapid growth of water demand and slower growth of peak power Water can be stored, whereas electricity cannot

TRENDS IN DESALINATION AND POWER MARKETS Movement towards market pricing of water Privatisation of water supply Introduction of Build Own and Operated (BOO) concept to power and desalination projects Profitability moving from manufacturing to ownership and O&M Hybrid and Nanofiltration (NF) as a solution to the power surplus and need for cost reduction.

Desalting Inventory Desalting Inventory Worldwide there are 15,233 desalting units with total capacity of 32,400,000 m3 /d or 5,706 MIGPD Over the last two years the increase averaged 10.5% / year The Middle East is still the dominant market Saudi Arabia 22.4% UAE 20.4% USA 12.0% Kuwait 8.4%

Total desalination capacity worldwide By Region Caribbean South America Australia 3.5% 0.8% 0.8% North America 16.2% Africa 5.1% Middle East 49.1% Asia 11.2% Europe 13.3%

Total desalination capacity worldwide by the source water. By Capacity River water Pure water Wastewater Brine Brackish water Seawater

Desalting Inventory Technology For all plants installed and contracted MSF represents 43.5% RO represents 43.5% For seawater as a feed MSF represents 66.3% RO represents 22.4% MED and HYBRIDS coming strong

The significant increase in fuel-energy and material cost has a dramatic impact on capital and operational cost of Desalination and Power plants. Impact of US$ 60-75 per barrel oil, natural gas exceeding 11 $/MMBTU and high demand for raw materials, steel, copper, nickel and concrete has dramatically increased pressure to develop novel solutions. Can we minimize energy consumption and reduce volume and weight of desalination plants?

Desalination is an energy and capital intensive process. All major desalination technologies Multistage Flash (MSF), Multi-effect Distillation (MED and MED TVC), and Mechanical Vapor Compression (MVC) as well as Reverse Osmosis (RO) and Hybrids will be significantly affected by energy costs

Energy Requirements (Steam/Electricity) product Process Live Steam (ton product/ton steam) Electricity kwh/ton Multi Stage Flash 8 4 Vapour Compression n/a 8 Multi Effect Distillation 12 2 Reverse Osmosis: with energy recovery without energy recovery n/a 3.5-5.5 5.5 n/a 8.5

Desalination Technologies Multi-Stage Stage-Flash Distillation (MSF) Multi-Effect Effect- Distillation (MED) Reverse Osmosis (RO) Vapour Compression Distillation (VCD)

Thermally driven Desalination Technologies Multi-stage Flash (MSF) Multi-effect Distillation (MED) Multi-effect Distillation with Thermocompression (MED - TC)

Multi Stage Flash (MSF) Raw seawater total dissolved solids (TDS): 35-47,000 mg/l Maximum brine temperature: 112 o C Performance ratio: 8 Electrical power: 3-43 4 kwh/m 3 Scale inhibitors used for scale control Recycle type plant Dual purpose plant

MSF well established reliable technology with the limits for Performance Ratio (PR) of PR=10 typical PR=8, internal power consumption of 4kWhr/ton of water, with turndown ratio from 110-70% of nominal capacity capital cost $4.00-$8.00 $8.00 per gallon per day installed (GPD).

MSF KEY PARAMETERS Capital Cost MSF 5.5 US$ MM per MIGD Capital Cost Intake /Outfall 0.1 US$ MM per MIGD of cooling MSF GOR 8 Tons of product/ton of steam LP Steam Supply 2.5-3 Bar. A Lost Power Potential 1.225 MW/MIGD Power Consumption 4 kw.hr/m³ of distillate Steam Consumption 23.7 Tons/MIGD Chemical Costs 40,000 US$/yr per MIGD MSF R&R 1% TIC/yr Labor 40,000 US$/yr per MIGD

Multi Effect Distillation (MED) Raw seawater total dissolved solids (TDS): 35-47,000 mg/l Maximum brine temperature: 76 o C Performance ratio: 12 Electrical power: 2 kwh/m 3 Scale inhibitors used for scale control Dual purpose plant

MED with wide range of performance ratios from PR-8 to PR-16, typical PR=12, internal power consumption of 1.8 kwhr/ton of water with turndown ratios from 120 to 45% of nominal capacity, capital cost of MED plants vary from $3.50-$7.00 $7.00 per GPD. MED unit Thermocompression (MED-TC) are similar in characteristic to MED but require higher pressure steam-jet compressor acting as the heat pump. They are designed where 2 to 10 atm steam is available, for water vapour to be thermocompressed across several effects. MED-TC is particularly in use with Gas Turbines.

Multi-Effect Distillation

MED KEY PARAMETERS Capital Cost MED 4.5 US$ MM per MIGD Capital Cost Intake /Outfall 0.1 US$ MM per MIGD of cooling MED GOR 12 Tons of product/ton of steam LP Steam Supply 2.5-3 Bar A Lost Power Potential 1.225 MW/MIGD Power Consumption 1.8 KWh/m³ of distillate Steam Consumption 15.8 Tons/MIGD Chemical Costs 40,000 US$/yr per MIGD MED R&R 1% TIC/yr Labor 40,000 US$/yr per MIGD

Electrically driven Desalination Technologies Reverse Osmosis (RO) Vapour Compression Distillation (VCD) Hybrids

Reverse Osmosis (RO) Raw seawater total dissolved solids (TDS): 35-47,000 mg/l Feed pressure: 1000 psia (70 bars) Conversion factor: 35%-50% 50% Membrane life: 5 years Electrical energy consumption: 4.5 kwh/m 3

Seawater RO has become a mature technology with high degree of reliability. It is using electric energy to operate and with energy recovery devices can recover 25% to 30% of total energy, from the high pressure RO reject brine stream. As a result the total plant energy requirements can vary from 4.2 to 7.4 kwhr per ton of product. The RO system can vary some output, but its big advantage is quick start-up allowing its shut-down during peak power operation. The capital cost of the RO plant vary from $3.50- $6.5.00 per GPD.

RO KEY PARAMETERS Capital Cost RO 4.0 US$ MM per MIGD Capital Cost Intake /Outfall Power Consumption 5 Membrane Replacement Rate RO Chemical Costs 0.1 US $MM per MIGD feed Kwh/m³ of Permeate 20% Per yr 50,000 US$/yr per MIGD RO R&R 2% TIC/yr RO Labor 50,000 US$/yr per MIGD

Advantages of Simple Hybrid MSF-RO Power System A common, considerably small seawater intake can be used Product waters from the RO and MSF plants are blended to obtain suitable product water quality A single stage RO process can be used The RO membrane life can be extended Excess power production from the desalting complex can be reduced significantly, or power to water ratio can be significantly reduced Increase Recovery Ratio

Fujeirah Plant - SWRO Racks and Feed Pump/ER Turbine Arrangement

Power Generation Technologies Back-pressure Steam Turbines Extraction Steam Turbines Gas Turbines Combined Cycle Plants Gas Turbines Steam Turbines

Typical Power to Water Ratios for Different Technologies Technology PWR=MW required/million Imperial Gallons per day Steam Turbine BTG - MSF PWR = 5.0 Steam Turbine EST - MED PWR = 7.0 Steam Turbine EST - MSF PWR = 10.0 Gas Turbine GT - HRSG - MED PWR = 6.0 Gas Turbine GT - HRSF - MSF PWR = 8.0 Combined Cycle BTG - MED PWR = 10.0 Combined Cycle BTG - MSF PWR = 16.0 Combined Cycle EST - MED PWR = 12.0 Combined Cycle EST - MSF PWR = 19.0 Reverse Osmosis RO PWR = 0.8-1.5

Traditional Power Desalination Combined Cycle Steam & Power Power for Sale Power to Desal Multi Stage Flash Distillation Feed Lost Power Revenue Opportunity Steam to Desal Brine Reject CW SEA Product Water

POWER AND DESALINATION PRIVATE PROJECTS IN THE MIDDLE EAST Authority plant Power contractor Lot P Water contractor Lot D ADWEA Al Taweelah A2 Siemens Hanjung ADWEA Al Taweelah A1 Siemens Sidem MEW Oman Barka Enelpower Hitachi MEW Qatar Ras Laffan Enelpower FI- Italimpianti ADWEA Shuweihat Siemens FI- Italimpianti

POWER AND DESALINATION PRIVATE PROJECTS IN MIDDLE EAST Authority Plant Water cap Power Technology Developer MIGD MW ADWEA 50 710 MSF CMS Al Taweelah A2 ADWEA Al Taweelah A1 50 1100 MED TRACTEBEL TOTALFINA MEW Qatar Ras Laffan 40 750 MSF AES MEW Oman Barka 30 600 MSF AES ADWEA Shuweihat 100 1500 MSF CMS MEW Oman Barka 30 500 MSF AES

New Hybrid Power Desalination Combined Cycle Steam & Power Power for Sale Power to Desal Multi Stage Flash Distillation Lost Power Revenue Opportunity Steam to Desal Reverse Osmosis Nanofiltration SEA Product Water

Nanofiltration NF with Multistage MSF Flash Process Makeup Softening Nanofiltration Deaeration Pretreatment Reject Cooling Water Out Soft Feed Recycle Softening Steam Seawater Reject Section Recovery Section Brine Heater Blowdown MSF Condensate Recycle Distillate

Water Security is based on: Enough desalination capacity. Enough Storage capacity to cover strategic and seasonal variations.

Water Supplies are Scarce Groundwater reserves are being depleted and becoming more saline There is an increasing demand due to population growth, agricultural needs, industrialization and socio-economic improvements

Energy is Power Power is Water, Water is Security Combining Desalination and Aquifer Storage: The DASR Concept

Creating Additional Water Electricity demand drops to 30 40% of peak during the winter months Over 50% of power generation capacity of power desalination plants is idle in winter Idle power can be used to produce low-cost water (above normal demand) using nano-filtration and other membrane desalination technologies

GAS to Power, Power to Seawater Desalination and Storage/Aquifer Storage and Recovery (DASR) Power grid Power Generation Water desalination Water grid Underground Gas Fresh water - underground

BESIX LEADING EDGE WATER TECHNOLOGIES MISSION ECONOMICALLY INCREASE THE OUTPUT OF MSF PLANTS BY: ADDING THE LET NF SYSTEM OPTIMIZING MSF PLANT PERFORMANCE CUTING CAPITAL COSTS BY AT LEAST 25% NO NEED FOR NEW INTAKE AND POWER PLANT The Nanofiltration system will utilize idle electricity for production of water at low marginal cost of power.

Growth for Integrated Hybrid Increasing capacity of existing plants upgrade alongside rehab NF able to capitalize on the effluent water Provide new plants with a clear advantage through a better IGD/$ invested (Capex) Reduce power to water ratio (Kwh/IGD) Improve thermal and membrane based processes

Benefits of Nanofiltration PREFERENTIALLY REMOVES SCALING (DIVALENT) IONS ALLOWS HIGHER TOP BRINE TEMPERATURE FOR MSF (121 vs. 110 C) Higher Flash Range Increases Production Reduced MSF Capital Costs Reduced MSF Operating Costs

THE SEWA CASE of INTEGRATED HYBRID INCREASE 44% THE CAPACITY OF EXISTING MSF FROM 5 MIGD to 7.2 MIGD MIMIMUM FOOT PRINT, NO ROOM FOR NEW DESALINATION PLANTS REDUCE OPERATING COST NO CHANGES TO INTAKE STRUCTURE NO INCREASE IN POWER FACILITIES CUTTING MSF CAPITAL COST FOR ADDITIONAL CAPACITY BY 40%

PLANT OPTIMIZATION IS BASED ON: COMPUTER SIMULATION OF PLANT OPERATIONS RESULTING IN: PLANT MODIFICATIONS TO INCREASE WATER PRODUCTION AND IMPROVING EFFICIENCY COMPREHENSIVE ENGINEERING REVIEW

Investment Costs Comparison Intake $ inv / IGD MSF modifications Desalination plant Civil & Engineering Misc. and commercial Total Direct Investment Total Investment RO N/A 3.3 0.9 0.1 4.3 0.7 5.0 NF + MSF 0.5 2.3 0.25 0.1 3.4 N/A 3.4

Unit Cost Analysis Annual Investment return * Operating Costs Total RO $ / m³ m 0.330 0.268 0.598 NF + MSF $ / m³ m 0.177-.245.245 0.226-.234.234 0.403-.479.479 * Based on a 20 year life and 6% interest rate

Improvements in distillation and membrane processes R. Borsani in the presentation MSF Innovation Beyond Large Size Unit at the IDA Forum on Innovation and Integration in Desalination Dubai described the new frontiers, as TOP BRINE TEMPERATURE : The Increase of TBT can Allow Higher Production With Almost Same Desal Trains HYBRIDISATION : The Application Of Hybrid Technologies (MSF + RO Or MSF + MED) Can Improve Overall Efficiency THERMAL IMPROVEMENT : New MSF Schemes And Ancillary Equipment.

HYBRID WITH NF PRIOR TO MSF LP Steam Bypass Seawater Discharge Brine Heater Seawater Pump Seawater Supply Distillate Product Condensate Return Pre- treatment Chemicals Brine Blowdown Pump Recycle Pump Potable Water Vacuum De- aerator Makeup Pump NF Feed Pump NF Array RO Feed Pump RO Membranes RO Permeate RO Energy Recovery LET Proprietary Brine Discharge NF, RO, MSF Brine

Potential for MED technology improvements. At IDA Forum on Innovation G. Canton in presentation The Recent Progress and Next Generation of MED Plants outline the significant growth and potential for the Multi-effect distillation technology. The 8 MIGD MED, plant started production in Sharjah August 2006, it is the largest single unit and 10X 6 MIGD=60 MIGD Hidd- Bahrain plant awarded is the world largest MED plant.

Future Developments Further reduction of $ invested / IGD to $2.5/IGD through optimization Introduction of UF/MF as pre treatment Reduce operating costs through Energy reduction energy recovery, one pass Chemical reduction NF for MED NF for RO

Energy is Power, Power is Water, Water is Security